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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Functionalization of (-)-beta-pinene and (-)-limonene via cross metathesis with symmetrical internal olefins

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Author(s):
Fernandes, Luciana Sarmento [1, 2] ; Mandelli, Dalmo [1] ; Carvalho, Wagner A. [1] ; Fischmeister, Cedric [2] ; Bruneau, Christian [2]
Total Authors: 5
Affiliation:
[1] Univ Fed ABC, Ctr Ciencias Nat & Humanas, Santo Andre, SP - Brazil
[2] Univ Rennes, ISCR, CNRS, UMR6226, F-35000 Rennes - France
Total Affiliations: 2
Document type: Journal article
Source: Catalysis Communications; v. 135, FEB 2020.
Web of Science Citations: 1
Abstract

The straightforward functionalization of sterically demanding alpha,alpha-disubstituted double bonds of the natural products beta-pinene and limonene via cross metathesis with symmetrical internal olefins is described. The reaction is catalyzed by Hoveyda-Grubbs type ruthenium catalysts in dimethyl carbonate as green solvent and makes possible the clean introduction of ester and nitrile groups in one step without formation of byproducts. (AU)

FAPESP's process: 18/01258-5 - Novel chemical catalytic and photocatalytic processes for the direct conversion of methane and CO2 to products
Grantee:José Maria Correa Bueno
Support type: Research Projects - Thematic Grants
FAPESP's process: 15/26787-2 - Valuation of natural products via methathesis and epoxidation of alkenes
Grantee:Luciana Sarmento Fernandes
Support type: Scholarships in Brazil - Doctorate