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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Fabrication of nanoporous gold-islands via hydrogen bubble template: An efficient electrocatalyst for oxygen reduction and hydrogen evolution reactions

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Author(s):
Hernandez-Saravia, Lucas Patricio [1, 2] ; Sukeri, Anandhakumar [1] ; Bertotti, Mauro [1]
Total Authors: 3
Affiliation:
[1] Univ Sao Paulo, Inst Chem, Dept Fundamental Chem, Ave Prof Lineu Prestes 748, Sao Paulo, SP - Brazil
[2] Univ Tarapaca, Dept Chem, Ave Gen Velazquez 1775, Arica, Arica Y Parinac - Chile
Total Affiliations: 2
Document type: Journal article
Source: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY; v. 44, n. 29, p. 15001-15008, JUN 7 2019.
Web of Science Citations: 2
Abstract

In this report, the fabrication of a high surface area nanoporous gold-island (NPG-islands) onto a glassy carbon (GC) surface by a simple one-step electrodeposition procedure based on a dynamic hydrogen bubble template method is described. The surface morphology, purity and crystalline structure of the porous NPG-islands were analyzed by field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray analysis (EDX), and X-ray diffraction (XRD) techniques. Cyclic voltammetry and linear sweep voltammetry methods were used for electrochemical studies and the electrocatalytic activity of the NPG-islands surface was investigated towards the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER). Electrochemical results revealed exceptional ORR activity of the NPG-islands evaluated by the shift of the onset potential towards less negative values compared to bare GC (0.55 V) and Au (0.25 V) electrodes, respectively, with a 3-fold increased current density in neutral PBS solution (pH 7). Rotating-disk measurements indicate a direct conversion of oxygen to water via a four-electron reduction pathway. The electrocatalytic activity was also evaluated for HER in 0.5 mol L-1 H2SO4 solution and a benchmark current density of 10 mA cm(-2 )at a very low overpotential of -0.075 V was obtained, which is similar to bulk Pt performance. The plausible mechanism of the HER was realized from the Tafel plot and the obtained slope of 46 mV dec(-1) suggests the Volmer-Heyrovsky mechanism takes place in such electrochemical process. Furthermore, the durability of the catalyst was also studied and exceptional stability was observed in cyclic voltammetry (up to 2000 cycles) and chronopotentiometry (at 10 mA cm(-2) for 19 h). (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. (AU)

FAPESP's process: 18/08782-1 - Miniaturized and integrated chemical sensors: new fabrication platforms for biological, clinical and environmental applications
Grantee:Mauro Bertotti
Support Opportunities: Research Projects - Thematic Grants