Studies on the use of bioethanol in proton exchange membrane and solid oxide fuel cells

• Grant number: 14/09087-4
• Support type: Research Projects - Thematic Grants
• Duration: February 01, 2016 - July 31, 2020
• Field of knowledge: Interdisciplinary Subjects
• Principal researcher: Marcelo Linardi
• Grantee: Marcelo Linardi
• Home Institution: Instituto de Pesquisas Energéticas e Nucleares (IPEN). Secretaria de Desenvolvimento Econômico (São Paulo - Estado). São Paulo , SP, Brazil
• Pesquisadores principais: Fabio Coral Fonseca
• Assoc. researchers: Alexandre José de Castro Lanfredi ; Almir Oliveira Neto ; Daniel Zanetti de Florio ; Edgar Ferrari da Cunha ; Elisabete Inacio Santiago ; Estevam Vitorio Spinacé ; Jorge Moreira Vaz ; Patricia da Silva Pagetti de Oliveira ; Vanderlei Sérgio Bergamaschi
• Associated grant(s): 16/50339-2 - Chemical fabrication of active nanomaterials for fuel cells on natural gas and bioethanol fluels, AP.R SPRINT
• Associated scholarship(s): 19/15110-2 - Development of core-shell catalysts for ethanol steam reforming reaction, BP.PD; 19/06813-0 - Studies on the use of bioethanol in proton exchange membrane and solid oxide fuel cells, BP.PD; 19/04499-6 - Development of anodes with catalytic layers for direct ethanol solid oxide fuel cells, BP.DD; + associated scholarships 19/07033-8 - Technical training for the development of direct ethanol solid oxide fuel cells, BP.TT; 19/00004-2 - Optimization of components for intermediate temperature direct ethanol fuel cells, BP.TT; 18/05819-1 - Evaluation of catalysts for the preferential oxidation of carbon monoxide in hydrogen-rich mixtures (CO-PROX reaction), BP.TT; 18/02453-6 - Optimization of components for intermediate temperature direct ethanol fuel cells, BP.TT; 17/04929-5 - Development of catalysts to obtain hydrogen from bio-ethanol, BP.PD; 16/24387-0 - Preparation of suspensions of solid electrolytes for deposition of thin layers by inkjet printing, BP.IC; 16/07156-4 - Development of anodes with catalytic layers for direct ethanol solid oxide fuel cells, BP.DD - associated scholarships

Abstract

The use of bioethanol in Proton Exchange Membrane Fuel Cell (PEMFC) and Solid Oxide Fuel Cell (SOFC), either directly as a fuel or indirectly in the form of reformate hydrogen, has a number of technical barriers that require scientific and technological advances in order to provide high efficiency, durability, reliability and low cost to these devices. This project aims to address critical issues for the major scientific and technological challenges to advance the use of ethanol in fuel cells. For PEMFC the main focus will be the development of anode catalysts, electrolytes, and membrane/electrode/bipolar plates assemblies that allow a more efficient use of ethanol For SOFC it will be investigated anode materials resistant to carbon deposits for the direct use of ethanol. Ethanol will be also studied as a source of hydrogen by developing catalysts for steam reforming and for purification by the preferential oxidation of carbon monoxide reaction (PROX-CO) of hydrogen-rich mixtures resulting from the steam reforming and shift processes. The success of this project will bring significant contributions to the advancement of the understanding of the electrochemical processes, in the development of devices that use a strategic biofuel and training of specialized human resources. (AU)

Scientific publications

(61)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

DRESCH, MAURO ANDRE; MATOS, BRUNO RIBEIRO; MARTINS GODOI, DENIS RICARDO; LINARDI, MARCELO; FONSECA, FABIO CORAL; MERCEDES VILLULLAS, HEBE DE LAS; SANTIAGO, ELISABETE INACIO. Advancing direct ethanol fuel cell operation at intermediate temperature by combining Nafion-hybrid electrolyte and well-alloyed PtSn/C electrocatalyst. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 46, n. 24, p. 13252-13264, APR 6 2021. (17/11937-4, 14/50279-4, 14/12255-6, 14/09087-4)

