| Full text | |
| Author(s): |
Real, Carla G.
;
Thaines, Ericson H. N. S.
;
Pocrifka, Leandro A.
;
Freitas, Renato G.
;
Singh, Gurpreet
;
Zanin, Hudson
Total Authors: 6
|
| Document type: | Journal article |
| Source: | JOURNAL OF ENERGY STORAGE; v. 52, p. 16-pg., 2022-05-18. |
| Abstract | |
This study investigated flexible, freestanding niobium pentoxide (Nb2O5) decorated multiwalled carbon nano tube (MWCNT) electrode material in a sodium-ion pseudocapacitor and its respective energy storage mechanism. Sodium is an abundant element in the Earth's crust, with attractive sustainability and low-cost appeal for the scientific community and energy markets such as electric vehicles and renewable energies. Combined with niobium pentoxide and carbon nanotubes, sodium ions can perform ultra-fast intercalation into niobium pent oxide and electrostatic adsorption onto carbon high surface areas. Niobium pentoxide particles were investigated using X-ray diffraction via Rietveld refinement, a powerful technique to study crystalline materials' electronic and structural properties that directly influence Na+-ion diffusion. The niobium pentoxide-decorated MWCNT electrode material was investigated within a symmetric supercapacitor (SIC) and as an anode for sodium-ion batteries (SIBs). A finite-length transmission line was used to model the impedance behavior of the solid and liquid phases that comprised the material/solution interface. This numerical modelling allowed investigators to infer the presence of MWCNT as a nanostructured matrix since Nb2O5 dispersive nanoparticles increased the overall pseudopacacitance by 63.2% for Nb2O5/MWCNT compared to MWCNT nanostructured electrodes. Electrochemical findings revealed a maximum capacitance of 192 F g(-1) for the SIC full cell, with capacitance retention of 96% after 10,000 cycles. In addition, the SIC delivered outstanding power density from 98.7 to 24,671 W kg(-1) and high energy density from 5.4 to 2.7 W h kg(-1). In an SIB half-cell configuration, the electrode delivered a reversible sodium-ion storage capacity of ~163 mA h g(-1), with a retention capacity of ~68 mA h g(-1) after 100 cycles at 25 mA g(-1). These systems bridge the gap between supercapacitors and batteries by employing the best properties of them both. (AU) | |
| FAPESP's process: | 17/11958-1 - CINE - Advanced Energy Storage Division |
| Grantee: | Rubens Maciel Filho |
| Support Opportunities: | Research Grants - Research Centers in Engineering Program |
| FAPESP's process: | 14/02163-7 - Development of supercapacitors devices from graphene, carbon nanotubes and diamonds |
| Grantee: | Hudson Giovani Zanin |
| Support Opportunities: | Research Grants - Young Investigators Grants |