Cross-linked cellulose beads as an eco-friendly support for ZnO/SnO2/ carbon xerogel hybrid photocatalyst: Exploring the synergy between adsorption and photocatalysis under simulated sunlight

Author(s)

de Moraes, Nicolas Perciani ; Pereira, Renan Amarante ; da Silva, Thiago Vieira Chicuta ; da Silva, Bruno Henrique Baena ; de Assis, Gabrielle Policarpo ; Campos, Tiago Moreira Bastos ; Thim, Gilmar Patrocinio ; Lanza, Marcos Roberto de Vasconcelos ; de Freitas, Larissa ; Rodrigues, Liana Alvares

• Document type: Journal article
• Source: International Journal of Biological Macromolecules; v. 254, p. 13-pg., 2023-11-08.

Abstract

This paper explores the application of cross-linked cellulose beads as a sustainable and cost-effective support for the ZnO/SnO2/carbon xerogel hybrid photocatalyst. The application of the developed photocatalytic beads, named CB-Cat, was directed at a simultaneous adsorption/photocatalysis process, which was carried out under simulated sunlight. The characterization of the CB-Cat indicated a good dispersion of the photocatalyst of choice throughout the cellulose matrix, confirming its incorporation into the cellulose beads. Furthermore, it is possible to observe the presence of the photocatalyst on the surface of the CB-Cat, confirming its availability for the photonic activation process. The results showed that the simultaneous adsorption/photocatalysis process was optimal for enhancing the efficiency of methylene blue (MB) removal, especially when compared to the isolated adsorption process. Additionally, the regeneration of the CB-Cat between cycles was favorable toward the maintenance of the MB removal efficiency, as the process carried out without regeneration displayed significant efficiency drops between cycles. Finally, the mechanism evaluation evidenced that hydroxyl and superoxide radicals were the main responsible for the MB photocatalytic degradation during illumination with simulated sunlight. (AU)

• FAPESP's process: 14/50945-4 - INCT 2014: National Institute for Alternative Technologies of Detection, Toxicological Evaluation and Removal of Micropollutants and Radioactivies
• Grantee: Maria Valnice Boldrin
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 18/16360-0 - Development of ZnO/Bi2O3/Carbon xerogel ternary composites as photocatalysts for the degradation of persistent organic pollutants
• Grantee: Nicolas Perciani de Moraes
• Support Opportunities: Scholarships in Brazil - Doctorate
• FAPESP's process: 18/10492-1 - Photocatalytic evaluation of heterojunctions semiconductor/ZnO/carbon xerogel in the photodegradation of 4-chlorophenol in both fluidized bed and batch reactors
• Grantee: Liana Alvares Rodrigues
• Support Opportunities: Regular Research Grants
• FAPESP's process: 17/10118-0 - Study and application of electrochemical technology for the analysis and degradation of endocrine interferents: materials, sensors, processes and scientific dissemination
• Grantee: Marcos Roberto de Vasconcelos Lanza
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 22/04058-2 - Photoelectrocatalytic degradation of pollutants (bisphenol-A, sulfamerazine, and 2,4-D) using H2O2 electrogenerated in carbonaceous matrices obtained from sustainable sources
• Grantee: Nicolas Perciani de Moraes
• Support Opportunities: Scholarships in Brazil - Post-Doctoral