CATARINE SANTOS LOPES ALENCAR; ANA RITA NOBORIKAWA PAIVA; JULIO CESAR MARTINS DA SILVA; JORGE MOREIRA VAZ; ESTEVAM VITORIO SPINACÉ. One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, v. 23, n. 5, p. -, 2020. (14/50279-4, 17/11937-4, 14/09087-4)

ANTONIASSI, R. M.; SILVA, J. C. M.; LOPES, T.; OLIVEIRA NETO, A.; SPINACE, E. V.. Carbon-supported Pt nanoparticles with (100) preferential orientation with enhanced electrocatalytic properties for carbon monoxide, methanol and ethanol oxidation in acidic medium. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 42, n. 8, p. 28786-28796, NOV 30 2017. (14/50279-4, 14/22130-6, 14/09087-4, 17/15304-6)

NANDENHA, J.; NAGAHAMA, I. H. F.; YAMASHITA, J. Y.; FONTES, E. H.; AYOUB, J. M. S.; DE SOUZA, R. F. B.; FONSECA, F. C.; NETO, A. O.. Activation of Methane on PdZn/C Electrocatalysts in an Acidic Electrolyte at Low Temperatures. International Journal of Electrochemical Science, v. 14, n. 12, p. 10819-10834, DEC 2019. (14/50279-4, 17/11937-4, 14/09087-4)

PEREIRA, V, C.; FONTES, E. H.; NANDENHA, J.; ASSUMPCAO, M. H. M. T.; NETO, A. O.. Electrocatalytic Performance of PtSn/C-In2O3 center dot SnO2 Nanoparticles Prepared by Sodium Borohydride Reduction Process for Ethanol Oxidation in Acidic and Alkaline Electrolytes. International Journal of Electrochemical Science, v. 13, n. 11, p. 10587-10600, NOV 2018. (14/50279-4, 14/09087-4)

SANTOS QUEIROZ, CARLA MOREIRA; MACHADO, ARTHUR PIGNATARO; NOBORIKAWA PAIVA, ANA RITA; ANTONIASSI, RODOLFO MOLINA; VAZ, JORGE MOREIRA; SPINACE, ESTEVAM VITORIO. Active Pt/CeO2 catalysts prepared by an alcohol-reduction process for low-temperature CO-PROX reaction. MATERIALS FOR RENEWABLE AND SUSTAINABLE ENERGY, v. 8, n. 3, SEP 2019. (14/50279-4, 17/11937-4, 14/09087-4, 17/15469-5)

ANTONIASSI, RODOLFO M.; QUIROZ, JHON; BARBOSA, EDUARDO C. M.; PARREIRA, LUANNA S.; ISIDORO, ROBERTA A.; SPINACE, V, ESTEVAM; SILVA, JULIO C. M.; CAMARGO, PEDRO H. C.. Improving the Electrocatalytic Activities and CO Tolerance of Pt NPs by Incorporating TiO2 Nanocubes onto Carbon Supports. CHEMCATCHEM, v. 13, n. 8, FEB 2021. (14/09087-4, 16/17866-9, 16/00819-8, 15/26308-7, 15/11452-5, 17/15469-5, 17/11937-4)

GODOI, C. M.; SANTOS, M. C. L.; SILVA, A. J.; TAGOMORI, T. L.; RAMOS, A. S.; DE SOUZA, R. F. B.; NETO, A. OLIVEIRA. Methane conversion to higher value-added product and energy co-generation using anodes OF PdCu/C in a solid electrolyte reactor: alkaline fuel cell type monitored by differential mass spectroscopy. RESEARCH ON CHEMICAL INTERMEDIATES, v. 47, n. 2, p. 743-757, FEB 2021. (14/50279-4, 17/11937-4, 14/09087-4)

