The role of nanoparticle concentration and CNT coating in high-performance polymer-free micro/nanostructured carbon nanotube-nanoparticle composite electrode for Li intercalation

Author(s)

Freitas Neto, D. B. ^[1] ; Xavier, F. F. S. ^[1] ; Matsubara, E. Y. ^[1] ; Parmar, R. ^{[1, 2]} ; Gunnella, R. ^[2] ; Rosolen, J. M. ^[1]

Affiliation

^[1] Univ Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, Ave Bandeirantes 3900, BR-14040901 Ribeirao Preto, SP - Brazil

^[2] Univ Camerino, Phys Div, Via Madonna Dele Carceri 9, I-62032 Camerino, MC - Italy

• Document type: Journal article
• Source: JOURNAL OF ELECTROANALYTICAL CHEMISTRY; v. 858, FEB 1 2020.
• Web of Science Citations: 0

Abstract

We investigate how Li intercalation into composite electrodes resulting from the combination of graphitic carbon felt (CF) with carbon nanotubes (CNTs) functionalized with electroactive nanoparticles (NPs) depends on NP concentration. To this end, we study CF electrodes coated or not with hydrophilic CNTs containing electrodeposited beta/gamma-MnO(2)NPs (wt% 25, 42, and 69) with hollow-nanotube structure. Galvanic coupling between the CNTs and the NPs is the reason why the electrochemical performance of CNT-NP nanocomposites varies with the NP concentration. The CNT coating on the CF electrode also avoids capacity fading of the CF/MnO2NP electrodes and prevents carbon fibers from interconnecting with SEL More specifically, the CNTs stabilize the solid electrolyte interphase and prevent NP detachment, thereby producing electrodes with long-term cyclability. The best electrochemical performance occurs for CNT/MnO2NP mass wt% 25 (1114 mAh g(-1), 1st discharge/charge Faradaic efficiency similar to 80% at 1 A g(-1), cut-off potential = 4-0.005 V vs Li+ /Li). (C) 2020 Elsevier B.V. All rights reserved. (AU)

• FAPESP's process: 17/04759-2 - Free-binder electrodes for storage/conversion energy
• Grantee: Jose Mauricio Rosolen
• Support Opportunities: Regular Research Grants