| Full text | |
| Author(s): |
Yeo, Chien Ing
[1]
;
Halim, Siti Nadiah Abdul
[1]
;
Ng, Seik Weng
[1]
;
Tan, Seng Lim
[1]
;
Zukerman-Schpector, Julio
[2]
;
Ferreira, Marco A. B.
[2]
;
Tiekink, Edward R. T.
[1]
Total Authors: 7
|
| Affiliation: | [1] Univ Malaya, Dept Chem, Kuala Lumpur 50603 - Malaysia
[2] Univ Fed Sao Carlos, Dept Quim, Lab Cristalog Estereodinam & Modelagem Mol, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 2
|
| Document type: | Journal article |
| Source: | CHEMICAL COMMUNICATIONS; v. 50, n. 45, p. 5984-5986, 2014. |
| Web of Science Citations: | 27 |
| Abstract | |
Evidence for C-H center dot center dot center dot pi( CuCl center dot center dot center dot HNCS) interactions, i.e. C-H center dot center dot center dot pi(quasichelate ring) where a six-membered quasi-chelate ring is closed by an N-H center dot center dot center dot Cl hydrogen bond, is presented based on crystal structure analyses of (Ph3P)(2)Cu{[}ROC(=S)N(H) Ph]Cl. Similar intramolecular interactions are identified in related literature structures. Calculations suggest that the energy of attraction provided by such interactions approximates 3.5 kcal mol(-1). (AU) | |
| FAPESP's process: | 13/02311-3 - New approaches in asymmetric synthesis of tetrahydrofuran and tetrahydropyran-derivatives with potential application in the preparation of bioactive molecules |
| Grantee: | Marco Antonio Barbosa Ferreira |
| Support Opportunities: | Regular Research Grants |