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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Application of polyacrylamide-based hydrogels for water removal from biodiesel in isothermal experiments

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Author(s):
Goncalves, Henrique Luiz [1] ; Fregolente, Patricia Bogalhos Lucente [2] ; Fregolente, Leonardo Vasconcelos [1] ; Soares, Joao P. B. [3]
Total Authors: 4
Affiliation:
[1] Univ Estadual Campinas, Chem Engn Sch, BR-13081970 Campinas, SP - Brazil
[2] Salesian Univ Ctr Sao Paulo, BR-13075490 Campinas, SP - Brazil
[3] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9 - Canada
Total Affiliations: 3
Document type: Journal article
Source: FUEL; v. 306, DEC 15 2021.
Web of Science Citations: 0
Abstract

Fuels with water contents higher than the limits specified by regulatory agencies may be subjected to high turbidity, microbial growth fouling, sludge formation, and promote the corrosion and failure of fuel injection components. In this investigation, polyacrylamide, poly(acrylamide-co-sodium acrylate) and poly(acrylamideco-acrylic acid) hydrogels were used to adsorb water from biodiesel in a batch system at 20 degrees C. The water content of biodiesel samples saturated with water could be lowered down to near 400 mg of water/kg of biodiesel under equilibrium conditions, a value comparable to other more mature technologies and in accordance with the EN 14214 standard. Among the three adsorption isotherm models fitted to the experimental data, the Freundlich model presented the best fit for polyacrylamide and poly(acrylamide-co-sodium acrylate) hydrogels, but all models failed for the poly(acrylamide-co-acrylic acid) hydrogel. The use of hydrogels for removal of water from fuels can be easily scaled up to a continuous process for commercial applications. (AU)

FAPESP's process: 15/20630-4 - Biorefinery development integrated to a bioethanol sugar cane plant with zero CO2 emission: routes to convert renewable resources to bio-products and bio-electricity
Grantee:Rubens Maciel Filho
Support Opportunities: Research Projects - Thematic Grants
FAPESP's process: 17/12120-1 - Development of technology for water removal from liquid fuels using hydrogels
Grantee:Leonardo Vasconcelos Fregolente
Support Opportunities: Program for Research on Bioenergy (BIOEN) - Regular Program Grants