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Study on selectivity of hydrogenolysis / reductive hydrogenation processes of sugarcane bagasse under supercritical state catalyzed by structured metal oxides

Grant number: 13/23886-4
Support type:Program for Research on Bioenergy (BIOEN) - Regular Program Grants
Duration: April 01, 2014 - September 30, 2016
Field of knowledge:Physical Sciences and Mathematics - Chemistry
Principal Investigator:Mauricio Boscolo
Grantee:Mauricio Boscolo
Home Institution: Instituto de Biociências, Letras e Ciências Exatas (IBILCE). Universidade Estadual Paulista (UNESP). Campus de São José do Rio Preto. São José do Rio Preto , SP, Brazil

Abstract

The development of strategies for selective catalytic depolymerization and deoxygenation of lignocellulosic biomass is a challenge due to its complex structure, especially due to the recalcitrant behavior of lignin in relation to the hydrolysis of its phenolic ethers. The proposed research focuses on the synthesis and characterization of solid structured metal oxides catalysts derived from hydrotalcites with a formula of Mg6Al2(CO3)(OH)16.4(H2O) and doped with different transition elements (Cu, Zn, Fe, Nb, Ni, Zn, Mo, Ti, Zr), and lanthanides (La and Lu ) for the deconstruction of lignocellulosic material by means of conventional catalytic hydrogenation and hydrogenolysis using as hydrogen source (methanol or ethanol) through their respective reforms in their supercritical state (250 to 300oC and pressures above 62 atm). Using sugarcane bagasse as a substrate, we expect obtain lignin phenolic monomer units as well as their derivatives with different levels of saturation, including alcohols derived from cellulose and hemicellulose for use as fuel or for chemical intermediates. (AU)

Scientific publications (13)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
SIQUEIRA, MARCOS RECHI; PERRONE, OLAVO MICALI; METZKER, GUSTAVO; DE OLIVEIRA LISBOA, DANIELA CORREA; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Highly selective 1-butanol obtained from ethanol catalyzed by mixed metal oxides: Reaction optimization and catalyst structure behavior. MOLECULAR CATALYSIS, v. 476, OCT 2019. Web of Science Citations: 0.
MODENES-JUNIOR, MARCO A.; ZITO, CECILIA A.; PERFECTO, TARCISIO M.; VOLANTI, DIOGO P. Ethanol detection using composite based on reduced graphene oxide and CuO hierarchical structure under wet atmosphere. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, v. 248, SEP 2019. Web of Science Citations: 0.
SANTANA, ANA P. R.; ANDRADE, DANIEL F.; MORA-VARGAS, JORGE A.; AMARAL, CLARICE D. B.; OLIVEIRA, ANDREA; GONZALEZ, MARIO H. Natural deep eutectic solvents for sample preparation prior to elemental analysis by plasma-based techniques. Talanta, v. 199, p. 361-369, JUL 1 2019. Web of Science Citations: 1.
ZITO, CECILIA A.; PERFECTO, TARCISIO M.; OLIVEIRA, TAIS N. T.; VOLANTI, DIOGO P. Bicone-like ZnO structure as high-performance butanone sensor. Materials Letters, v. 223, p. 142-145, JUL 15 2018. Web of Science Citations: 0.
ZITO, CECILIA A.; PERFECTO, TARCISIO M.; FONSECA, CRISTIANE S.; VOLANTI, DIOGO P. Effective reduced graphene oxide sheets/hierarchical flower-like NiO composites for methanol sensing under high humidity. NEW JOURNAL OF CHEMISTRY, v. 42, n. 11, p. 8638-8645, JUN 7 2018. Web of Science Citations: 5.
PERFECTO, TARCISIO M.; ZITO, CECILIA A.; MAZON, TALITA; VOLANTI, DIOGO P. Flexible room-temperature volatile organic compound sensors based on reduced graphene oxide-WO3 center dot 0.33H(2)O nano-needles. JOURNAL OF MATERIALS CHEMISTRY C, v. 6, n. 11, p. 2822-2829, MAR 21 2018. Web of Science Citations: 6.
ZITO, CECILIA A.; PERFECTO, TARCISIO M.; VOLANTI, DIOGO P. Palladium-Loaded Hierarchical Flower-like Tin Dioxide Structure as Chemosensor Exhibiting High Ethanol Response in Humid Conditions. ADVANCED MATERIALS INTERFACES, v. 4, n. 22 NOV 23 2017. Web of Science Citations: 9.
MARCELO MANCINI; ADONIS COELHO; OLAVO M. PERRONE; JOÃO C. THOMEO; MAURICIO BOSCOLO. ÓXIDOS METÁLICOS DERIVADOS DE MATERIAIS TIPO HIDROTALCITAS CONTENDO Ga3+ COMO CATALISADORES PARA SÍNTESE DE BIODIESEL ETÍLICO. Química Nova, v. 40, n. 5, p. 528-533, Jun. 2017.
ZITO, CECILIA A.; PERFECTO, TARCISIO M.; VOLANTI, DIOGO P. Impact of reduced graphene oxide on the ethanol sensing performance of hollow SnO2 nanoparticles under humid atmosphere. SENSORS AND ACTUATORS B-CHEMICAL, v. 244, p. 466-474, JUN 2017. Web of Science Citations: 42.
COELHO, ADONIS; PERRONE, OLAVO MICALI; GOMES, ELENI; DA-SILVA, ROBERTO; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Mixed metal oxides from sucrose and cornstarch templated hydrotalcite-like LDHs as catalysts for ethyl biodiesel synthesis. APPLIED CATALYSIS A-GENERAL, v. 532, p. 32-39, FEB 25 2017. Web of Science Citations: 11.
DE SOUZA MORETTI, MARCIA MARIA; PERRONE, OLAVO MICALI; CARREIRA NUNES, CHRISTIANE DA COSTA; TABOGA, SEBASTIAO; BOSCOLO, MAURICIO; DA SILVA, ROBERTO; GOMES, ELENI. Effect of pretreatment and enzymatic hydrolysis on the physical-chemical composition and morphologic structure of sugarcane bagasse and sugarcane straw. Bioresource Technology, v. 219, p. 773-777, NOV 2016. Web of Science Citations: 16.
PERFECTO, T. M.; ZITO, C. A.; VOLANTI, D. P. Room-temperature volatile organic compounds sensing based on WO3 center dot 0.33H(2)O, hexagonal-WO3, and their reduced graphene oxide composites. RSC ADVANCES, v. 6, n. 107, p. 105171-105179, 2016. Web of Science Citations: 15.

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