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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Preparation of core-shell Pt@Fe3O4 @SiO2 nanostructures by oxidation of core-shell FePt@SiO2 nanoflowers and their performance in preferential CO oxidation reaction

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Author(s):
da Silva, Tiago Luis [1] ; Marques da Silva, Alisson Henrique [1] ; Assaf, Jose Mansur [1]
Total Authors: 3
Affiliation:
[1] Univ Fed Sao Carlos, Dept Engn Quim, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: MATERIALS RESEARCH EXPRESS; v. 6, n. 1 JAN 2019.
Web of Science Citations: 0
Abstract

Core-shell Pt@Fe3O4@SiO2 nanostructures were successfully prepared in three step procedure. FePt nanoflowers were first prepared by an oleylamine-mediated chemical synthetic route, and then coated with thin silica (SiO2) layer (-5 nm) by a method based in microemulsion. Then, the core-shell Pt@Fe3O4@SiO2 nanostructures were prepared thorough the calcination step at 550 degrees C in air static of FePt nanoflowers (FePt@SiO2) samples. The silica layer played an important role to avoid nanoparticles agglomeration during the heat treatment. Iron oxide (Fe3O4) shell grown on Pt nanoparticle surface showed able to act as promoter for CO conversion in Preferential Reaction of Oxidation of CO (PROX-CO). (AU)

FAPESP's process: 14/50279-4 - Brasil Research Centre for Gas Innovation
Grantee:Julio Romano Meneghini
Support type: Research Grants - Research Centers in Engineering Program