The Acylation of α-Carbonyl Sulfoxonium Ylides with <i>N</i>-Hydroxyphthalimide Esters

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The Acylation of α-Carbonyl Sulfoxonium Ylides with N-Hydroxyphthalimide Esters

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Author(s):	Mizobuchi, Eduardo F. ; Burtoloso, Antonio C. B. Total Authors: 2
Document type:	Journal article
Source:	SYNTHESIS-STUTTGART; v. N/A, p. 8-pg., 2024-10-02.
Abstract
A new method for the synthesis of 1,3-dicarbonyl sulfoxonium ylides is described. This acylation reaction is carried out under mild conditions using inexpensive and bench-stable N -hydroxyphthalimide esters as acylating agents. The reactions proceed via a non-radical, transition-metal-free pathway, and the corresponding products are obtained in yields of up to 85%. (AU)

FAPESP's process:	20/15230-5 - Research Centre for Greenhouse Gas Innovation - RCG2I
Grantee:	Julio Romano Meneghini
Support Opportunities:	Research Grants - Research Centers in Engineering Program


FAPESP's process:	23/02675-7 - New methodologies to form C-C bonds from sulfoxonium ylides
Grantee:	Antonio Carlos Bender Burtoloso
Support Opportunities:	Regular Research Grants