Nanostructured layered solids as acid, basic and redox catalysts

• Grant number: 14/06942-0
• Support Opportunities: Research Projects - Thematic Grants
• Start date: December 01, 2014
• End date: November 30, 2018
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Heloise de Oliveira Pastore
• Grantee: Heloise de Oliveira Pastore
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated research grant(s): 18/10870-6 - 26th Ibero-American Congress of Catalysis (CICat), AR.EXT
• Associated scholarship(s): 18/18494-3 - Development of acidity characterization methods for lamellar solids and zeolites in aqueous media, BP.PD; 18/01427-1 - Development of lamellar materials doped with rare earth ions for catalysis and as temperature sensors., BP.PD

Abstract

This project involves the synthesis and characterization of three layered materials: magadiite and octosilicate (also known as RUB-18) from the family of the hydrated layered silicates and talc, a 2:1 phyllosilicate clay, and their use in the catalytic reactions of ethanol to ethylene, ethylether and acetaldehyde. Al, V, Ti, Fe and B will be introduced into the structure of RUB-18, while Al and V, isolated or together, will be introduced in magadiite. Aluminum and boron, in the 3+ formal oxidation state, will be examined as the sources of acid sites; the other metallic ions, V+4/+5, Ti+4 and Fe+3 may provide redox catalytic sites. The two metals with which we have larger experience, V+4/+5 e Al+3, will be introduced in magadiite, with the objective to generate acidity and redox capability simultaneously, in order to produce a bifunctional catalyst. Talc will be organomodified from the synthesis, with organic groups covalently bound to the lamella. The target pending groups contain amine functionalities that will work as basic catalytic sites and for the growth of dendrons that will provide the material with a larger number of active sites. Solids will be characterized in relation to their structure, thermal and hydrothermal stability and the features of the active sites: adsorption of molecular probes for acid sites (NH3 e CO), basic (CO2) and redox (O2/H2) and examined by thermoprogrammed desorption and Fourier transformed infrared spectroscopy. After confirmation of the identity of the solids and some of their reactivities, and before a deeper characterization, the lamellar materials will be tested in the transformation of ethanol as catalytic model reaction for each determined function. (AU)

Scientific publications

(18)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

PAZ, GIZEUDA L.; MUNSIGNATTI, ERICA C. O.; PASTORE, HELOISE O.. Novel catalyst with layered structure: Metal substituted magadiite. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v. 422, n. SI, p. 43-50, OCT 2016. (14/06942-0)

BAFERO, GABRIEL B.; MUNSIGNATTI, ERICA C. O.; PASTORE, HELOISE O.. Lamellar-zeolitic transformations mediated by diffusionless and recrystallization mechanisms. Microporous and Mesoporous Materials, v. 323, AUG 2021. (14/06942-0)

RAMOS, FRANCISCA S. O.; ALMEIDA, RAMON K. S.; LOPES JUNIOR, CICERO A.; ARRUDA, MARCO AURELIO Z.; PASTORE, HELOISE O.. A Straightforward Method for Determination of Al and Na in Aluminosilicates Using ICP OES. Journal of the Brazilian Chemical Society, v. 28, n. 8, p. 1557-1563, 2017. (14/06942-0, 12/09001-7, 13/25706-3)

RAMOS, FRANCISCA S. O.; PASTORE, HELOISE O.. 2D-to-disguised 3D materials with built-in acid sites: H+-[Al]-RUB-18. DALTON TRANSACTIONS, v. 46, n. 35, p. 11728-11737, SEP 21 2017. (14/06942-0, 12/09001-7)

ANDRADE, JR., MARCOS A. S.; NOGUEIRA, ANA F.; MIETTUNEN, KATI; TIIHONEN, ARMI; LUND, PETER D.; PASTORE, HELOISE O.. Quasi-solid electrolyte with polyamidoamine dendron modified-talc applied to dye-sensitized solar cells. Journal of Power Sources, v. 325, p. 161-170, SEP 1 2016. (14/06942-0, 13/05911-1)

SANTANA ANDRADE, JR., MARCOS A.; TIIHONEN, ARMI; MIETTUNEN, KATI; LUND, PETER; NOGUEIRA, ANA F.; PASTORE, HELOISE O.. Gel Electrolytes with Polyamidopyridine Dendron Modified Talc for Dye-Sensitized Solar Cells. ACS APPLIED MATERIALS & INTERFACES, v. 9, n. 24, p. 20454-20466, JUN 21 2017. (14/06942-0, 13/05911-1)

SILVA, BRUNA NADIA N.; PASTORE, HELOISE O.; LEITAO, ALEXANDRE A.. The role of hydration water in inorganic M+n-magadiites (M+n = K+, Ca+2 , Mg-2): Advances in structural and electronic analysis by DFT calculations. APPLIED CLAY SCIENCE, v. 231, p. 9-pg., 2023-01-03. (14/06942-0)

