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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Chemical and spectroscopic studies of a new palladium(II) complex with N-acetyl-L-cysteine

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Author(s):
Corbi, P. P. [1, 2] ; Cagnin, F. [1] ; Massabni, A. C. [1]
Total Authors: 3
Affiliation:
[1] UNESP, Univ Estadual Paulista, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP - Brazil
[2] Centro Univ Araraquara, Ctr Univ Araraquara, Assoc Sao Bento de Ensino, Dept Ciencias Biol & Saude, BR-14801320 Araraquara, SP - Brazil
Total Affiliations: 2
Document type: Journal article
Source: Journal of Coordination Chemistry; v. 61, n. 22, p. 3666-3673, 2008.
Web of Science Citations: 4
Abstract

Chemical and spectroscopic studies of a new palladium(II) N-acetyl-L-cysteine complex are described. Elemental analyses for the solid complex are consistent with the formula {[}Pd(C(5)H(8)NO(3)S)(2)] H(2)O or {[}Pd(NAC)(2)] H(2)O. Solid-state (13)C nuclear magnetic resonance (NMR), UV-Visible (UV-Vis) and infrared (IR) spectroscopic analyses are consistent with coordination of the ligand to palladium(II) through the nitrogen and sulfur atoms in a square-planar geometry. Thermogravimetric and differential thermal analyses confirmed the composition; final residue was identified as metallic palladium. (AU)