A Reliable and Straightforward Combination of vortex-assisted Dispersive Magnetic solid-phase Extraction with Direct Sorbent Sampling for Highly Sensitive Silver Determination in Water Samples Using Flame and Metal Furnace AAS

Author(s)

dos Santos, Diego Prudencio ; Ferreira, Milena do Prado ; Diniz, Kristiany Moreira ; Segatelli, Mariana Gava ; de Figueiredo, Eduardo Costa ; Tarley, Cesar Ricardo Teixeira

• Document type: Journal article
• Source: Bulletin of Environmental Contamination and Toxicology; v. 113, n. 4, p. 9-pg., 2024-10-01.

Abstract

In the present paper, the assessment of vortex-assisted dispersive magnetic solid-phase extraction using amino-functionalized mesoporous combined with direct magnetic sorbent sampling (DMSS) in flame or furnace atomic absorption spectrometry (FAAS or FF-AAS) was demonstrated for highly sensitive silver determination in water samples. The developed method showed significant enrichment factors compared to conventional pneumatic nebulization by FAAS, 607 for DMSS-FF-AAS and 114 for DMSS-FAAS. The analytical curve showed linearity in the range from 5.0 to 70.0 mu g L- 1 and 1.0 to 15.0 mu g L- 1 and limits of detection of 0.59 and 0.09 mu g L- 1 for DMSS-FAAS and DMSS-FF-AAS, respectively. The intra and inter-day precision evaluated as a percentage of the relative standard deviation (RSD,%) ranged from 1.89 to 4.71% for levels of 25.0 and 65.0 mu g L- 1. The method was applied in different kinds of water samples without matrix effects, yielding recovery values from 90 to 110%. (AU)

• FAPESP's process: 14/50867-3 - INCT 2014: National Institute of Science and Technology in Bioanalysis
• Grantee: Marco Aurelio Zezzi Arruda
• Support Opportunities: Research Projects - Thematic Grants