MATOS, B. R.; GOULART, C. A.; TOSCO, B.; DA SILVA, J. S.; ISIDORO, R. A.; SANTIAGO, I, E.; LINARDI, M.; SCHADE, U.; PUSKAR, L.; FONSECA, F. C.; et al. Properties and DEFC tests of Nafion - Functionalized titanate nanotubes composite membranes prepared by melt-extrusion. JOURNAL OF MEMBRANE SCIENCE, v. 604, JUN 1 2020. (14/50279-4, 17/11937-4, 14/09087-4)

NANDENHA, J.; YAMASHITA, J. Y.; SOUZA, F. M.; FONTES, E. H.; BATISTA, B. L.; SANTOS, M. C.; LINARDI, M.; NETO, A. O.. Methane activation on PdMn/C-ITO electrocatalysts using a reactor-type PEMFC. RESEARCH ON CHEMICAL INTERMEDIATES, v. 46, n. 10, JUL 2020. (14/50279-4, 14/09087-4, 17/11937-4, 17/22976-0, 17/10118-0, 17/21846-6)

GARCIA, LUIS M. S.; RAJAK, SANIL; CHAIR, KHAOULA; GODOY, CAMILA M.; SILVA, ARACELI JARDIM; GOMES, PAULO V. R.; SANCHES, EDGAR APARECIDO; RAMOS, ANDREZZA S.; DE SOUZA, RODRIGO F. B.; DUONG, ADAM; et al. Conversion of Methane into Methanol Using the [6,6 `-(2,2 `-Bipyridine-6,6 `-Diyl)bis(1,3,5-Triazine-2,4-Diamine)](Nitrato-O)Copper(II) Complex in a Solid Electrolyte Reactor Fuel Cell Type. ACS OMEGA, v. 5, n. 26, p. 16003-16009, JUL 7 2020. (14/50279-4, 17/11937-4, 14/09087-4)

YOVANOVICH, MARCOS; DA SILVA, ARACELI JARDIM; DE SOUZA, RODRIGO F. B.; USSUI, VALTER; NETO, ALMIR OLIVEIRA; LAZAR, DOLORES R. R.. Conversion of Methane to Methanol using WO3/TiO2 Porous Photocatalyst. International Journal of Electrochemical Science, v. 16, n. 7, JUL 2021. (14/50279-4, 14/09087-4, 17/11937-4)

NANDENHA, JULIO; RAMOS, CARLOS EDUARDO DOMINGUES; DA SILVA, SIRLANE G.; DE SOUZA, RODRIGO FERNANDO BRAMBILLA; FONTES, ERIC HOSSEIN; OTTONI, CRISTIANE ANGELICA; NETO, ALMIR OLIVEIRA. Borohydride Reduction Method for PdIn/C Electrocatalysts Synthesis towards Glycerol Electrooxidation under Alkaline Condition. Electroanalysis, v. 33, n. 4, JAN 2021. (14/50279-4, 14/09087-4, 17/21846-6, 17/11937-4, 17/22976-0)

RAMOS, A. S.; SANTOS, M. C. L.; GODOI, C. M.; DE QUEIROZ, L. C.; NANDENHA, J.; FONTES, E. H.; BRITO, W. R.; MACHADO, M. B.; NETO, A. O.; DE SOUZA, R. F. B.. High CO tolerance of Pt nanoparticles synthesized by sodium borohydride in a time-domain NMR spectrometer. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 45, n. 43, p. 22973-22978, SEP 3 2020. (14/50279-4, 14/09087-4)

OTTONI, CRISTIANE ANGELICA; DA SILVA, SIRLANE G.; DE SOUZA, RODRIGO F. B.; OLIVEIRA NETO, ALMIR. Glycerol oxidation reaction using PdAu/C electrocatalysts. IONICS, v. 22, n. 7, p. 1167-1175, JUL 2016. (14/09087-4)

