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Synthesis of stimuli-responsive polymer nanoparticles obtained by emulsion and miniemulsion polymerization for production of recycable carpet

Abstract

Automotive and industrial carpets are made with poly(ethylene terephthalate) (PET) fibers impregnated by an aqueous emulsion copolymers, which make it impossible to recycling and reuse these fibers for subsequent production of new carpets. Currently 35 % of the total carpet production is composed by scraps and leftovers from the manufacturing process, which are incinerated or disposed of in landfills. In this context, the production of polymeric nanoparticles with multi-stimulus response that improve the redispersilbe of polymeric film and subsequent reuse of carpet fibers are of great industrial and academic interest. The objective of this research project is to synthesize polymeric nanoparticles with multi-stimulus responsive for carpet production, in order to reuse of fibers and polymeric nanoparticles for production of new materials. The polymeric nanoparticles will be obtained via emulsion and miniemulsion polymerization of monomers: styrene (Sty), n-butyl acrylate (ABu) and ethylene glycol dimethacrylate (EGDMA). In the present project, three polymeric stabilizer will be carried out to obtain the polymer nanoparticles with stimulus response: (i) oligomeric stabilizer obtained by copolymerization of methacrylic acid with N,N-diethylaminoethyl methacrylate (DEAEMA), (ii) copolymerization of methacrylic acid with methacrylamide and (iii) cassava starch modified with cationic groups. The polymeric nanoparticles will be characterized and used for the production of carpets, which will be evaluated in accordance with the stability of the pieces and redispersibility of the polymeric film and reuse of these fibers and nanoparticles. This research project will be developed in partnership with BASF and ICT-UNIFESP for carpet characterizations and reprocessability. (AU)

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Scientific publications (6)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
ALCANTARA RODRIGUES, LINA DAYSE; GUERRINI, LILIA MULLER; DE OLIVEIRA, MAURICIO PINHEIRO. Thermal and mechanical properties of cationic starch-graft-poly(butyl acrylate-co-methyl methacrylate) latex film obtained by semi-continuous emulsion polymerization for adhesive application. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 146, n. 1, p. 143-152, OCT 2021. Web of Science Citations: 0.
OLIVEIRA, TAILA S.; BRAZIL, TAYRA R.; GUERRINI, LILIA M.; REZENDE, MIRABEL C.; OLIVEIRA, MAURICIO P. Synthesis and characterization of poly (acrylonitrile-g-lignin) by semi-batch solution polymerization and evaluation of their potential application as carbon materials. JOURNAL OF POLYMER RESEARCH, v. 27, n. 11 OCT 23 2020. Web of Science Citations: 0.
SAMUEL AUGUSTO DOS SANTOS; MARLON SANDRO DOS SANTOS; MAURÍCIO PINHEIRO DE OLIVEIRA. Efeito dos ácidos itacônico e fumárico na copolimerização em emulsão do estireno com acrilato de n-butila para produção de argamassa cimentícia. MATERIA-RIO DE JANEIRO, v. 24, n. 3, p. -, 2019.
LAURA ALVES CAMPOS; SAMUEL A. SANTOS; FÁBIO HENRIQUE FRANCO; MARLON SANDRO DOS SANTOS; LÍLIA MÜLLER GUERRINI; MAURÍCIO PINHEIRO DE OLIVEIRA. Influência da concentração dos monômeros de acrilato e metacrilato de hidroxipropila na copolimerização em emulsão do estireno com acrilato de n-butila e acrilonitrila para produção de adesivos.. MATERIA-RIO DE JANEIRO, v. 24, n. 3, p. -, 2019.
MESSMER, NIGEL RODERICK; GUERRINI, LILIA MUELLER; OLIVEIRA, MAURICIO PINHEIRO. Effect of unmodified kraft lignin concentration on the emulsion and miniemulsion copolymerization of styrene with n-butyl acrylate and methacrylic acid to produce polymer hybrid latex. POLYMERS FOR ADVANCED TECHNOLOGIES, v. 29, n. 3, p. 1094-1106, MAR 2018. Web of Science Citations: 2.
MESSMER, NIGEL R.; ANJOS, ERICK G. R.; GUERRINI, LILIA M.; OLIVEIRA, MAURICIO P. Effect of geometry and hybrid adhesive on strength of finger joints of Pinus elliottii subject to humidity and temperature. JOURNAL OF ADHESION, v. 94, n. 8, p. 597-614, 2018. Web of Science Citations: 0.

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