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Direct dry transfer of CVD graphene to 2D and 3D polymeric substrates


CVD graphene is a suitable material for industrial applications, since it is possible to obtain graphene with macro dimensions (mm to cm) which is different from that obtained with other techniques. For the first time a project is dedicated to transfer process of CVD graphene for two and three dimensional substrates without causing any damage to the graphene like cracks and/or wrinkles without including the etching step. "Direct Dry Transfer - DDT" will be the technique used here. This methodology was developed and patented in collaboration by Mackenzie Presbyterian University and National University of Singapore. This project was led by Prof. Guilhermino J. M. Fechine and supported by FAPESP (2012/17197-9). The great advances of this innovative technique are the possibility of transferring large areas of graphene and control the amount of graphene transferred to the final substrate. This project will utilize the infrastructure of the SPEC project, "Graphene: Photonics and optic-electronics" (2012 / 50259-8) in the production and characterization of graphene, which will result in a large decrease of the project cost. On the other hand, the understanding of graphene-polymer interface, consequently, domain of graphene transfer processes will result in the most appropriate technology to produce devices intended by the SPEC projects. For a complete mastery of the graphene transfer is needed the understanding of the phenomena that govern this process, especially those who are directly connected to graphene-polymer interface. The strategy to solve this equation with many variables is to utilize multidisciplinary procedures that include: Theoretical calculations and simulations of graphene-polymer interface, surface properties (AFM, XPS, NEXAFS and contact angle), rheological measurements and molecular weight of the polymers. Several methodologies of polymer processing will be also used to transfer graphene to polymeric substrates with 2 and 3 dimensions. Aiming to achieve a deeper understanding at the level of the research proposed here, national and international collaborations in different areas will be part of this project. These collaborations extend to the area of synthesis and transfer of graphene (Prof. Anthony HC Neto and Prof. Barbaros Olzymaz - National University of Singapore) and evaluation of graphene-polymer interface using different approaches (Prof. Daniel Weibel - UFRGS, Dr. Julio Criginski Cezar - LNLS, Prof. Michael Huggins - University of Wollongong / Australia and Prof. Loic Hugues G. Hilliou - University of Minho / Portugal). (AU)

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Scientific publications (9)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
DANDA, CHAITANYA; AMURIN, LEICE G.; MUNOZ, PABLO A. R.; NAGAOKA, DANILO A.; SCHNEIDER, TYLER; TROXELL, BRANDY; KHANI, SHAGHAYEGH; DOMINGUES, SERGIO H.; ANDRADE, RICARDO J. E.; FECHINE, GUILHERMINO J. M.; MAIA, JOAO M. Integrated Computational and Experimental Design of Ductile, Abrasion-Resistant Thermoplastic Polyurethane/Graphene Oxide Nanocomposites. ACS APPLIED NANO MATERIALS, v. 3, n. 10, p. 9694-9705, OCT 23 2020. Web of Science Citations: 0.
COSTA, MARIANA C. F.; PARRA, GUSTAVO G.; LARRUDE, DUNIESKYS R. G.; FECHINE, GUILHERMINO J. M. Screening effect of CVD graphene on the surface free energy of substrates. Physical Chemistry Chemical Physics, v. 22, n. 29, p. 16672-16680, AUG 7 2020. Web of Science Citations: 0.
NEJAIM, YURI; GOMES, AMANDA FARIAS; QUEIROZ, POLYANE MAZUCATTO; SIQUEIRA, ANDRE DA SILVA; RIVEROS MUNOZ, PABLO ANDRES; MACEDO FECHINE, GUILHERMINO JOSE; HAITER-NETO, FRANCISCO. Artifact expression of polylactic acid/hydroxyapatite/graphene oxide nanocomposite in CBCT: a promising dental material. CLINICAL ORAL INVESTIGATIONS, v. 24, n. 5, p. 1695-1700, MAY 2020. Web of Science Citations: 0.
DE OLIVEIRA, YURI D. C.; AMURIN, LEICE G.; VALIM, FERNANDA C. F.; FECHINE, GUILHERMINO J. M.; ANDRADE, RICARDO J. E. The role of physical structure and morphology on the photodegradation behaviour of polypropylene-graphene oxide nanocomposites. Polymer, v. 176, p. 146-158, AUG 2 2019. Web of Science Citations: 1.
DA COSTA, M. C. E.; SOUSA, M. R. M.; LARRUDE, D. R. G.; FECHINE, G. J. M. Adhesion between graphene and polymers: A surface analysis perspective. EXPRESS POLYMER LETTERS, v. 13, n. 1, p. 52-64, JAN 2019. Web of Science Citations: 1.
MUNOZ, P. A. R.; DE OLIVEIRA, C. F. P.; AMURIN, L. G.; RODRIGUEZ, C. L. C.; NAGAOKA, D. A.; TAVARES, M. I. B.; DOMINGUES, S. H.; ANDRADE, R. J. E.; FECHINE, G. J. M. Novel improvement in processing of polymer nanocomposite based on 2D materials as fillers. EXPRESS POLYMER LETTERS, v. 12, n. 10, p. 930-945, OCT 2018. Web of Science Citations: 6.
MALDONADO, LUIZ F.; MUNOZ, PABLO A. R.; FECHINE, GUILHERMINO J. M. Transfer of Graphene CVD to Surface of Low Density Polyethylene (LDPE) and Poly(butylene adipate-co-terephthalate) (PBAT) Films: Effect on Biodegradation Process. JOURNAL OF POLYMERS AND THE ENVIRONMENT, v. 26, n. 8, p. 3187-3196, AUG 2018. Web of Science Citations: 0.
KESSLER, FELIPE; MUNOZ, PABLO A. R.; PHELAN, CIARAN; ROMANI, ERIC C.; LARRUDE, DUNIESKYS R. G.; FREIRE JUNIOR, FERNANDO L.; DE SOUZA, EUNEZIO A. THOROH; DE MATOS, CHRISTIANO J. S.; FECHINE, GUILHERMINO J. M. Direct dry transfer of CVD graphene to an optical substrate by in situ photo-polymerization. Applied Surface Science, v. 440, p. 55-60, MAY 15 2018. Web of Science Citations: 3.
KESSLER, FELIPE; DA ROCHA, CAIQUE O. C.; MEDEIROS, GABRIELA S.; FECHINE, GUILHERMINO J. M. Chemical vapor deposition graphene transfer process to a polymeric substrate assisted by a spin coater. MATERIALS RESEARCH EXPRESS, v. 3, n. 3 MAR 2016. Web of Science Citations: 4.

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