Development and application of electromembrane extraction in capillary electrophoresis methods

• Grant number: 13/22485-6
• Support Opportunities: Regular Research Grants
• Start date: March 01, 2014
• End date: August 31, 2016
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Dosil Pereira de Jesus
• Grantee: Dosil Pereira de Jesus
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

In this project microextraction systems using electric field, so-called electromembrane extraction (EME), will be developed. The main aim of this project is the use of EME to enhance the speed, the extraction efficiency and the detectability of analytes in capillary electrophoresis methods. A new configuration of EME using separated electrolysis is proposed, as well as strategies to obtain efficient microextractions of polar compounds. The developed EME systems will be evaluated, optimized, and applied for extraction and preconcentration of phenolic acids in olive oil and sulfonamide residues in bovine milk and chicken egg. (AU)

Scientific publications

(11)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

OLIVEIRA, AMILTON MOREIRA; LOUREIRO, HUGO CAMPOS; SOUZA DE JESUS, FRANCIELLY FERNANDA; DE JESUS, DOSIL PEREIRA. Electromembrane extraction and preconcentration of carbendazim and thiabendazole in water samples before capillary electrophoresis analysis. JOURNAL OF SEPARATION SCIENCE, v. 40, n. 7, p. 1532-1539, APR 2017. (13/22485-6, 13/22127-2)

TRAVASSOS LEMOS, MARIA AUGUSTA; CASSELLA, RICARDO JORGENSEN; DE JESUS, DOSIL PEREIRA. A simple analytical method for determining inorganic anions and formate in virgin olive oils by capillary electrophoresis with capacitively coupled contactless conductivity detection. FOOD CONTROL, v. 57, p. 327-332, NOV 2015. (13/22485-6)

MARQUES, THAIS TAMYE; SHIROMA, LETICIA SAYURI; DE JESUS, DOSIL PEREIRA. Determination of tetrakis(hydroxymethyl)phosphonium sulfate in commercial formulations and cooling water by capillary electrophoresis with contactless conductivity detection. JOURNAL OF SEPARATION SCIENCE, v. 38, n. 5, p. 852-857, MAR 2015. (13/22485-6)

JOANNI, EDNAN; PERESSINOTTO, JONNAS; DOMINGUES, PATRICIA SILVA; SETTI, GRAZIELLE DE OLIVEIRA; DE JESUS, DOSIL PEREIRA. Fabrication of molds for PDMS microfluidic devices by laser swelling of PMMA. RSC ADVANCES, v. 5, n. 32, p. 25089-25096, 2015. (13/22485-6, 13/25108-9)

SHIROMA, LETICIA S.; MARQUES, THAIS T.; JESUS, DOSIL P.. A rapid and simple capillary electrophoresis method for indirect determination of the biocide 2,2-dibromo-3-nitrilo-propionamide (DBNPA) in cooling waters. WATER SCIENCE AND TECHNOLOGY, v. 71, n. 3, p. 434-439, 2015. (13/22485-6)

CAMILA D. M. CAMPOS; RICHARD P. S. DE CAMPOS; JOSÉ A. FRACASSI DA SILVA; DOSIL P. JESUS; RICARDO M. ORLANDO. PREPARO DE AMOSTRAS ASSISTIDO POR CAMPO ELÉTRICO: FUNDAMENTOS, AVANÇOS, APLICAÇÕES E TENDÊNCIAS. Química Nova, v. 38, n. 8, p. 1093-1106, 2015-09-00. (11/02477-3, 13/22485-6)

COELHO, ALINE GUADALUPE; DE JESUS, DOSIL PEREIRA. A simple method for determination of erythritol, maltitol, xylitol, and sorbitol in sugar-free chocolates by capillary electrophoresis with capacitively coupled contactless conductivity detection. ELECTROPHORESIS, v. 37, n. 22, p. 2986-2991, NOV 2016. (13/22485-6, 13/22127-2)

SETTI, G. O.; JOANNI, E.; POPPI, R. J.; DOS SANTOS, D. P.; DE JESUS, D. P.. Temporal drift in Raman signal intensity during SERS measurements performed on analytes in liquid solutions. ANALYST, v. 141, n. 17, p. 5071-5077, 2016. (13/22485-6, 13/25108-9, 13/22127-2)

LEMOS, M. A. T.; PINHEIRO, A. M.; CASSELLA, R. J.; JESUS, D. P.. Simultaneous determination of potassium, sodium, calcium, and magnesium in virgin olive oils by capillary electrophoresis with capacitively coupled contactless conductivity detection. ANALYTICAL METHODS, v. 6, n. 11, p. 3629-3633, JUN 7 2014. (13/22485-6, 08/57805-2)

SETTI, GRAZIELLE O.; MAMIAN-LOPEZ, MONICA B.; PESSOA, PRISCILA R.; POPPI, RONEI J.; JOANNI, EDNAN; JESUS, DOSIL P.. Sputtered gold-coated ITO nanowires by alternating depositions from Indium and ITO targets for application in surface-enhanced Raman scattering. Applied Surface Science, v. 347, p. 17-22, AUG 30 2015. (13/22485-6, 13/25108-9)

SETTI, GRAZIELLE O.; DE JESUS, DOSIL P.; JOANNI, EDNAN. Self-catalyzed carbon plasma-assisted growth of tin-doped indium oxide nanostructuresby the sputtering method. MATERIALS RESEARCH EXPRESS, v. 3, n. 10, OCT 2016. (13/22485-6, 08/57805-2, 13/25108-9, 13/22127-2)