Study on selectivity of hydrogenolysis / reductive hydrogenation processes of sugarcane bagasse under supercritical state catalyzed by structured metal oxides

• Grant number: 13/23886-4
• Support Opportunities: Program for Research on Bioenergy (BIOEN) - Regular Program Grants
• Start date: April 01, 2014
• End date: September 30, 2016
• Field of knowledge: Physical Sciences and Mathematics - Chemistry
• Principal Investigator: Mauricio Boscolo
• Grantee: Mauricio Boscolo
• Host Institution: Instituto de Biociências, Letras e Ciências Exatas (IBILCE). Universidade Estadual Paulista (UNESP). Campus de São José do Rio Preto. São José do Rio Preto , SP, Brazil
• City of the host institution: São José do Rio Preto

Abstract

The development of strategies for selective catalytic depolymerization and deoxygenation of lignocellulosic biomass is a challenge due to its complex structure, especially due to the recalcitrant behavior of lignin in relation to the hydrolysis of its phenolic ethers. The proposed research focuses on the synthesis and characterization of solid structured metal oxides catalysts derived from hydrotalcites with a formula of Mg6Al2(CO3)(OH)16.4(H2O) and doped with different transition elements (Cu, Zn, Fe, Nb, Ni, Zn, Mo, Ti, Zr), and lanthanides (La and Lu ) for the deconstruction of lignocellulosic material by means of conventional catalytic hydrogenation and hydrogenolysis using as hydrogen source (methanol or ethanol) through their respective reforms in their supercritical state (250 to 300oC and pressures above 62 atm). Using sugarcane bagasse as a substrate, we expect obtain lignin phenolic monomer units as well as their derivatives with different levels of saturation, including alcohols derived from cellulose and hemicellulose for use as fuel or for chemical intermediates. (AU)

Scientific publications

(18)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

SANTANA, ANA P. R.; ANDRADE, DANIEL F.; MORA-VARGAS, JORGE A.; AMARAL, CLARICE D. B.; OLIVEIRA, ANDREA; GONZALEZ, MARIO H.. Natural deep eutectic solvents for sample preparation prior to elemental analysis by plasma-based techniques. Talanta, v. 199, p. 361-369, JUL 1 2019. (17/18531-3, 17/13230-5, 13/23886-4)

ZITO, CECILIA A.; PERFECTO, TARCISIO M.; FONSECA, CRISTIANE S.; VOLANTI, DIOGO P.. Effective reduced graphene oxide sheets/hierarchical flower-like NiO composites for methanol sensing under high humidity. NEW JOURNAL OF CHEMISTRY, v. 42, n. 11, p. 8638-8645, JUN 7 2018. (16/04371-1, 17/01267-1, 13/23886-4, 16/25267-8)

DE SOUZA MORETTI, MARCIA MARIA; PERRONE, OLAVO MICALI; CARREIRA NUNES, CHRISTIANE DA COSTA; TABOGA, SEBASTIAO; BOSCOLO, MAURICIO; DA SILVA, ROBERTO; GOMES, ELENI. Effect of pretreatment and enzymatic hydrolysis on the physical-chemical composition and morphologic structure of sugarcane bagasse and sugarcane straw. Bioresource Technology, v. 219, p. 773-777, NOV 2016. (13/23886-4, 10/08827-3)

COELHO, ADONIS; PERRONE, OLAVO MICALI; GOMES, ELENI; DA-SILVA, ROBERTO; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Mixed metal oxides from sucrose and cornstarch templated hydrotalcite-like LDHs as catalysts for ethyl biodiesel synthesis. APPLIED CATALYSIS A-GENERAL, v. 532, p. 32-39, FEB 25 2017. (15/22954-1, 13/23886-4, 15/11588-4)

ZITO, CECILIA A.; PERFECTO, TARCISIO M.; VOLANTI, DIOGO P.. Palladium-Loaded Hierarchical Flower-like Tin Dioxide Structure as Chemosensor Exhibiting High Ethanol Response in Humid Conditions. ADVANCED MATERIALS INTERFACES, v. 4, n. 22, NOV 23 2017. (16/04371-1, 17/01267-1, 15/05916-9, 14/17343-0, 13/23886-4)

VARGAS, JORGE ANDRES MORA; DIAS, RAFAEL MAFRA DE PAULA; DE LIMA, LIVIA PADILHA; ORTEGA, JULIETH ORDUNA; BOSCOLO, MAURICIO; METZKER, GUSTAVO. Conversion of 1-butanol into High Value-Added Chemicals by Mixed Metal Oxides: The Influence of Co²⁺, Ni²⁺, and Zn²⁺ into Condensed Phase Products Distribution. CATALYSIS LETTERS, v. 154, n. 5, p. 9-pg., 2023-10-17. (13/23886-4, 20/02471-4, 17/13230-5, 17/09520-8)

ZITO, CECILIA A.; PERFECTO, TARCISIO M.; OLIVEIRA, TAIS N. T.; VOLANTI, DIOGO P.. Bicone-like ZnO structure as high-performance butanone sensor. Materials Letters, v. 223, p. 142-145, JUL 15 2018. (17/01267-1, 16/25267-8, 16/04371-1, 13/23886-4, 16/22219-2)

