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(Reference retrieved automatically from SciELO through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Aromaticity: historical evolution of the concept and quantitative criteria

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Author(s):
Giovanni Finoto Caramori [1] ; Kleber Thiago de Oliveira [2]
Total Authors: 2
Affiliation:
[1] Universidade Federal de Santa Catarina. Centro de Ciências Físicas e Matemáticas. Departamento de Química - Brasil
[2] Universidade Federal do ABC. Centro de Ciências Naturais e Humanas - Brasil
Total Affiliations: 2
Document type: Journal article
Source: Química Nova; v. 32, n. 7, p. 1871-1884, 2009-00-00.
Abstract

In this paper the evolution of the concept of aromaticity is discussed. It considers not only historical aspects of the aromaticity concept but also the different criteria (theoretical and experimental) that have appeared to explain the properties of the aromatic compounds. The topics range from the isolation of benzene by Faraday (1825) until the modern criteria based on geometries, magnetic properties, resonance energy (RE), aromatic stabilization energy (ASE), topological analyses, and others. A chronological separation of issues concerning aromaticity was made, splitting the definitions before and after the appearance of the quantum chemistry. This work reviews the concept of aromaticity. (AU)

FAPESP's process: 07/04379-3 - Potential action of Isatin-Schiff base complexes and derivatives on oxidative stress: a chemical bond study
Grantee:Giovanni Finoto Caramori
Support Opportunities: Scholarships in Brazil - Post-Doctoral