nhanced electromechanical properties in low-temperature gadolinium-doped ceria composites with low-dimensional carbon allotrope

Author(s):Show less -

Han, Jinkyu ^{[1, 2]} ; Kabir, Ahsanul ^[1] ; Tinti, Victor Buratto ^{[1, 3]} ; Santucci, Simone ^[1] ; Song, Da Som ^[4] ; Kim, So Young ^[4] ; Song, Wooseok ^[4] ; Kim, Eunyoung ^[5] ; Bu, Sang Don ^[5] ; Kern, Frank ^[6] ; de Florio, Daniel Zanetti ^[3] ; Esposito, Vincenzo ^[1]

Affiliation

^[1] Tech Univ Denmark, Dept Energy Convers & Storage, DK-2800 Lyngby - Denmark

^[2] ASTAR, Inst Mat Res & Engn, Singapore 138634 - Singapore

^[3] Fed Univ ABC UFABC, Engn Modelling & Appl Social Sci Ctr CECS, Av Estados 5001, BR-09210580 Santo Andre, SP - Brazil

^[4] Korea Res Inst Chem Technol KRICT, Thin Film Mat Res Ctr, Daejeon 34114 - South Korea

^[5] Jeonbuk Natl Univ, Res Inst Phys & Chem, Dept Phys, Jeonju 54896 - South Korea

^[6] Univ Stuttgart, Inst Mfg Technol Ceram Components & Composites, D-70569 Stuttgart - Germany

• Document type: Journal article
• Source: JOURNAL OF MATERIALS CHEMISTRY A; v. 10, n. 8, p. 4024-4031, FEB 22 2022.
• Web of Science Citations: 0

Abstract

We couple the spark plasma sintering (SPS) technique with the ball mill process to fabricate a new electro-chemo-mechanical functional carbon-metal oxide hybrid material. Graphene oxide (GO) or carbon nanotubes (CNT) carbon allotropes are mechanically mixed with gadolinium-doped ceria (CGO). SPS allows consolidating dense carbon-metal oxide hybrids with uniform morphology and high crystallinity. The carbon allotropes and SPS lead to highly reduced CGO. The metal oxide presents a chemically tuned grain boundary with highly oxygen defect concentration at the near-grain boundary region. The hybrid interface can hinder chemical oxidation at high-temperature depending on the carbon allotropy. As a result, the hybrid materials with CNT display high ionic conductivity and activation energy, reducing the space charge layer and charge distribution. This feature enhances the electromechanical properties at room temperature. We especially disclose electrostriction in the CNT-based hybrids superior to the pure CGO and follow a non-Newnham relation. Notably, integrating carbon materials with metal oxides using the SPS can generally be applied to synthesising a range of functional metal oxide composite. (AU)

• FAPESP's process: 17/11937-4 - A sustainable path to methane conversion by advanced electrochemical technologies
• Grantee: Fabio Coral Fonseca
• Support Opportunities: Research Grants - Research Centers in Engineering Program
• FAPESP's process: 15/24999-2 - New ceramic compounds for protonic solid oxide fuel cells
• Grantee: Daniel Zanetti de Florio
• Support Opportunities: Regular Research Grants