Plasmonic quantum size effects in silver nanoparticles are dominated by interfaces and local environments

Author(s)

Campos, Alfredo ^{[1, 2]} ; Troc, Nicolas ^[3] ; Cottancin, Emmanuel ^[3] ; Pellarin, Michel ^[3] ; Weissker, Hans-Christian ^{[4, 5]} ; Lerme, Jean ^[3] ; Kociak, Mathieu ^{[1, 2]} ; Hillenkamp, Matthias ^{[3, 6]}

Affiliation

^[1] CNRS, Lab Phys Solides, UMR 8502, Orsay - France

^[2] Univ Paris Sud, Orsay - France

^[3] Univ Claude Bernard Lyon 1, Inst Lumiere Matiere, Univ Lyon, CNRS, UMR5306, Villeurbanne - France

^[4] Aix Marseille Univ, CNRS, CINaM, UMR 7325, Marseille - France

^[5] Univ Estadual Campinas, European Theoret Spect Facil, R Sergio B de Holanda 777, Campinas, SP - Brazil

^[6] Univ Estadual Campinas, Inst Fis Gleb Wataghin, R Sergio B de Holanda 777, Campinas, SP - Brazil

• Document type: Journal article
• Source: Nature Physics; v. 15, n. 3, p. 275+, MAR 2019.
• Web of Science Citations: 15

Abstract

The physical properties of metals change when their dimensions are reduced to the nano-scale and new phenomena such as the localized surface-plasmon resonance (LSPR) appear. This collective electronic excitation can be tuned over a large spectral range by adapting the material, size and shape. The existing literature is as rich as it is controversial-for example, size-dependent spectral shifts of the LSPR in small metal nanoparticles, induced by quantum effects, are reported to the red, to the blue or entirely absent. Here we report how complementary experiments on size-selected small silver nanoparticles embedded in silica can yield inconsistent results on the same system: whereas optical absorption shows no size effect in the range between only a few atoms and similar to 10 nm, a clear spectral shift is observed in single-particle electron spectroscopy. Our quantitative interpretation, based on a mixed classical/quantum model, resolves the apparent contradictions, not only within our experimental data, but also in the literature. Our comprehensive model describes how the local environment is the crucial parameter controlling the manifestation or absence of quantum size effects. (AU)

• FAPESP's process: 16/12807-4 - Polymer layers with embedded metal nanoparticles: building blocks for (bio)sensors
• Grantee: Osvaldo Novais de Oliveira Junior
• Support Opportunities: Research Grants - Visiting Researcher Grant - International