Advanced search
Start date
Betweenand
Related content
(Reference retrieved automatically from SciELO through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

The role of bondline thickness on mechanical properties of bio-based polyurethane

Full text
Author(s):
Paulo Henrique Lixandrão Fernando [1] ; Cleber Lucius da Costa [2] ; Kelly Cristina de Lira Lixandrão [3] ; Demetrio Jackson dos Santos [4]
Total Authors: 4
Affiliation:
[1] ABC Federal University (UFABC). Engineering, Modeling and Applied Social Sciences Center - Brasil
[2] ABC Federal University (UFABC). Engineering, Modeling and Applied Social Sciences Center - Brasil
[3] ABC Federal University (UFABC). Engineering, Modeling and Applied Social Sciences Center - Brasil
[4] ABC Federal University (UFABC). Engineering, Modeling and Applied Social Sciences Center - Brasil
Total Affiliations: 4
Document type: Journal article
Source: MATERIA-RIO DE JANEIRO; v. 24, n. 3 2019-09-16.
Abstract

ABSTRACT Bio-based adhesives have been largely applied on several applications in many industrial areas, including automotive and laminated food packaging. Polyurethanes (PU) occupy a leading position among the most used bio-based polymers due to their large range of properties and application versatility. Recent works reported that PU obtained from castor oil and Kraft lignin as polyol developed high mechanical properties and blend miscibility. In spite of its well-known mechanical behavior, additional investigations might support the application of this bio-based PU as adhesive. In this context, our work investigated the effect of adhesive (bondline) thickness variation (size effect) on shear modulus of a bio-based polyurethane under finite deformation and related shear stress distribution. Polyurethane was obtained using a blend of Kraft lignin and castor oil as polyol (20 wt% of Kraft lignin) and applied as adhesive for metal bonding, in which adhesive thickness changed from tens of micrometers up to 220 micrometers. Steel plates were used as substrates and adhesive shear modulus was evaluated using substrates with large thickness (4.76 mm), which minimized the effect of substrate deformation on shear modulus measurement. Single lap joints were uniaxial loaded in order to generate the shear stress on adhesive bondline. Additionally, shear modulus changes were simulated by finite element analysis (FEA), analytical models and compared to experimental data. Results revealed the size effect and pointed to high shear modulus of the PU bondline, justifying its use as an adhesive for structural applications. (AU)

FAPESP's process: 17/22936-9 - TEMPERATURE MODULATED OPTICAL REFRACTOMETRY: A MOLECULAR PERSPECTIVE ON CURING KINETIC AND PHASE SEPARATION OF LIGNIN-BASED POLYURETHANES
Grantee:Demetrio Jackson dos Santos
Support Opportunities: Regular Research Grants