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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Ether-Bond-Containing Ionic Liquids and the Relevance of the Ether Bond Position to Transport Properties

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Author(s):
Monteiro, Marcelo J. [1] ; Camilo, Fernanda F. [2] ; Ribeiro, Mauro C. C. [1] ; Torresi, Roberto M. [1]
Total Authors: 4
Affiliation:
[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo - Brazil
[2] Univ Fed Sao Paulo, Dept Ciencias Exatas & Terra, Diadema, SP - Brazil
Total Affiliations: 2
Document type: Journal article
Source: Journal of Physical Chemistry B; v. 114, n. 39, p. 12488-12494, OCT 7 2010.
Web of Science Citations: 59
Abstract

The ionic liquids (ILs) 1-ethoxyethyl-2,3-dimethylimidazolium bis(trifluoromethanesulfonyl)imide, {[}EtO-(CH(2))(2)MMI]{[}Tf(2)N], and N-(ethoxyethyl)-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, {[}EtO(CH(2))(2)MMor]{[}Tf(2)N] were synthesized, and relevant properties, such as thermal stability, density, viscosity, electrochemical behavior, ionic conductivity, and self-diffusion coefficients for both ionic species, were measured and compared with those of their alkyl counterparts, 1-n-butyl-2,3-dimethylimidazolium bis(trifluoromethanesulfonyl)imide, {[}BMMI]{[}Tf(2)N], and N-n-butyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide,{[}BMP]{[}Tf(2)N] and N-n-butyl-N-methylmorpholinium bis(trilfuoromethanesulfonyl)imide {[}BMMor]{[}Tf(2)N]{[}. This comparison was done to evaluate the effects caused by the presence of the ether bond in either the side chain or in the organic cation ring. The salt, LiTf(2)N, was added to the systems to estimate IL behavior with regard to lithium cation transport. Pure {[}EtO(CH(2))(2)MMI]{[}Tf(2)N] and their LiTf(2)N solutions showed low viscosity and the highest conductivity among the ILs studied. The H(R) (AC conductivity/NMR calculated conductivity ratio) values showed that, after addition of LiTf(2)N, ILs containing the ether bond seemed to have a greater number of charged species. Structural reasons could explain these high observed HR values for {[}EtO(CH(2))(2)MMor]{[}Tf(2)N]. (AU)