Nuclear magnetic resonance characterization of porosity-preserving microcrystalline quartz coatings in Fontainebleau sandstones

Author(s)

Jacomo, Marta Henriques ^[1] ; Ferreira Trindade, Ricardo Ivan ^[1] ; French, Marsha ^[2] ; Lucas-Oliveira, Everton ^[3] ; Montrazi, Elton Tadeu ^[3] ; Bonagamba, Tito Jose ^[3]

Affiliation

^[1] Univ Sao Paulo, Inst Astron Geofis & Ciencias Atmosfer, Sao Paulo - Brazil

^[2] Colorado Sch Mines, Dept Geol & Geol Engn, Golden, CO 80401 - USA

^[3] Univ Sao Paulo, IFSC, Sao Carlos, SP - Brazil

• Document type: Journal article
• Source: AAPG BULLETIN; v. 103, n. 9, p. 2117-2137, SEP 2019.
• Web of Science Citations: 0

Abstract

The almost-pure quartz-cemented Fontainebleau Formation (Paris Basin, France) sandstones are known to preserve their porosity because of microcrystalline quartz coatings. Here, we use nuclear magnetic resonance (NMR) techniques, petrography, scanning electron microscopy, porosity and permeability measurements, hysteresis, and mercury injection capillary pressure curves to identify and analyze their porosity structure. Nuclear magnetic resonance experiments include transverse relaxation time (T-2) distributions and T-2-filtered T-2-T-2 exchange (T2F-TREx), a technique that provides estimates on the diffusion coupling by comparing the evolution of families of pores in T-2 distributions at different exchange times. Samples were divided according to their texture, composition, and abundance of microcrystalline quartz crystals, comprising group 1 samples with very low amounts of coatings and group 2 samples with entire grains coated by microquartz. Both groups show three (or four) peaks in NMR 2-MHz T-2 distribution at approximately 1 (peak A), 10(-1) (peak B), and 10(-2) s (peak C); group 2 samples present a slight shift to shorter T-2 times in comparison with other samples. The longest T-2 peak A is because of intergranular macropores, whereas the shortest peak C is because of the microporosity associated with the microcrystalline quartz coating at the surface of the pores. Peak B is also because of microporosity associated with microcrystalline quartz, but with a different surface/volume ratio being likely related to flat-shaped pores within the microcrystalline coating. The T2F-TREx indicates the proton exchange is higher between macropores and the pore surface micropores (peak C) than between macropores and the internal flat-shaped micropores; no exchange between the two sets of micropores can be observed. Our results show the potential of NMR techniques in characterizing the microporosity in Fontainebleau sandstones, which is key for the mechanism of porosity preservation in these rocks. (AU)

• FAPESP's process: 16/06114-6 - The Neoproterozoic Earth System and the rise of biological complexity
• Grantee: Ricardo Ivan Ferreira da Trindade
• Support Opportunities: Research Projects - Thematic Grants