Chemometric tools in chemical fractionation data of soil samples from five antarctic research stations

Author(s)

Guerra, Marcelo B. B. ^[1] ; Rosa, Paula F. ^[1] ; Schaefer, Carlos E. G. R. ^{[2, 3]} ; Michel, Roberto F. M. ^{[2, 3, 4]} ; Almeida, Ivan C. ^{[2, 3]} ; Pereira-Filho, Edenir R. ^[1]

Affiliation

^[1] Univ Fed Sao Carlos, Dept Quim, Grp Anal Instrumental Aplicada, BR-13565905 Sao Carlos, SP - Brazil

^[2] Univ Cambridge, SPRI, Cambridge CB2 IER - England

^[3] Univ Fed Vicosa, Dept Ciencias Solo, BR-36570000 Vicosa, MG - Brazil

^[4] FEAM, BR-31630900 Belo Horizonte, MG - Brazil

• Document type: Journal article
• Source: Journal of the Brazilian Chemical Society; v. 23, n. 7, p. 1388+, JUL 2012.
• Web of Science Citations: 2

Abstract

The aim of this study was to carry out a broad chemical investigation of selected soil samples from Antarctica, near different Antarctic scientific stations. Soil samples collected in background reference sites, with minimal human impact, far away from the stations were used as control samples. Anthropogenic places at the vicinity of the following stations Frei Montalva and Escudero (Chile), Great Wall (China), Bellingshausen (Russia) and Artigas (Uruguay) were studied as a priori human impacted sites. The sequential extraction procedure (SEP) based on the BCR (Community Bureau of Reference) protocol was applied for Cu, Mn and Zn determination. With the help of PCA (principal component analysis) and PARAFAC (parallel factor analysis) methods, meaningful information was extracted from the raw data obtained from SEP procedure. Soil samples affected by the scientific stations are associated with higher heavy metal contents (especially Cu and Zn, between the investigated metals, in the most labile fractions of the SEP applied). This pollution signal is associated with diesel use for the energy generation by the Antarctic stations. (AU)

• FAPESP's process: 07/04515-4 - Combination of atomic absorption spectrometry with sequential determination and thermospray flame furnace atomic absorption spectrometry
• Grantee: Edenir Rodrigues Pereira Filho
• Support Opportunities: Regular Research Grants
• FAPESP's process: 09/09481-6 - Evaluation of cupper, manganese and zinc concentrations in Antartica soils using sequential extraction and chemometric tools
• Grantee: Paula de Freitas Rosa Remiro
• Support Opportunities: Scholarships in Brazil - Scientific Initiation
• FAPESP's process: 08/08260-3 - Chemical analyses of environmental samples from Antartica: spectrometric determination of Cd, Cr, Ni and Pb, use of micro X-Ray fluorescence with synchrotron radiation and application of chemometric tools
• Grantee: Marcelo Braga Bueno Guerra
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)