FONTES, E. H.; DA SILVA, SIRLANE G.; SPINACE', E. V.; NETO, A. O.; DE SOUZA, R. F. B.. In Situ ATR-FTIR Studies of Ethanol Electro-oxidation in Alkaline Medium on PtRh/C Electrocatalyst Prepared by an Alcohol Reduction Process. ELECTROCATALYSIS, v. 7, n. 4, p. 297-304, JUL 2016. (14/50279-4, 14/09087-4)

STEIL, M. C.; NOBREGA, S. D.; GEORGES, S.; GELIN, P.; UHLENBRUCK, S.; FONSECA, F. C.. Durable direct ethanol anode-supported solid oxide fuel cell. APPLIED ENERGY, v. 199, p. 180-186, AUG 1 2017. (13/26961-7, 14/50767-9, 14/50279-4, 14/09087-4)

MALKO, DANIEL; KUCERNAK, ANTHONY; LOPES, THIAGO. Performance of Fe-N/C Oxygen Reduction Electrocatalysts toward NO2-, NO, and NH2OH Electroreduction: From Fundamental Insights into the Active Center to a New Method for Environmental Nitrite Destruction. Journal of the American Chemical Society, v. 138, n. 49, p. 16056-16068, DEC 14 2016. (16/07848-3, 14/50279-4, 14/09087-4)

SANTOS, M. C. L.; OTTONI, C. A.; DE SOUZA, R. F. B.; DA SILVA, S. G.; ASSUMPCAO, M. H. M. T.; SPINACE, E. V.; NETO, A. O.. Methanol Oxidation in Alkaline Medium Using PtIn/C Electrocatalysts. ELECTROCATALYSIS, v. 7, n. 6, p. 445-450, NOV 2016. (14/09087-4)

LEAL, GEORGIA BARBALHO; CIOTTI, LIGIA; WATACABE, BEATRIZ NAOMY; LOUREIRO DA SILVA, DANIELA C.; ANTONIASSI, RODOLFO M.; SILVA, JULIO CESAR M.; LINARDI, MARCELO; GIUDICI, REINALDO; VAZ, JORGE MOREIRA; SPINACE, V, ESTEVAM. Preparation of Au/TiO2 by a facile method at room temperature for the CO preferential oxidation reaction. Catalysis Communications, v. 116, p. 38-42, NOV 2018. (16/21227-1, 14/09087-4, 14/50279-4, 17/15469-5)

DA SILVA, ANDERSON G. M.; BATALHA, DANIEL C.; RODRIGUES, THENNER S.; CANDIDO, EDUARDO G.; LUZ, SULUSMON C.; DE FREITAS, ISABEL C.; FONSECA, FABIO C.; DE OLIVEIRA, DANIELA C.; TAYLOR, JASON G.; CORDOBA DE TORRESI, SUSANA I.; et al. Sub-15 nm CeO2 nanowires as an efficient non-noble metal catalyst in the room-temperature oxidation of aniline. CATALYSIS SCIENCE & TECHNOLOGY, v. 8, n. 7, p. 1828-1839, APR 7 2018. (15/26308-7, 15/21366-9, 14/50279-4, 14/09087-4)

PEREIRA, VIVIANE SANTOS; DA SILVA, JULIO C. M.; OLIVEIRA NETO, ALMIR; SPINACE, ESTEVAM V.. PtRu Nanoparticles Supported on Phosphorous-Doped Carbon as Electrocatalysts for Methanol Electro-Oxidation. ELECTROCATALYSIS, v. 8, n. 3, p. 245-251, MAY 2017. (14/09087-4)

DOUBEK, GUSTAVO; SEKOL, RYAN C.; LI, JINYANG; RYU, WON-HEE; GITTLESON, FORREST S.; NEJATI, SIAMAK; MOY, ERIC; REID, CANDY; CARMO, MARCELO; LINARDI, MARCELO; et al. Guided Evolution of Bulk Metallic Glass Nanostructures: A Platform for Designing 3D Electrocatalytic Surfaces. Advanced Materials, v. 28, n. 10, p. 1940+, MAR 9 2016. (14/09087-4)

