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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Synthesis of luminescent polymers in the UV light region from dimethacrylate monomer using novel quinoline dyes

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Alarcon, Rafael Turra [1] ; dos Santos, Giovanny Carvalho [1] ; de Oliveira, Arthur Rossi [1] ; da Silva-Filho, Luiz Carlos [1] ; Bannach, Gilbert [1]
Total Authors: 5
[1] UNESP Sao Paulo State Univ, Sch Sci, Chem Dept, BR-17033260 Bauru, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Journal of Applied Polymer Science; v. 136, n. 19 MAY 15 2019.
Web of Science Citations: 0

This study aims at thermal and morphological features, as well as the degree of conversion these luminescent polymers obtained using a dimethacrylate monomer, and quinoline dyes as photoinitiator. The photoinitiators provide a fluorescent propriety to the final polymer. Thermal properties such as thermal stability, steps of mass loss, and glass transition are obtained by thermogravimetry-differential thermal analysis and derivative thermogravimetric and differential scanning calorimetry. Using the mid-infrared spectroscopy, it is possible to calculate the degree of conversion/rate of polymerization; the data indicate that the quinoline derivatives could be used as photoinitiators in lower concentration (0.1%) resulting in solid rigid polymers with higher conversion (74.24, 71.81, 66.36, and 61.09%). The morphological characteristics of polymers are analyzed by scanning electronic microscopy. Finally, solid ultraviolet-visible (UV-vis) analysis shows a bathochromic shift, due to the stabilization of the molecules in the solid state, compared to liquid UV-vis analysis. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47461. (AU)

FAPESP's process: 13/09022-7 - Thermoanalytical studies, synthesis and characterization of the solid co-crystals of antibiotics (fluoroquinolones) with some co-formers
Grantee:Massao Ionashiro
Support type: Regular Research Grants
FAPESP's process: 18/03460-6 - Structural modification of triglycerides aiming new monomers and polymers, using different synthetic routes: microwave irradiation and photopolymerization
Grantee:Rafael Turra Alarcon
Support type: Scholarships in Brazil - Doctorate
FAPESP's process: 16/01599-1 - Studies about the use of NbCl5 in multicomponent reactions for the synthesis of organic dyes
Grantee:Luiz Carlos da Silva Filho
Support type: Regular Research Grants
FAPESP's process: 18/14506-7 - Study about the one-pot synthesis and application as organic dyes of quinolone and anthrazoline derivatives
Grantee:Luiz Carlos da Silva Filho
Support type: Regular Research Grants
FAPESP's process: 15/00615-0 - Studies on the synthesis and photochemical and photophysical characterization of quinoline derivatives with donor-p-acceptor structure for use as sensitizing dyes in organic electronic devices
Grantee:Giovanny Carvalho dos Santos
Support type: Scholarships in Brazil - Doctorate
FAPESP's process: 17/08820-8 - Synthesis and characterization of biopolymers from vegetable oils and glycerol following the principles of green chemistry
Grantee:Gilbert Bannach
Support type: Regular Research Grants