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Optical and luminescent properties of Dy 3+/Sm 3+doped and codoped Zinc Borophosphate glasses for W-LED application

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Author(s):
Dantas, N. F. ; Melo, G. H. A. ; Lodi, T. A. ; Pedrochi, F. ; Steimacher, A.
Total Authors: 5
Document type: Journal article
Source: Journal of Luminescence; v. 270, p. 10-pg., 2024-03-14.
Abstract

In this work, a series of zinc borophosphate glasses (ZnPBAl), doped and codoped with Dy 3 + and Sm 3 + , was studied for potential application in W -LEDs. The samples were prepared by the melt -quenching method and their luminescent and optical properties were investigated. The optical absorption spectra presented all Dy 3 + and Sm 3 + peaks corresponding to the transitions from the 6 H 15/2 and 6 H 5/2 states, respectively, to the excited energy levels. The 350 nm excitation source was chosen, considering photoluminescence excitation (PLE) results, to investigate the energy transfer from Dy 3 + to Sm 3 + ions. The energy transfer was indicated by photoluminescence (PL) spectra of Dy:Sm-codoped glasses and investigated by the energy transfer efficiency (eta) using the lifetime data of both doped and codoped samples. The PL as a function of temperature was also studied. The CIE diagram of Dy-doped glasses showed their color emission close to the white region and the simulation of a combined Blue LED created an illumination route from warm to cold white light. (AU)

FAPESP's process: 23/01625-6 - Development of new methodologies for the manufacture of optical fibers from exotic glasses
Grantee:Marcelo Nalin
Support Opportunities: Regular Research Grants
FAPESP's process: 23/09906-4 - Development of new methodologies for the manufacture of optical fibers from exotic glasses
Grantee:Thiago Augusto Lodi
Support Opportunities: Scholarships in Brazil - Support Program for Fixating Young Doctors