| Full text | |
| Author(s): |
Martins Neto, Jose de Ribamar
;
Torresi, Roberto M.
;
Cordoba de Torresi, Susana I.
Total Authors: 3
|
| Document type: | Journal article |
| Source: | JOURNAL OF ELECTROANALYTICAL CHEMISTRY; v. 765, p. 7-pg., 2016-03-15. |
| Abstract | |
WO3 nanoplates were synthesized in non-aqueous solvent using a one-step process ultrasonic irradiation. The nanostructured morphology was maintained in the films prepared by electrophoretic deposition (EPD) process onto ITO substrates. Spectroelectrochemical experiments were carried out by using both, H2SO4 and a protic ionic liquid (PIL) N-methyl-pyrrolidinium tetrafluoroborate, electrolytes. Cyclic voltammograms (CVs) were combined with transmittance measurements for all films that undergo typical reversible color change from colorless to blue. The integrated cathodic current of intercalation/deintercalation was used to calculate the coloration efficiency (CE) of films; the value obtained being in good agreement with nanostructured WO3 films. The coloration/bleaching processes showed good color efficiency, fast coloration time and optical contrast in acid electrolytes. The results using PIL as electrolyte, instead of H2SO4, show that all electrochromic parameters were improved, including the cyclic durability that was higher in this medium. Therefore, the use of a PIL enables proton intercalation but no dissolution suggesting its use as a suitable electrolyte for electrochromic devices. (C) 2015 Elsevier B.V. All rights reserved. (AU) | |
| FAPESP's process: | 09/53199-3 - Molecular recognition and energy storage: fundamental studies concerning geometry, size and synthesis effects on the optimization of the chemical properties of electroactive materials |
| Grantee: | Roberto Manuel Torresi |
| Support Opportunities: | Research Projects - Thematic Grants |