ANTONIASSI, R. M.; SILVA, J. C. M.; OLIVEIRA NETO, A.; SPINACE, E. V.. Synthesis of Pt+SnO2/C electrocatalysts containing Pt nanoparticles with preferential (100) orientation for direct ethanol fuel cell. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 218, p. 91-100, DEC 5 2017. (14/09087-4)

DA SILVA, SIRLANE G.; FONTES, ERIC H.; ASSUMPCAO, MONICA H. M. T.; LINARDI, MARCELO; SPINACE, ESTEVAM; SILVA, JULIO CESAR M.; NETO, ALMIR O.. Fuel cell and electrochemical studies of the ethanol electro-oxidation in alkaline media using PtAuIr/C as anodes. IONICS, v. 23, n. 9, p. 2367-2376, SEP 2017. (14/50279-4, 14/09087-4)

MARANI, DEBORA; REIS MORAES, LETICIA PORAS; GUALANDRIS, FABRIZIO; SANNA, SIMONE; DE FLORIO, DANIEL ZANETTI; ESPOSITO, VINCENZO; FONSECA, FABIO CORAL. Nucleation front instability in two-dimensional (2D) nanosheet gadolinium-doped cerium oxide (CGO) formation. CrystEngComm, v. 20, n. 10, p. 1405-1410, MAR 14 2018. (15/20434-0, 14/09087-4, 14/50279-4)

SILVA, JULIO CESAR M.; DE FREITAS, ISABEL C.; NETO, ALMIR O.; SPINACE, ESTEVAM V.; RIBEIRO, VILMARIA A.. Palladium nanoparticles supported on phosphorus-doped carbon for ethanol electro-oxidation in alkaline media. IONICS, v. 24, n. 4, p. 1111-1119, APR 2018. (14/09087-4)

RIBEIRO, VILMARIA A.; DE FREITAS, ISABEL C.; NETO, ALMIR O.; SPINACE, ESTEVAM V.; SILVA, JULIO CESAR M.. Platinum nanoparticles supported on nitrogen-doped carbon for ammonia electro-oxidation. Materials Chemistry and Physics, v. 200, p. 354-360, OCT 1 2017. (14/09087-4)

DO REGO, ULISSES ALVES; LOPES, THIAGO; BOTT-NETO, JOSE LUIZ; TANAKA, AURO ATSUSHI; TICIANELLI, EDSON ANTONIO. Oxygen reduction electrocatalysis on transition metal-nitrogen modified tungsten carbide nanomaterials. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 810, p. 222-231, FEB 1 2018. (14/22130-6, 14/50279-4, 13/16930-7, 17/15304-6, 14/09087-4)

SANTOS, THAMYSCIRA H.; GRILO, JOAO P. F.; LOUREIRO, FRANCISCO J. A.; FAGG, DUNCAN P.; FONSECA, FABIO C.; MACEDO, DANIEL A.. Structure, densification and electrical properties of Gd3+ and Cu2+ co-doped ceria solid electrolytes for SOFC applications: Effects of Gd2O3 content. CERAMICS INTERNATIONAL, v. 44, n. 3, p. 2745-2751, FEB 15 2018. (14/50279-4, 14/09087-4)

GUALTEROS, JESUS A. D.; GARCIA, MARCO A. S.; DA SILVA, ANDERSON G. M.; RODRIGUES, THENNER S.; CANDIDO, EDUARDO G.; E SILVA, FELIPE A.; FONSECA, FABIO C.; QUIROZ, JHON; DE OLIVEIRA, DANIELA C.; CORDOBA DE TORRESI, SUSANA I.; et al. Synthesis of highly dispersed gold nanoparticles on Al2O3, SiO2, and TiO2 for the solvent-free oxidation of benzyl alcohol under low metal loadings. Journal of Materials Science, v. 54, n. 1, p. 238-251, JAN 2019. (17/12407-9, 15/21366-9, 14/50279-4, 14/09087-4)

