SOL-GEL alpha-Al2O3 samples: Analysis of the TL kinetics

Author(s)

Polo, Ivon Oramas ^[1] ; Junot, Danilo Oliveira ^[1] ; Caldas, Linda V. E. ^[1]

Affiliation

^[1] IPEN CNEN, Ave Prof Lineu Prestes 2242, BR-05508000 Sao Paulo, SP - Brazil

• Document type: Journal article
• Source: Journal of Applied Physics; v. 125, n. 18 MAY 14 2019.
• Web of Science Citations: 0

Abstract

The analysis of the thermoluminiscence (TL) kinetics parameters of SOL-GEL -Al2O3 with several different concentrations of impurities prepared through the solgel process is reported. A TL glow curve measured at 0.2K/s after beta irradiation to 0.5Gy revealed one peak at approximately 447K. TL spectra were acquired and showed luminescent emission bands around 420nm and 750nm. The activation energies, the frequency factors, and the kinetic order involved in the TL emission were evaluated using the maximum peak temperature response, the peak shape of the TL glow curve, the TL glow curve area, and the glow curve fitting methods. The order of kinetics of the peak was evaluated as first order using T-M dependence on the radiation dose. The (T-M-T-stop) technique was used for determining the number of peaks in the glow curve. The activation energies obtained are in agreement with all the applied methods. The activation energy calculated by various methods varied from 0.885 +/- 0.008eV to 1.05 +/- 0.10eV. The frequency factor determined by all methods was of the order of 10(9)s(-1). The dosimetric peak is affected by thermal quenching. The following thermal quenching parameters were estimated: the activation energy of the thermal quenching W=1.05 +/- 0.15eV and the constant C=8.27x10(10)s(-1). The trapping parameters of SOL-GEL -Al2O3 detectors are reported in the present work for the first time. (AU)