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Recyclable Palladium Catalyst Supported on Dolomite for Dynamic Kinetic Resolution of (+/-)-1-Phenylethylamine

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Author(s):
Mendonca, Renata C. Z. ; Esteves, Laura M. ; Oliveira, Hugo A. ; de Lima, Sania M. ; de Siqueira, Fernanda A.
Total Authors: 5
Document type: Journal article
Source: CATALYSIS LETTERS; v. 152, n. 4, p. 10-pg., 2021-07-01.
Abstract

This work proposes a new selective palladium catalyst supported on dolomite to synthesize enantiomerically enriched N-[(R)-( +)-1-phenylethyl] amide. 2.5 wt.% Pd catalyst demonstrated high activity for reactions performed under mild conditions reaching a total enantiomeric excess up to 99%. It could be reused up to 5 cycles after the regeneration step. [GRAPHICS] . (AU)

FAPESP's process: 19/00641-2 - Studies on the kinetic dynamic chemoenzymatic resolution of alcohols and amines, aiming at the synthesis of enantiomerically pure molecules with potential biological activity.
Grantee:Fernanda Amaral de Siqueira
Support Opportunities: Regular Research Grants