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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Synthesis of d-glyco-alkynone derivatives via carbonylative Sonogashira reaction

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Author(s):
Darbem, Mariana P. [1] ; Esteves, C. Henrique A. [1] ; de Oliveira, Isadora M. [2] ; Reis, Joel S. [1] ; Pimenta, Daniel C. [3] ; Stefani, Helio A. [1]
Total Authors: 6
Affiliation:
[1] Univ Sao Paulo, Fac Ciencias Farmaceut, Sao Paulo, SP - Brazil
[2] Univ Sao Paulo, Inst Quim, Sao Paulo, SP - Brazil
[3] Inst Butantan, Sao Paulo, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: RSC ADVANCES; v. 9, n. 17, p. 9468-9474, 2019.
Web of Science Citations: 2
Abstract

A carbonylative Sonogashira coupling approach to the synthesis of glyco-alkynones is described. Eighteen examples were obtained in moderate do nearly quantitative yields under mild conditions employing Mo(CO)(6) as a safe carbon monoxide source. Functionalization of the alkynyl moiety via cycloaddition with organic azides provided six examples of glyco-triazoles. (AU)

FAPESP's process: 16/24396-9 - Triazolic 2-Aryloxazolines: synthesis of small libraries, biological activity, fluorescence and ligands
Grantee:Mariana Pompilio Darbem Rocha
Support type: Scholarships in Brazil - Doctorate
FAPESP's process: 16/04289-3 - Synthesis of calcogeno amino acids derivatives and 4-calcogeno quinolines via multicomponent reactions
Grantee:Isadora Maria de Oliveira
Support type: Scholarships in Brazil - Doctorate (Direct)
FAPESP's process: 17/26673-2 - CuH-Catalyzed fluorination of alkenes ánd PET applications
Grantee:Carlos Henrique Alves Esteves
Support type: Scholarships in Brazil - Post-Doctorate
FAPESP's process: 16/02392-1 - 2-aryloxazolines: synthesis, biological activity ánd fluorescence
Grantee:Joel Savi dos Reis
Support type: Scholarships in Brazil - Post-Doctorate
FAPESP's process: 17/24821-4 - Carbonylative Coupling and Intramolecular Cycloaddition [2 + 2] Reactions Employing D-Glucal
Grantee:Helio Alexandre Stefani
Support type: Regular Research Grants