Use of the europium III to reveal structure of the matrices obtained by sol-gel methodology

• Grant number: 11/09823-4
• Support Opportunities: Regular Research Grants
• Start date: September 01, 2011
• End date: February 28, 2014
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Eduardo José Nassar
• Grantee: Eduardo José Nassar
• Host Institution: Reitoria. Universidade de Franca (UNIFRAN). Franca , SP, Brazil

Abstract

In the last decade, the nanotechnology has been explored in several area of the knowledge, this is promote the necessity of study and preparation materials nanostructured for specify applications. The preparation these materials involve different methodologies of the synthesis and use a several technique of characterization. Some example can be cite of the nanostructure materials as bucky ball C60, carbon nanotube, semiconductors, porous materials, biomaterials, phosphorus, catalyst, and others. The sol-gel methodology is an important technology has been used to prepare these nanostructured materials, several groups in the Brazil and the world have studied these technology. Our group has utilized the sol-gel process since its foundation at 12 years ago, in the preparation of the materials to application in catalysis, phosphors, glass, biomaterials, surface fictionalization and coatings. In all materials is necessary to know the structure or nanostructure for defined the application. The rare earths ions, mainly europium III ion, due to its spectroscopy properties, can be used as tools to study molecular structure. The emission spectra of the ion can be helper in the study of matrix structure. The proposal of this project is to support the several research line of the sol-gel group, to reveal the structure and nanostructure of the materials obtained by sol-gel hydrolytic and non-hydrolytic methodology, using the emission spectra of the europium III ion to using in specify applications these materials. Other technique will be use to characterization of the materials. (AU)

Scientific publications

(11)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

MARCELA G. MATOS; EMERSON H. DE FARIA; KATIA J. CIUFFI; LUCAS A. ROCHA; EDUARDO J. NASSAR; MARC VERELST. EFEITO DA CONCENTRAÇÃO DOS ÍONS Eu3+ E Bi3+ NAS PROPRIEDADES FOTOLUMINESCENTE DA MATRIZ DE YVO4. Química Nova, v. 41, n. 8, p. 849-856, 2018-08-00. (11/20313-8, 11/09823-4, 12/11673-3)

TANAKA, JULIO TADASHI; MOSCARDINI, SUSANE BONAMIN; DO NASCIMENTO MELO, WILLIAN EURIPEDES; BRUNCKOVA, HELENA; NASSAR, EDUARDO JOSE; ROCHA, LUCAS ALONSO. NIR Luminescence Enhancement of YVO4:Nd Phosphor for Biological Application. Journal of Fluorescence, v. 31, n. 1, NOV 2020. (11/09823-4)

MATOS, MARCELA G.; ROCHA, LUCAS A.; NASSAR, EDUARDO J.; VERELST, MARC. Influence of Bi3+ ions on the excitation wavelength of the YVO4:Eu3+ matrix. Optical Materials, v. 62, p. 12-18, DEC 2016. (12/11673-3, 11/09823-4, 11/20313-8)

AZEVEDO, CAROLINE B.; BATISTA, TULIO M.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Nanospherical Silica as Luminescent Markers Obtained by Sol-Gel. Journal of Fluorescence, v. 25, n. 2, p. 433-440, MAR 2015. (12/11673-3, 11/15199-1, 11/09823-4)

BARBOSA, LORRANA VIETRO; CASTRO, MONA STEFANY DE SOUZA; CIUFFI, KATIA JORGE; NASSAR, EDUARDO J.; MARCAL, LIZIANE; PEREIRA, LORENA RODRIGUES; SANTOS, MARIO FERREIRA CONCEICAO; AMBROSIO, SERGIO RICARDO; GOMES, PIETRA STEFANY DA SILVA; NOGUEIRA, FLAVIA APARECIDA RESENDE; et al. Kaolinite-titanium nanocomposite applied to the photodegradation of the genotoxic compound cisplatin and the terephthalic acid hydroxylation reaction. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, v. 676, p. 12-pg., 2023-11-05. (17/15482-1, 18/05080-6, 18/25010-2, 11/09823-4, 17/16278-9, 11/09823-4, 19/26439-5, 20/06712-6, 16/01501-1)

MIURA, BARBARA A.; FERREIRA, NATALIA H.; OLIVEIRA, POLLYANNA F.; DE FARIA, EMERSON H.; TAVARES, DENISE C.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Functionalization of luminescent YVO4:Eu3+ nanoparticles by sol-gel. Journal of Luminescence, v. 159, p. 93-99, MAR 2015. (12/24427-0, 11/21310-2, 12/11673-3, 11/09823-4, 11/15757-4)

SALTARELLI, MICHELLE; MATOS, MARCELA G.; DE FARIA, EMERSON H.; CIUFFI, KATIA J.; ROCHA, LUCAS A.; NASSAR, EDUARDO J.. Preparation of YVO4:Eu3+ at low temperature by the hydrolytic sol-gel methodology. Journal of Sol-Gel Science and Technology, v. 73, n. 2, p. 283-292, FEB 2015. (12/11673-3, 11/09823-4, 11/20313-8)

MATIAS, CARLOS R.; NASSAR, EDUARDO J.; VERELST, MARC; ROCHA, LUCAS A.. Synthesis and Characterization of Nb2O5:La3+,Eu3+ Phosphors Obtained by the Non-Hydrolytic Sol-Gel Process. Journal of the Brazilian Chemical Society, v. 26, n. 12, p. 2558-2570, DEC 2015. (11/15757-4, 11/09823-4, 12/11673-3)

MATOS, MARCELA G.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; CALEFI, PAULO S.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.; VITORINO SARMENTO, VICTOR HUGO. Synthesis and photoluminescent properties of yttrium vanadate phosphor prepared by the non-hydrolytic sol-gel process. Journal of Luminescence, v. 147, p. 190-195, MAR 2014. (12/11673-3, 11/09823-4, 11/20313-8)

PEREIRA, PAULA F. S.; MATOS, MARCELA G.; FERREIRA, CAMILA M. A.; DE FARIA, EMERSON H.; CALEFI, PAULO S.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Aluminate matrix doped with Tm3+/Tb3+/Eu3+ obtained by non-hydrolytic sol-gel route: White light emission. Journal of Luminescence, v. 146, p. 394-397, FEB 2014. (12/11673-3, 12/20908-4, 11/09823-4, 11/20313-8)

SOTILES, ANNE RAQUEL; BARBOSA, LORRANA VIETRO; VEDOVATO, YAN PITA; WYPYCH, FERNANDO; FARIA, EMERSON HENRIQUE DE. Effect of Zn2Cr layered double hydroxide on photocatalytic hydroxylation of terephthalic acid and photodegradation of sodium diclofenac. CATALYSIS TODAY, v. 423, p. 11-pg., 2023-11-01. (17/15482-1, 11/09823-4)