RODRIGUES, THENNER S.; DE MOURA, ARTHUR B. L.; E SILVA, FELIPE A.; CANDIDO, EDUARDO G.; DA SILVA, ANDERSON G. M.; DE OLIVEIRA, DANIELA C.; QUIROZ, JHON; CAMARGO, PEDRO H. C.; BERGAMASCHI, VANDERLEI S.; FERREIRA, JOAO C.; et al. Ni supported Ce0.9Sm0.1O2-delta nanowires: An efficient catalyst for ethanol steam reforming for hydrogen production. FUEL, v. 237, p. 1244-1253, FEB 1 2019. (14/09087-4, 14/50279-4, 17/04929-5)

DO REGO, ULISSES A.; LOPES, THIAGO; BOTT-NETO, JOSE L.; GOMEZ-MARIN, ANA M.; TANAKA, AURO A.; TICIANELLI, EDSON A.. Non-Noble Fe-N-x/C Electrocatalysts on Tungsten Carbides/N-Doped Carbons for the Oxygen Reduction Reaction. ELECTROCATALYSIS, v. 10, n. 2, p. 134-148, MAR 2019. (17/15304-6, 14/09087-4, 13/16930-7, 14/50279-4, 14/22130-6)

BERUSKI, OTAVIO; LOPES, THIAGO; KUCERNAK, ANTHONY R. J.; PEREZ, JOELMA. Investigation of convective transport in the gas diffusion layer used in polymer electrolyte fuel cells. PHYSICAL REVIEW FLUIDS, v. 2, n. 10, OCT 17 2017. (13/11316-9, 17/15304-6, 11/50727-9, 14/09087-4, 13/16930-7, 14/50279-4, 14/22130-6)

MALKO, DANIEL; KUCERNAK, ANTHONY; LOPES, THIAGO. In situ electrochemical quantification of active sites in Fe-N/C non-precious metal catalysts. NATURE COMMUNICATIONS, v. 7, OCT 31 2016. (14/50279-4, 14/09087-4, 16/07848-3)

DA SILVA, A. A. A.; STEIL, M. C.; TABUTI, F. N.; RABELO-NETO, R. C.; NORONHA, F. B.; MATTOS, V, L.; FONSECA, F. C.. The role of the ceria dopant on Ni / doped-ceria anodic layer cermets for direct ethanol solid oxide fuel cell. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 46, n. 4, SI, p. 4309-4328, JAN 14 2021. (13/26961-7, 17/11937-4, 14/50279-4, 14/09087-4)

FONTES, E. H.; RAMOS, C. E. D.; OTTONI, C. A.; DE SOUZA, R. F. B.; ANTOLINI, E.; NETO, A. O.. Glycerol dehydrogenation steps on Au/C surface in alkaline medium: An in-situ ATR-FTIR approach. RENEWABLE ENERGY, v. 167, p. 954-959, APR 2021. (14/50279-4, 14/09087-4, 17/11937-4)

DA SILVA, JAQUELINE S.; CARVALHO, SABRINA G. M.; DA SILVA, RODRIGO P.; TAVARES, ANA C.; SCHADE, ULRICH; PUSKAR, LJILJANA; FONSECA, FABIO C.; MATOS, BRUNO R.. SAXS signature of the lamellar ordering of ionic domains of perfluorinated sulfonic-acid ionomers by electric and magnetic field-assisted casting. Physical Chemistry Chemical Physics, v. 22, n. 24, p. 13764-13779, JUN 28 2020. (14/09087-4, 17/11937-4, 14/50279-4, 13/50151-5)

RAMOS, ANDREZZA S.; SANTOS, MONIQUE CAROLINA L.; GODOI, CAMILA M.; OLIVEIRA NETO, ALMIR; FERNANDO B. DE SOUZA, RODRIGO. Obtaining C(2)and C(3)Products from Methane Using Pd/C as Anode in a Solid Fuel Cell-type Electrolyte Reactor. CHEMCATCHEM, v. 12, n. 18, JUL 2020. (14/50279-4, 17/11937-4, 14/09087-4)

