Multicomponent polymeric materials

• Grant number: 10/02098-0
• Support Opportunities: Regular Research Grants
• Duration: July 01, 2010 - June 30, 2012
• Field of knowledge: Physical Sciences and Mathematics - Chemistry
• Principal Investigator: Maria Isabel Felisberti
• Grantee: Maria Isabel Felisberti
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

This project aims to develop multicomponent polymeric materials such as copolymers, blends, composites and nanocomposites. The diversity and versatility of applications of these materials are due to the variety of the properties of their components as well as the methods used to prepare or to synthesize them. The appropriated selection of the components can result in polymeric materials with controlled and designed properties. In this context different projects have been developed in my research group: A. Synthesis of amphiphilic and water soluble copolymers by radical copolymerization of sacarose monomers or macromers from vegetal oil (both synthesized by the research group) or by (co)polymerization via ring opening polymerization (ROP) of lactones and cyclic carbonates; B. Preparation and characterization of tough blends and nanocomposites based on thermoplastics and clays; C. Preparation and characterization of composites based on biodegradable thermoplastic and natural fibers.The results obtained in these studies should allow to establishing relationships among structure and composition of materials with their properties. With this knowledge the team will be able to optimize the performance of the systems to produce polymeric materials of interest to the market. (AU)

Scientific publications

(12)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

TRINCA, RAFAEL BERGAMO; FELISBERTI, MARIA ISABEL. Segmented polyurethanes based on poly(L-lactide), poly(ethylene glycol) and poly(trimethylene carbonate): Physico-chemical properties and morphology. EUROPEAN POLYMER JOURNAL, v. 62, n. SI, p. 77-86, JAN 2015. (10/17804-7, 10/02098-0, 11/09479-1)

TRINCA, RAFAEL BERGAMO; FELISBERTI, MARIA ISABEL. Effect of diisocyanates and chain extenders on the physicochemical properties and morphology of multicomponent segmented polyurethanes based on poly(l-lactide), poly(ethylene glycol) and poly(trimethylene carbonate). Polymer International, v. 64, n. 10, p. 1326-1335, OCT 2015. (10/17804-7, 10/02098-0, 11/09479-1)

TRINCA, RAFAEL BERGAMO; FELISBERTI, MARIA ISABEL. Influence of the Synthesis Conditions on the Structural and Thermal Properties of Poly( L- lactide)- b- Poly( ethylene glycol)- b- Poly( L- lactide). Journal of Applied Polymer Science, v. 131, n. 13, JUL 5 2014. (10/17804-7, 08/07157-4, 10/02098-0, 11/09479-1)

DA CONCEICAO, THIAGO FERREIRA; FELISBERTI, MARIA ISABEL. The Influence of Rigid and Flexible Monomers on the Physical-Chemical Properties of Polyimides. Journal of Applied Polymer Science, v. 131, n. 24, p. 10-pg., 2014-12-15. (10/17804-7, 10/02098-0, 10/18268-1)

DA CONCEICAO, THIAGO FERREIRA; FELISBERTI, MARIA ISABEL. The Influence of Rigid and Flexible Monomers on the Physical-Chemical Properties of Polyimides. Journal of Applied Polymer Science, v. 131, n. 24, SI, DEC 15 2014. (10/17804-7, 10/02098-0, 10/18268-1)

DE CARVALHO, FABIANA PIRES; GONCALVES, MARIA DO CARMO; FELISBERTI, MARIA ISABEL. Effect of in situ polymerization conditions of methyl methacrylate on the structural and morphological properties of poly(methyl methacrylate)/poly(acrylonitrile-g-(ethylene-co-propylene-co-diene)-g-st yrene) PMMA/AES Blends. Journal of Applied Polymer Science, v. 124, n. 4, p. 2846-2856, MAY 15 2012. (10/02098-0)

TRINCA, RAFAEL BERGAMO; ABRAHAM, GUSTAVO A.; FELISBERTI, MARIA ISABEL. Electrospun nanofibrous scaffolds of segmented polyurethanes based on PEG, PLLA and PTMC blocks: Physico-chemical properties and morphology. Materials Science & Engineering C-Materials for Biological Applications, v. 56, p. 511-517, NOV 1 2015. (10/17804-7, 10/02098-0, 11/09479-1)

ALEXANDRINO, EVANDRO M.; DA CONCEICAO, THIAGO F.; FELISBERTI, MARIA I.. Improvement of Processing and Mechanical Properties of Polyetherimide by Antiplasticization with Resorcinol Bis(diphenyl phosphate). Journal of Applied Polymer Science, v. 131, n. 16, AUG 15 2014. (10/17804-7, 10/02098-0, 10/03383-0, 10/18268-1)

GUTIERREZ, MIGUEL CHAVEZ; DE PAOLI, MARCO-AURELIO; FELISBERTI, MARIA ISABEL. Cellulose acetate and short curaua fibers biocomposites prepared by large scale processing: Reinforcing and thermal insulating properties. INDUSTRIAL CROPS AND PRODUCTS, v. 52, p. 363-372, JAN 2014. (10/17804-7, 10/02098-0)

DE OLIVEIRA, HEITOR F. N.; FELISBERTI, MARIA ISABEL. Amphiphilic copolymers of sucrose methacrylate and acrylic monomers: Bio-based materials from renewable resource. Carbohydrate Polymers, v. 94, n. 1, p. 317-322, APR 15 2013. (10/17804-7, 10/02098-0)

TRINCA, RAFAEL BERGAMO; FELISBERTI, MARIA ISABEL. Segmented polyurethanes based on poly(L-lactide), poly(ethylene glycol) and poly(trimethylene carbonate): Physico-chemical properties and morphology. EUROPEAN POLYMER JOURNAL, v. 62, p. 10-pg., 2015-01-01. (11/09479-1, 10/17804-7, 10/02098-0)

DE CARVALHO, FABIANA PIRES; GONCALVES, MARIA DO CARMO; FELISBERTI, MARIA ISABEL. Effect of in situ polymerization conditions of methyl methacrylate on the structural and morphological properties of poly(methyl methacrylate)/poly(acrylonitrile-g-(ethylene-co-propylene-co-diene)-g-styrene) PMMA/AES Blends. Journal of Applied Polymer Science, v. 124, n. 4, p. 11-pg., 2012-05-15. (10/02098-0)