Effective chromium removal from water by polyaniline-coated electrospun adsorbent membrane

Author(s)

Dognani, Guilherme ^{[1, 2]} ; Hadi, Pejman ^{[1, 3]} ; Ma, Hongyang ^{[1, 4]} ; Cabrera, Flavio C. ^[2] ; Job, Aldo E. ^[2] ; Agostini, Deuber L. S. ^[2] ; Hsiao, Benjamin S. ^[1]

Affiliation

^[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 - USA

^[2] Sao Paulo State Univ UNESP, Sch Technol & Sci, BR-19060900 Presidente Prudente, SP - Brazil

^[3] SUNY Stony Brook, New York State Ctr Clean Water Technol, Stony Brook, NY 11794 - USA

^[4] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029 - Peoples R China

• Document type: Journal article
• Source: CHEMICAL ENGINEERING JOURNAL; v. 372, p. 341-351, SEP 15 2019.
• Web of Science Citations: 6

Abstract

Polyaniline (PAni)-coated polyvinylidenefluoride-co-hexafluoropropilene (PVDF-HFP) nanofibrous membranes were fabricated by electrospinning of PVDF-HFP followed by in-situ polymerization of PAni on the nanofiber surface. The resulting membranes with PAni coating were applied for chromium removal, where the efficiency was evaluated as functions of the pH value and adsorption time. Dynamic adsorption tests were also carried out at different flow rates and volumes of chromium in water. It was found that the PAni coating greatly enhanced the chromium removal efficiency with the maximum adsorption capacity being 15.08 mg/g at pH = 4.5. The desorption study further confirmed the recyclability of the PAni coated PVDF-HFP membrane showing an efficiency over 70% even after 5 cycles of usage. The structure and property relationships of these membranes were also characterized by FTIR spectroscopy, capillary flow porometer, water contact angle, scanning electron microscopy and X-ray photoelectron spectroscopy. (AU)

• FAPESP's process: 17/03638-7 - Study of flux, permeability, fouling and metal removal capacity of PVDF membranes with functionalized surface
• Grantee: Guilherme Dognani
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate
• FAPESP's process: 15/21261-2 - Development of water pre-filters from PVDF electrospun membranes with functionalized surface for adsorption of CR6+
• Grantee: Guilherme Dognani
• Support Opportunities: Scholarships in Brazil - Doctorate