DE CARMARGO, V. F.; FONTES, E. H.; NANDENHA, J.; DE SOUZA, R. F. B.; NETO, A. O.. High activity of Pt-Rh supported on C-ITO for ethanol oxidation in alkaline medium. RESEARCH ON CHEMICAL INTERMEDIATES, v. 46, n. 2, p. 1555-1570, FEB 2020. (14/50279-4, 17/11937-4, 14/09087-4)

BIANCOLLI, ANA LAURA G.; BSOUL-HAJ, SAJA; DOUGLIN, JOHN C.; BARBOSA, ANDREY S.; DE SOUSA JR, ROGERIO R.; RODRIGUES JR, ORLANDO; LANFREDI, ALEXANDRE J. C.; DEKEL, DARIO R.; SANTIAGO, ELISABETE I.. High-performance radiation grafted anion-exchange membranes for fuel cell applications: Effects of irradiation conditions on ETFE-based membranes properties. JOURNAL OF MEMBRANE SCIENCE, v. 641, JAN 1 2022. (19/26955-3, 14/09087-4, 17/11937-4)

DE SOUZA, RODRIGO F. B.; MAIA, VICTORIA A.; ZAMBIAZZI, PRISCILLA J.; OTUBO, LARISSA; LAZAR, DOLORES R. R.; NETO, ALMIR O.. Facile, clean and rapid exfoliation of boron-nitride using a non-thermal plasma process. MATERIALS TODAY ADVANCES, v. 12, DEC 2021. (14/09087-4, 14/50279-4, 17/11937-4)

BIANCOLLI, ANA LAURA G.; BARBOSA, ANDREY S.; KODAMA, YASKO; DE SOUSA, JR., ROGERIO R.; LANFREDI, ALEXANDRE J. C.; FONSECA, FABIO C.; REY, JOSE FERNANDO Q.; SANTIAGO, ELISABETE I.. Unveiling the influence of radiation-induced grafting methods on the properties of polyethylene-based anion-exchange membranes for alkaline fuel cells. Journal of Power Sources, v. 512, NOV 15 2021. (19/26955-3, 14/09087-4, 17/11937-4)

ESPOSITO, VINCENZO; KABIR, AHSANUL; ROSA, MASSIMO; NONG, NGO VAN; RODRIGUES, THENNER S.; RODRIGUES, LAYS N.; MACHADO, MARINA F. S.; MORAES, LETICIA P. R.; MARANI, DEBORA; FONSECA, FABIO CORAL. Tuning diffusion paths in shaped ceria nanocrystals. CrystEngComm, v. 21, n. 27, p. 4025-4029, JUL 21 2019. (14/50279-4, 17/11937-4, 14/09087-4, 17/04929-5, 19/04499-6)

SANTOS, MONIQUE C. L.; NUNES, LIVIA C.; SILVA, LUIS M. G.; RAMOS, ANDREZZA S.; FONSECA, FABIO C.; DE SOUZA, RODRIGO F. B.; NETO, ALMIR O.. Direct Alkaline Anion Exchange Membrane Fuel Cell to Converting Methane into Methanol. CHEMISTRYSELECT, v. 4, n. 39, p. 11430-11434, OCT 24 2019. (14/50279-4, 17/11937-4, 14/09087-4)

LOPES, THIAGO; BERUSKI, OTAVIO; MANTHANWAR, AMIT M.; KORKISCHKO, IVAN; PUGLIESI, REYNALDO; STANOJEV, MARCO ANTONIO; GARCIA ANDRADE, MARCOS LEANDRO; PISTIKOPOULOS, EFSTRATIOS N.; PEREZ, JOELMA; FONSECA, FABIO CORAL; et al. Spatially resolved oxygen reaction, water, and temperature distribution: Experimental results as a function of flow field and implications for polymer electrolyte fuel cell operation. APPLIED ENERGY, v. 252, OCT 15 2019. (16/12397-0, 13/11316-9, 14/50279-4, 14/09087-4, 17/11937-4, 14/22130-6, 17/15304-6)