CAMPOS, GUILHERME P.; ALBUQUERQUE, ELISE M.; FRAGA, MARCO A.; PASTORE, HELOISE O.. Continuous Cellobiose Hydrolysis over Lamellar Aluminosilicates-Unveiling [Al]-magadiite Water-Tolerant Acid Sites. Industrial & Engineering Chemistry Research, v. 60, n. 13, p. 4794-4805, APR 7 2021. (14/06942-0)

SILVA, BRUNA NADIA N.; PASTORE, HELOISE O.; LEITAO, ALEXANDRE A.. The steps of thermal treatment of Na-magadiite: a computational study using ab initio DFT calculations. Physical Chemistry Chemical Physics, v. 24, n. 23, p. 8-pg., 2022-05-12. (14/06942-0)

BAFERO, GABRIEL B.; ARAUJO, VICTOR A.; ALMEIDA, RAMON K. S.; PASTORE, HELOISE O.. Catalytic performance of ferrierite and omega zeolites obtained through 2D-3D-3D transformation from Na-RUB-18 layered silicate. Microporous and Mesoporous Materials, v. 302, AUG 1 2020. (13/25706-3, 14/06942-0)

ALMEIDA, RAMON K. S.; PAZ, GIZEUDA L.; BAFERO, GABRIEL B.; PASTORE, HELOISE O.. Properties of layered [Al]- and [V,Al]-magadiite catalysts as revealed by ethanol dehydration. Microporous and Mesoporous Materials, v. 284, p. 1-9, AUG 2019. (14/06942-0, 13/25706-3)

ANDRADE, JR., MARCOS A. S.; MIETTUNEN, KATI; TIIHONEN, ARMI; LUND, PETER D.; NOGUEIRA, ANA E.; PASTORE, HELOISE O.. Stabilizing Dendron-Modified Talc-Based Electrolyte for Quasi-Solid Dye-Sensitized Solar Cell. Electrochimica Acta, v. 228, p. 413-421, FEB 20 2017. (14/06942-0, 13/05911-1)

ANDRADE, JR., MARCOS A. S.; PASTORE, HELOISE O.. Toward a Delaminated Organotalc: The Use of Polyamidoamine Dendrons. ACS APPLIED MATERIALS & INTERFACES, v. 8, n. 3, p. 1884-1892, JAN 27 2016. (14/06942-0, 13/05911-1)

BAFERO, GABRIEL B.; RODRIGUES, MARIANA, V; MUNSIGNATTI, ERICA C. O.; PASTORE, HELOISE O.. Low temperature ethanol dehydration performed by MOR catalysts obtained from 2D-3D transformation. CATALYSIS TODAY, v. 394, p. 9-pg., 2022-07-01. (14/06942-0, 18/18494-3)

KRYSIAK, YASAR; MASLYK, MARCEL; SILVA, BRUNA NADIA; PLANA-RUIZ, SERGI; MOURA, HIPASSIA M.; MUNSIGNATTI, ERICA O.; VAISS, VIVIANE S.; KOLB, UTE; TREMEL, WOLFGANG; PALATINUS, LUKAS; et al. The Elusive Structure of Magadiite, Solved by 3D Electron Diffraction and Model Building. CHEMISTRY OF MATERIALS, v. 33, n. 9, p. 3207-3219, MAY 11 2021. (14/06942-0)

BAFERO, GABRIEL B.; SILVA, BRUNA NADIA N.; LEITAO, ALEXANDRE A.; PASTORE, HELOISE O.. The behavior of aluminum sites in H-[Al]-RUB-18 catalysts: A theoretical-experimental investigation. MOLECULAR CATALYSIS, v. 535, p. 13-pg., 2022-12-23. (21/12058-0, 14/06942-0)

PAZ, GIZEUDA L.; MUNSIGNATTI, ERICA C. O.; PASTORE, HELOISE O.. Novel catalyst with layered structure: Metal substituted magadiite. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v. 422, p. 8-pg., 2016-10-01. (14/06942-0)

LIMA, ERIKA T. L.; RODRIGUES, MARIANA V.; DO NASCIMENTO, LUIS A. S.; ZAMIAN, JOSE ROBERTO; DA COSTA, CARLOS E. F.; PASTORE, HELOISE O.; DA ROCHA FILHO, GERALDO N.. Effect of water on the organofunctionalization of SAPO-5 to form an efficient oleic acid esterification catalyst. Microporous and Mesoporous Materials, v. 334, p. 11-pg., 2022-02-28. (14/06942-0, 18/18494-3)