Advanced search
Start date
Betweenand
Related content
(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Carbon support treatment effect on Ru/C catalyst performance for benzene partial hydrogenation

Full text
Author(s):
Zanutelo, Cristiane [1] ; Landers, Richard [2] ; Carvalho, Wagner Alves [3] ; Gomez Cobo, Antonio Jose [1]
Total Authors: 4
Affiliation:
[1] Univ Estadual Campinas, Sch Chem Engn, Dept Chem Syst Engn, Lab Dev Catalyt Proc, BR-13083852 Campinas, SP - Brazil
[2] Univ Estadual Campinas, Gleb Wataghin Inst Phys, Dept Appl Phys, Surface Phys Lab, BR-13083970 Campinas, SP - Brazil
[3] Univ Fed ABC, Ctr Ciencias Nat & Humanas, BR-09210170 Santo Andre, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: APPLIED CATALYSIS A-GENERAL; v. 409, p. 174-180, DEC 15 2011.
Web of Science Citations: 19
Abstract

Ru/C catalysts were prepared from commercial activated carbon submitted to different treatments. The catalysts were prepared by incipient wetness impregnation, through an aqueous solution of the precursor RuCl3 center dot xH(2)O. After impregnation, some catalysts were submitted to direct reduction treatment under H-2 flow at the temperature of 150 degrees C, in order to evaluate the effects of activation. The supports were characterized by N-2 adsorption, Boehm and potentiometric titration. The X-ray photoelectron spectroscopy was used to study the supports and catalysts surfaces, while scanning electron microscopy allowed us to determine the chemical composition and observe the catalysts morphology. Ru/C catalysts performance was evaluated within the hydrogenation reaction of benzene in liquid phase, using a Parr reactor. The reaction was conducted under total pressure of 5.0 MPa of H-2, at a temperature of 100 degrees C with water in the reaction medium. The obtained results indicate that the Ru/C system catalytic performance is influenced for determined functional groups present on the activated carbon surface. The carbonyl groups decrease the activity and selectivity of the reactions, while an increase of the carboxylic groups leads to more active catalysts and the highest yield of cyclohexene. (C) 2011 Elsevier B.V. All rights (AU)

FAPESP's process: 06/04142-0 - Hydrogenation of dimethyl adipate at presence of pillared clay based catalysts
Grantee:Wagner Alves Carvalho
Support Opportunities: Regular Research Grants