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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Ultra-Fast Selective Fructose Dehydration Promoted by a Kraft Lignin Sulfonated Carbon Under Microwave Heating

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Author(s):
Nunes, Renan S. [1] ; Reis, Gabrielle M. [1] ; Vieira, Ligia M. [2] ; Mandelli, Dalmo [1] ; Carvalho, Wagner A. [1]
Total Authors: 5
Affiliation:
[1] Fed Univ ABC UFABC, Ctr Nat Sci & Humanities, Santo Andre, SP - Brazil
[2] Fed Fluminense Univ UFF, Inst Exact Sci, Volta Redonda - Brazil
Total Affiliations: 2
Document type: Journal article
Source: CATALYSIS LETTERS; v. 151, n. 2 JUL 2020.
Web of Science Citations: 0
Abstract

In this work, a highly acidic sulfonated carbon was obtained from eucalyptus kraft lignin, a byproduct from paper industry, and then used as catalyst in fructose dehydration. Reactions were performed employing dimethylsulfoxide (DMSO) as low cost/toxicity solvent and under microwave heating. The main product obtained was 5-hydroxymethylfurfural (5-HMF), a versatile platform compound that can be converted to several products of industrial interest. The catalyst is highly active to fructose dehydration and is able to convert 93.3% of the fructose (in a 10% m/v DMSO solution) with 98% of selectivity for 5-HMF in just 10 s at 393 K. Investigations about the catalyst dosage, reaction temperature and substrate concentration were carried out. In addition, the low-cost catalyst produced outperformed expensive commercial catalysts under the same conditions. After a simple regeneration process, the catalyst produced also can be recycled without significant loss in its catalytic activity. Graphic (AU)

FAPESP's process: 17/24931-4 - Polyols conversion promoted by alternative catalysts under conventional and microwave heating
Grantee:Wagner Alves Carvalho
Support type: Regular Research Grants
FAPESP's process: 16/05006-5 - Contaminants removal from pharmaceutical industry effluents using new materials from waste biodiesel
Grantee:Maraisa Gonçalves
Support type: Regular Research Grants