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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Versatile Electrochemical Oxidative C(sp(2))-H Bond Selenylation of Resveratrol

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Author(s):
Lazzaris, Maika J. [1] ; Martins, Guilherme M. [2] ; Xavier, Fernando R. [1] ; Braga, Antonio L. [2] ; Mendes, Samuel R. [1]
Total Authors: 5
Affiliation:
[1] Univ Estado Santa Catarina, SINCA Dept Quim, BR-89219719 Joinville, SC - Brazil
[2] Univ Fed Santa Catarina, Labselen, Dept Quim, BR-88040900 Florianopolis, SC - Brazil
Total Affiliations: 2
Document type: Journal article
Source: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY; v. 2021, n. 31 JUL 2021.
Web of Science Citations: 0
Abstract

A simple and environmentally benign procedure for electrochemical oxidative mono- and bis-selenylation of the resveratrol C(sp(2))-H bond was developed. Driven by galvanostatic electrolysis in an undivided cell, it provided efficient transformation under oxidant-, base-, and transition metal-free conditions, in an open system at room temperature. With satisfactory functional group compatibility, it required a substoichiometric amount of NaI, which acted as an electrolyte and mediator. (AU)

FAPESP's process: 14/50249-8 - Green chemistry: sustainable synthetic methods employing benign solvents, safer reagents, and bio-renewable feedstock
Grantee:Arlene Gonçalves Corrêa
Support Opportunities: Research Grants - Research Centers in Engineering Program