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Tuning of renewable sponge-like polyurethane physical-chemical and morphological properties using the pullulan as a reactive filler

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Author(s):
Maia, Lana S. ; de Bomfim, Anne Shayene C. ; de Oliveira, Daniel M. ; Pinhati, Fernanda R. ; da Conceicao, Monique O. T. ; Barud, Hernane S. ; Medeiros, Simone A. ; Rosa, Derval S. ; Mulinari, Daniella R.
Total Authors: 9
Document type: Journal article
Source: Journal of Applied Polymer Science; v. N/A, p. 13-pg., 2023-01-19.
Abstract

This study aimed to evaluate the effect of pullulan (Pull) on a renewable polyurethane sponge-like scaffold synthesized from the Pull mixture with the castor oil-based polyol and the prepolymer using the situ foaming method. The Pull contents on the sponge-like are 5, 10, and 20 wt.%. The samples were evaluated by optical microscopy (OM), scanning electron microscopy (SEM), density, Fourier transform infrared spectroscopy (FTIR), contact angle, Thermogravimetry, X-ray diffraction analysis (XRD), and compression strength test, respectively. FTIR results indicated that Pull was hydrogen-bonded to PU foam chains and increased the sponge-like scaffolds density, inducing a decrease in average cell size compared to the pristine PU, confirming that they act as nucleating agents. The Pull addition improved PU foams' hydrophobicity and mechanical properties and caused a thermal stability median between Pull and pristine PU. Thus, all renewable sponge-like scaffolds were hydrophobics and presented appropriate mechanical behavior, exhibiting better physicochemical properties, and appearing as promising candidates for biomedical applications. (AU)

FAPESP's process: 19/04269-0 - Evaluation of novel polymer nanoparticles as potential carriers for simultaneous release of a photosensitising agent and an active chemotherapeutic agent
Grantee:Simone de Fátima Medeiros Sampaio
Support Opportunities: Regular Research Grants
FAPESP's process: 20/13703-3 - Environmentally friendly porous materials for the recovery and revaluation of metals reclaimed from contaminated water
Grantee:Derval dos Santos Rosa
Support Opportunities: Research Projects - Thematic Grants