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Synthesis and characterization of biopolymers from vegetable oils and glycerol following the principles of green chemistry

Abstract

The objectives of this project are synthesis and characterization of new polymers following principles of green chemistry, using industrial wastes (glycerol), several vegetable oils such as babassu, soybean, grape, macauba and sunflower; and low cost reagents as maleic anhydride. An important point in this project is add value to bio-commodities produced in Brazil. Simultaneous Thermogravimetric/Derivative Thermogravimetry-Differential Thermal Analysis (TG/DTG-DTA), Differential Scanning Calorimetry (DSC) will characterize the synthesized polymers. Complementary studies will be made by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-Ray diffraction (XRD), Nuclear Magnetic Resonance (NMR 1H and 13C), High Resolution Mass Spectrometry (HRMS) as well as inherent viscosity, density and solvent resistance. Hence, after characterization will be possible propose applications for the synthesized polymers. (AU)

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Scientific publications (23)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY CARVALHO; ROLDAO, JUAN CARLOS; MAGDALENA, AROLDO GERALDO; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. A deep investigation into the thermal degradation of urethane dimethacrylate polymer. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 147, n. 4, p. 3083-3097, . (16/01599-1, 17/08820-8, 18/03460-6, 18/14506-7, 15/00615-0)
PIEDADE, LUCAS PEREIRA; PINTAO, CARLOS ALBERTO FONZAR; FOSCHINI, CESAR RENATO; SILVA, MARCOS RIBEIRO DA; AZEVEDO NETO, NILTON FRANCELOSI. Alternative dynamic torsion test to evaluate the elastic modulus of polymers. MATERIALS RESEARCH EXPRESS, v. 7, n. 9, . (07/04094-9, 17/08820-8)
BIM-JUNIOR, ODAIR; GAGLIERI, CAROLINE; BEDRAN-RUSSO, ANA K.; BUENO-SILVA, BRUNO; BANNACH, GILBERT; FREM, REGINA; XIMENES, VALDECIR FARIAS; LISBOA-FILHO, PAULO N.. MOF-Based Erodible System for On-Demand Release of Bioactive Flavonoid at the Polymer-Tissue Interface. ACS BIOMATERIALS SCIENCE & ENGINEERING, v. 6, n. 8, p. 4539-4550, . (17/08820-8, 14/50926-0, 18/02186-8)
ALARCON, RAFAEL TURRA; DOS SANTOS, GIOVANNY CARVALHO; DE OLIVEIRA, ARTHUR ROSSI; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. Synthesis of luminescent polymers in the UV light region from dimethacrylate monomer using novel quinoline dyes. Journal of Applied Polymer Science, v. 136, n. 19, . (13/09022-7, 18/03460-6, 16/01599-1, 18/14506-7, 15/00615-0, 17/08820-8)
HOLANDA, BRUNO B. C.; ALARCON, RAFAEL T.; GUERRA, RENAN B.; RINALDO, DANIEL; SPAZZINI, FABIOLA C. R.; CASTRO, RICARDO A. E.; BANNACH, GILBERT. Investigation of thermal degradation products of mebendazole by thermal and spectroscopic analysis. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, v. 135, p. 76-84, . (18/03460-6, 17/08820-8)
BALDO PIRES, OSMAR ANTONIO; ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. Synthesis and characterization of a biopolymer of glycerol and macadamia oil. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 137, n. 1, p. 161-170, . (13/09022-7, 16/01599-1, 17/08820-8, 18/03460-6, 15/00615-0)
ESTEVAM DA SILVA, JOSE EDUARDO; ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; MAGDALENA, AROLDO GERALDO; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. New thermal study of polymerization and degradation kinetics of methylene diphenyl diisocyanate. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 133, n. 3, p. 1455-1462, . (13/09022-7, 17/08820-8)
DEMARIO VIEIRA, RENATA LEIA; GAGLIERI, CAROLINE; DE OLIVEIRA, CRISTINA SOLTOVSKI; FERREIRA, LAURA TEOFILO; SCHNITZLER, EGON; BANNACH, GILBERT. Effect of the milling process on the thermal behavior and crystallinity of buckwheat starch. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 144, n. 3, . (17/08820-8)
GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; DE MOURA, ANIELE; MENDES, RONI A.; CAIRES, FLAVIO J.. Is Thermogravimetry an efficient alternative to gas chromatography in degree of biodiesel conversion?. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 135, n. 4, p. 2591-2597, . (17/14936-9, 17/08820-8)
