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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Correlation between hydrogen storage properties and textures induced in magnesium through ECAP and cold rolling

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Author(s):
Jorge, Jr., Alberto Moreira [1, 2, 3] ; de Lima, Gisele Ferreira [4] ; Martins Triques, Maria Regina [1] ; Botta, Walter Jose [1] ; Kiminami, Claudio Shyinti [1] ; Nogueira, Ricardo Pereira [3] ; Yavari, Alain Reza [2] ; Langdon, Terence G. [5, 6, 7]
Total Authors: 8
Affiliation:
[1] Univ Fed Sao Carlos, Dept Mat Engn, BR-13565905 Sao Carlos, SP - Brazil
[2] UJF, INPG, CNRS, SiMap Lab, UMR 5266, F-38402 St Martin Dheres - France
[3] UJF, INPG, CNRS, LEPMI, UMR 5279, F-38402 St Martin Dheres - France
[4] Univ Fed Sao Paulo, BR-12231280 Sao Jose Dos Campos, SP - Brazil
[5] Univ So Calif, Dept Aerosp & Mech Engn, Los Angeles, CA 90089 - USA
[6] Univ So Calif, Dept Mat Sci, Los Angeles, CA 90089 - USA
[7] Univ Southampton, Fac Engn & Environm, Mat Res Grp, Southampton SO17 1BJ, Hants - England
Total Affiliations: 7
Document type: Journal article
Source: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY; v. 39, n. 8, p. 3810-3821, MAR 6 2014.
Web of Science Citations: 28
Abstract

It is feasible to obtain a significant enhancement of the hydrogen storage capability in magnesium by selecting an appropriate sequence of mechanical processing. The Mg metal may be produced with different textures which will then give significant differences in the absorption/desorption kinetics and in the incubation times for hydrogenation. Using processing by equal-channel angular pressing (ECAP), different textures may be produced by changing both the numbers of passes through the ECAP die and the ram speed. Significant grain refinement is easily avoided by using commercial coarse-grained magnesium as the starting material. The use of cold rolling after ECAP further increases the preferential texture for hydrogenation. The results show that the hydriding properties are enhanced with a (002) texture where the improved kinetics lie mainly in the initial stages of hydrogenation. An incubation time is associated with the presence of a (101) texture and this is probably due to the magnesium oxide stability in this direction. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. (AU)

FAPESP's process: 11/51245-8 - Grain refinement and properties of ultrafine-grained AI, Mg and Ti alloys produced by equal-channel angular pressing with back-pressure
Grantee:Alberto Moreira Jorge Junior
Support Opportunities: Regular Research Grants