Hydrotalcites containing Ag, Cu, Ni, Fe, La or Nb as catalysts for dehydrogenation of ethanol and hydrogenation of sugar cane bagasse

• Grant number: 15/11588-4
• Support Opportunities: Scholarships in Brazil - Doctorate
• Effective date (Start): September 01, 2015
• Effective date (End): August 31, 2019
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Mauricio Boscolo
• Grantee: Olavo Micali Perrone
• Host Institution: Instituto de Biociências, Letras e Ciências Exatas (IBILCE). Universidade Estadual Paulista (UNESP). Campus de São José do Rio Preto. São José do Rio Preto , SP, Brazil
• Associated scholarship(s): 16/15575-7 - Synthesis of organic carbonates from CO2 and ethanol-Guerbet compounds catalyzed by Cu-hydrotalcites modified with Ag+, Ni2+, Fe3+, La3+ or Nb5+., BE.EP.DR

Abstract

Development of strategies catalytic and selective for depolymerization and deoxygenation of lignocellulosic biomass is challenging due to complex structure of lignocellulosic material, particularly for recalcitrant of lignin owing to the hydrolysis of its phenolic ethers. The proposed research aims to design synthesis and characterization of solid catalysts derived from hydrotalcite composed of oxides whose general formula is Mg6Al2 (CO3)(OH)16*4(H2O) containing the modifying elements Ag, Cu, Fe, La, Nb or Ni applied in the reform of ethanol for the production of H2 in supercritical state at temperatures ranging from 280 to 320ºC with pressures above 62 atm. As a result of dehydrogenation of ethanol, a variety of value-added secondary compounds are formed via a process called Guerbet reaction whose products are also investigated in terms of the selectivity of the catalysts. Along with this process, it will investigate the deconstruction of lignocellulosic material (bagasse) by catalytic hydrogenation, in the same reactor, using the H2 generated in the reforming of ethanol, which results in phenolic monomeric units derived from lignin with different levels of saturation and oxygenation, and cellulose and hemicellulose derivatives alcohols for use as fuel or intermediates for the chemical industry. (AU)

Scientific publications

(7)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

SIQUEIRA, MARCOS RECHI; PERRONE, OLAVO MICALI; METZKER, GUSTAVO; DE OLIVEIRA LISBOA, DANIELA CORREA; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Highly selective 1-butanol obtained from ethanol catalyzed by mixed metal oxides: Reaction optimization and catalyst structure behavior. MOLECULAR CATALYSIS, v. 476, OCT 2019. (16/15575-7, 17/13230-5, 92/03515-3, 15/11588-4, 13/23886-4)

ROSSI, JESSIKA DE SOUZA; PERRONE, OLAVO MICALI; SIQUEIRA, MARCOS RECHI; VOLANTI, DIOGO PASCHOALINI; GOMES, ELENI; DA-SILVA, ROBERTO; BOSCOLO, MAURICIO. Effect of lanthanide ion doping on Mg-Al mixed oxides as active acid-base catalysts for fatty acid ethyl ester synthesis. RENEWABLE ENERGY, v. 133, p. 367-372, APR 2019. (14/20504-6, 15/11588-4)

ORTEGA, JULIETH ORDUNA; MORA VARGAS, JORGE ANDRES; PERRONE, OLAVO MICALI; METZKER, GUSTAVO; GOMES, ELENI; DA SILVA, ROBERTO; BOSCOLO, MAURICIO. Soaking and ozonolysis pretreatment of sugarcane straw for the production of fermentable sugars. INDUSTRIAL CROPS AND PRODUCTS, v. 145, MAR 2020. (10/12624-0, 17/13230-5, 17/09520-8, 15/11588-4)

PERRONE, OLAVO MICALI; SIQUEIRA, MARCOS RECHI; METZKER, GUSTAVO; DE OLIVEIRA LISBOA, DANIELA CORREA; BOSCOLO, MAURICIO. Copper and lanthanum mixed oxides as catalysts for ethanol Guerbet coupling: The role of La3+ on the production of long-chain alcohols. ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, v. 40, n. 2, MAR 2021. (16/15575-7, 17/13230-5, 15/11588-4)

COELHO, ADONIS; PERRONE, OLAVO MICALI; GOMES, ELENI; DA-SILVA, ROBERTO; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Mixed metal oxides from sucrose and cornstarch templated hydrotalcite-like LDHs as catalysts for ethyl biodiesel synthesis. APPLIED CATALYSIS A-GENERAL, v. 532, p. 32-39, FEB 25 2017. (15/22954-1, 13/23886-4, 15/11588-4)

ORDUNA ORTEGA, JULIETH; MORA VARGAS, JORGE ANDRES; METZKER, GUSTAVO; GOMES, ELENI; DA SILVA, ROBERTO; BOSCOLO, MAURICIO. Enhancing the production of the fermentable sugars from sugarcane straw: A new approach to applying alkaline and ozonolysis pretreatments. RENEWABLE ENERGY, v. 164, p. 502-508, FEB 2021. (14/02080-4, 17/13230-5, 15/11588-4, 17/09520-8, 10/12624-0)

GUEBARA, PAMELA F.; PERRONE, OLAVO M.; SIQUEIRA, MARCOS R.; MANCINI, MARCELO; DA-SILVA, ROBERTO; GOMES, ELENI; BOSCOLO, MAURICIO. Metal Oxides Derived from Modified Hydromagnesite: Evaluation of Their Catalytic Activity in the Synthesis of Ethyl Biodiesel. CHEMISTRYSELECT, v. 4, n. 34, p. 10202-10207, SEP 13 2019. (17/13230-5, 15/11588-4)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

PERRONE, Olavo Micali. Hydrotalcites containing Ag, Cu, Ni, Fe, La or Nb as catalysts for ethanol dehydrogenation and sugarcane bagasse hydrogenation. 2019. Doctoral Thesis - Universidade Estadual Paulista (Unesp). Instituto de Biociências Letras e Ciências Exatas. São José do Rio Preto São José do Rio Preto.