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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Investigation of new PPV-type polymeric materials containing fluorene and thiophene units and their application in organic solar cells

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Author(s):
de Freitas, Jilian Nei ; Pivrikas, Almantas [1] ; Nowacki, Bruno [2] ; Akcelrud, Leni C. [2] ; Sariciftci, N. Serdar [1] ; Nogueira, Ana Flavia [3]
Total Authors: 6
Affiliation:
[1] Johannes Kepler Univ Linz, Linz Inst Organ Solar Cells, A-4040 Linz - Austria
[2] Univ Fed Parana, LaPPS, BR-80060000 Curitiba, Parana - Brazil
[3] Univ Estadual Campinas, LNES, Inst Chem, BR-13083970 Campinas, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: Synthetic Metals; v. 160, n. 15-16, p. 1654-1661, AUG 2010.
Web of Science Citations: 11
Abstract

New poly(p-phenylenevinylene) (PPV)-type conducting polymers containing different concentrations of thiophene and fluorene functional units were investigated in this work and the photophysical and electrochemical properties were evaluated. We observed a dependence of these properties on the concentration of thiophene units in the polymer backbone. The hole mobilities were estimated to be on the order of 10(-6) cm(2) V(-1) s(-1). The polymers were combined with different concentrations of a soluble fullerene derivative (PCBM) and applied in bulk-heterojunction photovoltaic cells. The effects of PCBM concentration and of annealing (post-production treatment) on these devices were investigated. The best results were obtained for the materials containing higher concentrations of thiophene units. (C) 2010 Elsevier B.V. All rights reserved. (AU)