FERREIRA, LAURA TEOFILO; ALARCON, RAFAEL TURRA; PERPETUO, GLAUCO LINI; BANNACH, GILBERT. Investigation and characterization by TG/DTG-DTA and DSC of the fusion of Riboflavin, and its interaction with the antibiotic norfloxacin in the screening of cocrystal. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 136, n. 2, p. 581-588, . (13/09022-7, 18/03460-6, 17/08820-8)
ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DE OLIVEIRA, ARTHUR ROSSI; BANNACH, GILBERT. Use of DSC in degree of conversion of dimethacrylate polymers: easier and faster than MIR technique. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 132, n. 2, p. 1423-1427, . (13/09022-7, 17/08820-8)
HOLANDA, BRUNO B. C.; BANNACH, GILBERT; SILVA, M. RAMOS; EUSEBIO, M. ERMELINDA S.; CASTRO, RICARDO A. E.. Polymorphism of gemfibrozil: Investigation by thermal and spectroscopic methods. Thermochimica Acta, v. 675, p. 113-118, . (17/08820-8)
ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; BANNACH, GILBERT. Dimethacrylate polymers with different glycerol content. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 132, n. 3, p. 1579-1591, . (13/09022-7, 17/08820-8)
GUERRA, RENAN BARRACH; GALICO, DIOGO ALVES; DE CAMPOS FRAGA-SILVA, THAIS FERNANDA; AGUIAR, JULIA; VENTURINI, JAMES; BANNACH, GILBERT. Rare-earth complexes with anti-inflammatory drug sulindac: Synthesis, characterization, spectroscopic and in vitro biological studies. Inorganica Chimica Acta, v. 526, . (17/08820-8, 13/04096-2)
ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; CAVALHEIRO, EDER T. G.; NORTH, MICHAEL; BANNACH, GILBERT. A new acrylated monomer from macaw vegetable oil that polymerizes without external photoinitiators. JOURNAL OF POLYMER RESEARCH, v. 28, n. 11, . (18/03460-6, 17/08820-8)
FERREIRA, BEATRIZ B.; HOLANDA, BRUNO B. DA C.; LACERDA, LUIZ G.; SCHNITZLER, EGON; VIEIRA, RENATA L. D.; GAGLIERI, CAROLINE; BANNACH, GILBERT. A compatibility study between rice starch and some non-steroidal anti-inflammatories. Thermochimica Acta, v. 698, . (17/08820-8)
ALARCON, RAFAEL T.; LAMB, KATIE J.; BANNACH, GILBERT; NORTH, MICHAEL. Opportunities for the Use of Brazilian Biomass to Produce Renewable Chemicals and Materials. CHEMSUSCHEM, v. 14, n. 1, p. 169-188, . (18/03460-6, 17/08820-8, 19/11493-4)
ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; NORTH, MICHAEL; BANNACH, GILBERT. Spectroscopic characterization and thermal behavior of baru nut and macaw palm vegetable oils and their epoxidized derivatives. INDUSTRIAL CROPS AND PRODUCTS, v. 154, . (17/08820-8, 19/11493-4)
GUERRA, RENAN B.; DE CAMPOS FRAGA-SILVA, THAIS FERNANDA; AGUIAR, JULIA; OSHIRO, PAULA B.; HOLANDA, BRUNO B. C.; VENTURINI, JAMES; BANNACH, GILBERT. Lanthanum(III) and neodymium(III) complexes with anti-inflammatory drug sulindac: Synthesis, characterization, thermal investigation using coupled techniques TG-FTIR, and in vitro biological studies. Inorganica Chimica Acta, v. 503, . (17/08820-8, 13/04096-2)
ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; DE SOUZA, OTAVIO A.; RINALDO, DANIEL; BANNACH, GILBERT. Microwave-Assisted Syntheses of Vegetable Oil-Based Monomer: A Cleaner, Faster, and More Energy Efficient Route. JOURNAL OF POLYMERS AND THE ENVIRONMENT, v. 28, n. 4, . (18/03460-6, 17/08820-8)
ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY C.; MORALLES, ANA C.; MORGON, NELSON H.; DE SOUZA, AGUINALDO R.; BANNACH, GILBERT. AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers. CHEMISTRYSELECT, v. 6, n. 31, p. 7838-7844, . (18/03460-6, 13/08293-7, 17/08820-8, 15/22338-9)
GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; DE MOURA, ANIELE; MAGRI, RAQUEL; DA SILVA-FILHO, LUIZ C.; BANNACH, GILBERT. Green and Efficient Modification of Grape Seed Oil to Synthesize Renewable Monomers. Journal of the Brazilian Chemical Society, v. 32, n. 11, p. 2120-2131, . (20/00906-3, 17/08820-8, 18/03460-6)
MAGRI, RAQUEL; GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; BANNACH, GILBERT. Epoxidation reaction in promising Brazilian biomass: decreased time and catalyst loading to produce renewable monomers. JOURNAL OF POLYMER RESEARCH, v. 28, n. 9, . (18/03460-6, 20/00906-3, 17/08820-8)

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