Primary thermometers based on sol-gel upconverting Er3+/Yb3+ co-doped yttrium tantalates with high upconversion quantum yield and emission color tunability

Author(s)

Borges, Fernanda Hediger ^[1] ; Martins, Joana Costa ^{[2, 3]} ; Caixeta, Fabio Jose ^[1] ; Pereira, Rafael Ramiro ^[1] ; Carlos, Luis Dias ^{[2, 3]} ; Ferreira, Rute A. S. ^{[2, 3]} ; Goncalves, Rogeria Rocha ^[1]

Affiliation

^[1] Univ Sao Paulo, Dept Quim, Lab Mat Luminescentes Micro & Nanoestruturados Ma, FFCLRP, Ribeirao Preto, SP - Brazil

^[2] Univ Aveiro, CICECO Aveiro Inst Mat, Aveiro - Portugal

^[3] Univ Aveiro, Dept Phys, Aveiro - Portugal

• Document type: Journal article
• Source: Journal of Sol-Gel Science and Technology; NOV 2021.
• Web of Science Citations: 0

Abstract

This study investigates how rare earth ion (RE3+) concentration affects stabilization of the crystalline structure and infrared-to-visible upconversion (UC) in Er3+/Yb3+ co-doped yttrium tantalates, synthesized by the sol-gel method. Under 980 nm, the samples exhibited intense UC luminescence. The crystalline phases strongly influenced the emission color of UC luminescence. The sample consisting of pure Y3TaO7 phase had a yellowish-green color, but a greener emission appeared in the presence of a small amount of M'-YTaO4. Increasing the RE3+ concentration influences the Y3TaO7 crystalline phase stabilization, as well as in the color tunability, since cross-relaxation processes take place, enhancing red emission intensity. This is the first report of UC quantum yield (UCQY) for yttrium tantalate samples (up to 0.016 +/- 0.002%). Samples doped with Er3+/Yb3+ 0.5/1.5 mol % annealed at 900 or 1100 degrees C were successfully developed as primary thermometers. The temperature of these materials can be predicted without any calibration through the Boltzmann law, using the ratio of the intensity of transitions of Er3+. The maximum relative thermal sensitivity was 1.31 +/- 0.05% K-1, which was higher than the sensitivity reported for other oxides. Nanothermometer repeatability was 98.8% and 99.8%, with minimum temperature uncertainty of 0.93 and 0.87 K for samples annealed at 900 and 1100 degrees C, respectively. The great tunability properties, UCQY values, and nanothermometry results indicated that primary thermometers can be implemented by using Er3+/Yb3+ co-doped yttrium tantalate upconverting nanoparticles for biophotonic applications in temperature sensing and deep tissue imaging. (AU)

• FAPESP's process: 17/10424-3 - Luminescent rare earth tantalate and niobate: synthesis, properties and applications in photonics
• Grantee: Fernanda Hediger Borges Ribeiro
• Support Opportunities: Scholarships in Brazil - Master
• FAPESP's process: 18/04587-0 - Yttrium Tantalates and Niobates rare earth ions doped with emission in the visible and near infrared region for photonics applications
• Grantee: Fernanda Hediger Borges Ribeiro
• Support Opportunities: Scholarships abroad - Research Internship - Master's degree
• FAPESP's process: 17/11301-2 - Rare earth doped micro and nanostructures luminescent materials: properties and applications
• Grantee: Rogéria Rocha Gonçalves
• Support Opportunities: Regular Research Grants