Fabrication of SrTiO3/g-C3N4 heterostructures for visible light-induced photocatalysis

Author(s)

Ferreira, Meiriele Antunes ^[1] ; da Silva, Gelson T. S. T. ^[2] ; Lopes, Osmando F. ^[3] ; Mastelaro, Valmor R. ^[4] ; Ribeiro, Caue ^{[2, 5]} ; Pires, Manoel J. M. ^{[6, 1]} ; Malagutti, Andrea R. ^[7] ; Avansi Jr, Waldir ; Mourao, Henrique A. J. L. ^{[6, 1]}

Affiliation

^[1] Univ Fed Vales Jequitinhonha & Mucuri, Programa Posgrad Quim, BR-39100000 Diamantina, MG - Brazil

^[2] Embrapa Instrumentacao, BR-13561206 Sao Carlos, SP - Brazil

^[3] Univ Fed Uberlandia, Inst Quim, BR-38400902 Uberlandia, MG - Brazil

^[4] Univ Sao Paulo, Inst Fis Sao Carlos, BR-13566590 Sao Carlos, SP - Brazil

^[5] Forschungszentrum Julich, Inst Energy & Climate Res IEK Electrochem Proc En, D-52425 Julich - Germany

^[6] Univ Fed Vales Jequitinhonha & Mucuri, Inst Ciencia & Tecnol, BR-39100000 Diamantina, MG - Brazil

^[7] Univ Fed Vales Jequitinhonha & Mucuri, Dept Farm, BR-39100000 Diamantina, MG - Brazil

• Document type: Journal article
• Source: MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING; v. 108, MAR 15 2020.
• Web of Science Citations: 0

Abstract

We investigated a new method for the preparation of visible light-activated heterostructured photocatalysts made up of SrTiO3 (STO) and g-C3N4 (CN). The photocatalysts were synthesized by the polymeric precursor method to obtain STO, which was further thermally treated at 550 degrees C for 2 h in presence of melamine at different proportions for CN formation. The SrTiO3/g-C3N4 heterostructures were termed as STOCN-Mel88%, STOCN-Mel92%, STOCN-Mel95%, STOCN-Mel97% and STOCN-Mel99% indicating the use of melamine at 88%, 92%, 95%, 97% or 99%. The SrTiO3/g-C3N4 heterostructures were characterized for their crystalline structure, optical properties, thermal stability, morphology and surface composition, and photocatalytic potential, which was evaluated by photodegradation of methylene blue dye and amiloride under visible light. The melamine content exhibited a strong influence on the formation of CN, as well as on the bulk structure, surface and photocatalytic properties of the SrTiO3/g-C3N4 heterostructures. The heterostructures were catalytically active under visible light due to their reduced band gap energy. The presence of oxygen vacancies in the STO phase associated with the CN phase improved the photogenerated electron-hole charge separation in the SrTiO3/g-C3N4 catalysts. The synthesis described here is efficient in obtaining visible light-activated photocatalysts that are applicable to photocatalytic processes under solar light. (AU)

• FAPESP's process: 18/01258-5 - Novel chemical catalytic and photocatalytic processes for the direct conversion of methane and CO2 to products
• Grantee: José Maria Correa Bueno
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
• Grantee: Elson Longo da Silva
• Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC