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Interactions between macromolecules and surfaces

Grant number: 10/51219-4
Support Opportunities:Regular Research Grants
Start date: July 01, 2010
End date: June 30, 2012
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
Principal Investigator:Denise Freitas Siqueira Petri
Grantee:Denise Freitas Siqueira Petri
Host Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil

Abstract

Understanding the fundamental physical chemistry aspects that control the interactions between macromolecules and surfaces is the main goal of this project. It is strategically organized in five modules. Module 1 aims at the dependence of surface energy on the solvent used for cellulose and hemicellulose film formation and how it correlates with cell adhesion. Formation and characterization of cellulose derivatives films will be performed in the Module 2, as well as the evaluation of the effect of functional group on the surface energy of cellulose and cellulose derivatives. Adsorption behavior of proteins and enzymes on polysaccharide films will be studied in the Module 3 and will be correlated with surface energy values determined in the Modules 1 and 2. The Module 4 aims at comprehending the effect of structural aspects of polycations on the complexation with uncharged or negatively charged surfactants and the complexes biocidal activity. In the Module 5 Interactions between proteins and polyelectrolytes or monosaccharides at the liquid-air interface will be investigated. (AU)

Articles published in Agência FAPESP Newsletter about the research grant:
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VEICULO: TITULO (DATA)
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Scientific publications (11)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
DOMINGUES, AMANDA A.; PEREIRA, FABIANO V.; SIERAKOWSKI, MARIA RITA; ROJAS, ORLANDO J.; PETRI, DENISE F. S.. Interfacial properties of cellulose nanoparticles obtained from acid and enzymatic hydrolysis of cellulose. Cellulose, v. 23, n. 4, p. 2421-2437, . (10/51219-4, 13/03480-3)
DAMATO, TATIANA CARDOSO; CARRASCO, LETICIA D. M.; CARMONA-RIBEIRO, ANA MARIA; LUIZ, RICARDO VAGNER; GODOY, ROBERTA; PETRI, DENISE F. S.. The interactions between surfactants and the epicuticular wax on soybean or weed leaves: Maximal crop protection with minimal wax solubilization. CROP PROTECTION, v. 91, p. 57-65, . (10/51219-4)
AMIM, JR., JORGE; PETRI, DENISE F. S.. Effect of amino-terminated substrates onto surface properties of cellulose esters and their interaction with lectins. Materials Science & Engineering C-Materials for Biological Applications, v. 32, n. 2, p. 348-355, . (10/51219-4)
OGEDA, THAIS L.; SILVA, IGOR B.; FIDALE, LUDMILA C.; EL SEOUD, OMAR A.; PETRI, DENISE F. S.. Effect of cellulose physical characteristics, especially the water sorption value, on the efficiency of its hydrolysis catalyzed by free or immobilized cellulase. Journal of Biotechnology, v. 157, n. 1, p. 246-252, . (10/51219-4)
BUENO, VANIA BLASQUES; SILVA, ANIELLE MARTINS; SOUZA BARBOSA, LEANDRO RAMOS; CATALANI, LUIZ HENRIQUE; TEIXEIRA-NETO, ERICO; CORNEJO, DANIEL REINALDO; SIQUEIRA PETRI, DENISE FREITAS. Hybrid composites of xanthan and magnetic nanoparticles for cellular uptake. CHEMICAL COMMUNICATIONS, v. 49, n. 85, p. 9911-9913, . (10/51219-4, 10/13034-2)
BLACHECHEN, LEANDRO S.; SILVA, JAQUELINE O.; BARBOSA, LEANDRO R. S.; ITRI, ROSANGELA; PETRI, DENISE F. S.. Hofmeister effects on the colloidal stability of poly(ethylene glycol)-decorated nanoparticles. COLLOID AND POLYMER SCIENCE, v. 290, n. 15, p. 1537-1546, . (10/51219-4)
OLIVEIRA, ALLAN M.; MIRANDA, PAULO B.; PETRI, DENISE F. S.. Self-Assembly of Poly(4-vynil-N-alkylpyridinium) Bromide onto Silica: Effect of Side-Chain Length on Structural Aspects at a Molecular Level. Journal of Physical Chemistry C, v. 116, n. 34, p. 18284-18291, . (10/51219-4, 09/16999-1)
BARRIOS, NELSON; PATINO-AGUDELO, ALVARO JAVIER; QUINA, FRANK HERBERT; SALAS, CARLOS; PEREIRA, JUAN. Specific anion effects on the interfacial properties and aggregation of alkylphenol ethoxylate surfactants. JOURNAL OF MOLECULAR LIQUIDS, v. 363, p. 9-pg., . (10/51219-4)
NUKUI, LARISSA H. N.; BARBOSA, LEANDRO R. S.; PETRI, DENISE F. S.. Impact of Monovalent and Divalent Cations on the Colloidal Stability of Negatively Charged Latex Particles Decorated with Poly(ethylene glycol). Industrial & Engineering Chemistry Research, v. 55, n. 3, p. 606-614, . (10/51219-4, 12/25096-8)
AMIM, JR., JORGE; MAIA, FRANCISCO C. B.; MIRANDA, PAULO B.; URZUA, MARCELA D.; PETRI, DENISE F. S.. Structural aspects of polyanion and hydrophobically modified polycation multilayers on hydrophilic or hydrophobic surfaces. SOFT MATTER, v. 8, n. 24, p. 6462-6470, . (10/51219-4)
STAUNER, THOMAS; SILVA, IGOR B.; EL SEOUD, OMAR A.; FROLLINI, ELISABETE; PETRI, DENISE F. S.. Cellulose loading and water sorption value as important parameters for the enzymatic hydrolysis of cellulose. Cellulose, v. 20, n. 3, p. 1109-1119, . (10/51219-4)