PERFECTO, TARCISIO M.; ZITO, CECILIA A.; MAZON, TALITA; VOLANTI, DIOGO P.. Flexible room-temperature volatile organic compound sensors based on reduced graphene oxide-WO3 center dot 0.33H(2)O nano-needles. JOURNAL OF MATERIALS CHEMISTRY C, v. 6, n. 11, p. 2822-2829, MAR 21 2018. (16/04371-1, 17/01267-1, 13/23886-4, 16/25267-8)

MARCELO MANCINI; ADONIS COELHO; OLAVO M. PERRONE; JOÃO C. THOMEO; MAURICIO BOSCOLO. ÓXIDOS METÁLICOS DERIVADOS DE MATERIAIS TIPO HIDROTALCITAS CONTENDO Ga3+ COMO CATALISADORES PARA SÍNTESE DE BIODIESEL ETÍLICO. Química Nova, v. 40, n. 5, p. 528-533, 2017-06-00. (13/23886-4)

PERFECTO, T. M.; ZITO, C. A.; VOLANTI, D. P.. Design of nanostructured WO3 center dot 0.33H(2)O via combination of ultrasonic spray nozzle and microwave-assisted hydrothermal methods for enhancing isopropanol gas sensing at room temperature. CrystEngComm, v. 19, n. 20, p. 2733-2738, MAY 28 2017. (16/04371-1, 15/05916-9, 13/23886-4, 14/17343-0)

MODENES-JUNIOR, MARCO A.; ZITO, CECILIA A.; PERFECTO, TARCISIO M.; VOLANTI, DIOGO P.. Ethanol detection using composite based on reduced graphene oxide and CuO hierarchical structure under wet atmosphere. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, v. 248, SEP 2019. (17/01267-1, 16/25267-8, 13/23886-4, 14/17343-0, 18/00033-0)

PERFECTO, T. M.; ZITO, C. A.; VOLANTI, D. P.. Room-temperature volatile organic compounds sensing based on WO3 center dot 0.33H(2)O, hexagonal-WO3, and their reduced graphene oxide composites. RSC ADVANCES, v. 6, n. 107, p. 105171-105179, 2016. (15/05916-9, 13/23886-4, 15/04306-2, 14/17343-0)

ZITO, CECILIA A.; PERFECTO, TARCISIO M.; VOLANTI, DIOGO P.. Impact of reduced graphene oxide on the ethanol sensing performance of hollow SnO2 nanoparticles under humid atmosphere. SENSORS AND ACTUATORS B-CHEMICAL, v. 244, p. 466-474, JUN 2017. (16/04371-1, 13/23886-4, 14/17343-0, 15/05916-9)

SANTANA, ANA PR; MORA-VARGAS, JORGE A.; GUIMARAES, TACIANA G. S.; AMARAL, CLARICE D. B.; OLIVEIRA, ANDREA; GONZALEZ, MARIO H.. Sustainable synthesis of natural deep eutectic solvents (NADES) by different methods. JOURNAL OF MOLECULAR LIQUIDS, v. 293, NOV 1 2019. (17/09520-8, 17/13230-5, 13/23886-4, 15/08873-9, 17/18531-3)

OLIVEIRA, TAIS N. T.; ZITO, CECILIA A.; PERFECTO, TARCISIO M.; AZEVEDO, GUSTAVO M.; VOLANTI, DIOGO P.. ZnO twin-rods decorated with Pt nanoparticles for butanone detection. NEW JOURNAL OF CHEMISTRY, v. 44, n. 36, p. 10-pg., 2020-09-28. (19/12345-9, 18/00033-0, 16/25267-8, 16/22219-2, 17/01267-1, 18/01258-5, 13/23886-4)

ROJAS STERLING, JUAN CAMILO; ORDUNA ORTEGA, JULIETH; METZKER, GUSTAVO; BOSCOLO, MAURICIO; MORA VARGAS, JORGE ANDRES. Fast and selective synthesis of mono-substituted sucrose methacrylate ester monomer. Carbohydrate Research, v. 511, JAN 2022. (13/23886-4, 17/13230-5, 20/02471-4)

SIQUEIRA, MARCOS RECHI; PERRONE, OLAVO MICALI; METZKER, GUSTAVO; DE OLIVEIRA LISBOA, DANIELA CORREA; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Highly selective 1-butanol obtained from ethanol catalyzed by mixed metal oxides: Reaction optimization and catalyst structure behavior. MOLECULAR CATALYSIS, v. 476, OCT 2019. (16/15575-7, 17/13230-5, 92/03515-3, 15/11588-4, 13/23886-4)

NASCIMENTO, PATRICIA A.; SCHULTZ, JULIANA; GONZALEZ, MARIO H.; OLIVEIRA, ANDREA. Simple GFAAS Method for Determination of Pb, As, and Cd in Cannabidiol Extracts Used for Therapeutic Purposes. Journal of the Brazilian Chemical Society, v. 31, n. 5, p. 894-903, MAY 2020. (13/23886-4, 17/09520-8, 17/13230-5, 17/18531-3, 15/08873-9)