| Full text | |
| Author(s): |
Total Authors: 2
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| Affiliation: | [1] Univ Estadual Campinas, Sch Chem Engn, Av Albert Einstein 500, BR-13083852 Campinas, SP - Brazil
Total Affiliations: 1
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| Document type: | Journal article |
| Source: | Fluid Phase Equilibria; v. 533, APR 1 2021. |
| Web of Science Citations: | 0 |
| Abstract | |
In this short communication, we show that the analytical solution for the single-particle density of a confined ideal gas within the grand canonical ensemble can be derived from its correlate within the canonical ensemble, without resorting to the Density Functional Theory, avoiding the inherent complications in the transformation between these ensembles. Framing the adsorption phenomenon as a phase equilibrium problem, we then show that both distributions are equal at the same thermodynamic state. (C) 2021 Elsevier B.V. All rights reserved. (AU) | |
| FAPESP's process: | 18/02713-8 - Molecular dynamics of confined fluids: equilibrium and transport properties |
| Grantee: | Luís Fernando Mercier Franco |
| Support Opportunities: | Research Grants - Young Investigators Grants |