Application of low-field nuclear magnetic resonance to assess the onset of asphaltene precipitation in petroleum

Author(s)

Morgan, Vinicius G. ^[1] ; Bastos, Thabita M. ^[2] ; Sad, Cristina M. S. ^[2] ; Leite, Juliete S. D. ^[2] ; Castro, V, Eustaquio R. ; Barbosa, Lucio L. ^[3]

Affiliation

^[1] Univ Fed Rio de Janeiro, Nanotechnol Engn Program COPPE, Rio De Janeiro - Brazil

^[2] V, Univ Fed Espirito Santo, Dept Chem, Vitoria, ES - Brazil

^[3] Univ Fed Sao Paulo, Dept Sea Sci, Lab Res Chem Engn Petr & Fuels, Santos, SP - Brazil

• Document type: Journal article
• Source: FUEL; v. 265, APR 1 2020.
• Web of Science Citations: 0

Abstract

Knowledge of the onset of the asphaltene precipitation point is important in preventing pipe clogging and the reduction of productivity. In this study, we propose a new and simple strategy to determine the onset point of asphaltene precipitation by a low-field nuclear magnetic resonance (NMR) technique based on transverse relaxation time (T-2) measurements. Six Brazilian crude oil (light, medium, and heavy) samples, with asphaltene contents ranging from 0.10 to 7.10 wt%, were assessed using n-heptane as the precipitant, according to the ASTM D6560 method. The good correlation between T-2 and the n-heptane/oil ratio indicated the onset precipitation values between 0.931 and 2.759 mL g(-1). NMR results shows agreement with optical microscopy and literature results. We also propose a correlation between asphaltene content and onset of the asphaltene precipitation. This new idea expand the applicability of low-field NMR in crude oil studies, providing an alternative method for asphaltene precipitation under laboratory conditions and opens the possibility to quantifying the asphaltene content in crude oil without the laborious standard ASTM method. (AU)

• FAPESP's process: 17/02856-0 - Development of Methodologies for Determine Brazilian Petroleum Properties and Onset Precipitation of Asphaltenes.
• Grantee: Lúcio Leonel Barbosa
• Support Opportunities: Regular Research Grants