MATOS, BRUNO R.; POLITANO, RODOLFO; REY, JOSE FERNANDO Q.; HERMIDA-MERINO, DANIEL; SCHADE, ULRICH; PUSKAR, LJILJANA; FONSECA, FABIO C.. Interplay of alpha/beta-Relaxation Dynamics and the Shape of Ionomer Building Blocks. SCIENTIFIC REPORTS, v. 8, SEP 7 2018. (14/50279-4, 16/14785-8, 14/09087-4, 13/50151-5)

LIMA DOS SANTOS, MONIQUE CAROLINA; DUTRA, RITA MARIA; RIBEIRO, VILMARIA APARECIDA; SPINACE, ESTEVAM VITORIO; NETO, ALMIR OLIVEIRA. Preparation of PtRu/C Electrocatalysts by Borohydride Reduction for Methanol Oxidation in Acidic and Alkaline Medium. International Journal of Electrochemical Science, v. 12, n. 5, p. 3549-3560, MAY 2017. (14/50279-4, 14/09087-4)

SILVA, JULIO CESAR M.; NTAIS, SPYRIDON; RAJARAMAN, VISHWANATHAN; TEIXEIRA-NETO, ERICO; TEIXEIRA-NETO, ANGELA A.; NETO, ALMIR O.; ANTONIASSI, RODOLFO M.; SPINACE, ESTEVAM V.; BARANOVA, ELENA A.. The Catalytic Activity of Pt:Ru Nanoparticles for Ethylene Glycol and Ethanol Electrooxidation in a Direct Alcohol Fuel Cell. ELECTROCATALYSIS, v. 10, n. 3, p. 203-213, MAY 2019. (14/09087-4, 14/09868-6)

RODRIGUES, THENNER S.; E SILVA, FELIPE A.; CANDIDO, EDUARDO G.; DA SILVA, ANDERSON G. M.; GEONMONOND, RAFAEL DOS S.; CAMARGO, PEDRO H. C.; LINARDI, MARCELO; FONSECA, FABIO C.. Ethanol steam reforming: understanding changes in the activity and stability of Rh/MxOy catalysts as function of the support. Journal of Materials Science, v. 54, n. 17, p. 11400-11416, SEP 2019. (15/26308-7, 14/50279-4, 17/04929-5, 14/09087-4)

NANDENHA, J.; PIASENTIN, R. M.; SILVA, L. M. G.; FONTES, E. H.; NETO, A. O.; DE SOUZA, R. F. B.. Partial oxidation of methane and generation of electricity using a PEMFC. IONICS, v. 25, n. 10, p. 5077-5082, OCT 2019. (14/09087-4, 17/11937-4, 14/50279-4)

GONCALVES BIANCOLLI, ANA LAURA; HERRANZ, DANIEL; WANG, LIANQIN; STEHLIKOVA, GABRIELA; BANCE-SOUALHI, RACHIDA; PONCE-GONZALEZ, JULIA; OCON, PILAR; TICIANELLI, EDSON A.; WHELLIGAN, DANIEL K.; VARCOE, JOHN R.; et al. ETFE-based anion-exchange membrane ionomer powders for alkaline membrane fuel cells: a first performance comparison of head-group chemistry. JOURNAL OF MATERIALS CHEMISTRY A, v. 6, n. 47, p. 24330-24341, DEC 21 2018. (15/09210-3, 15/23621-6, 14/09087-4, 14/50279-4, 16/13277-9)

SILVA, P. S. M.; ESPOSITO, V.; MARANI, D.; DE FLORIO, D. Z.; MACHADO, I. F.; FONSECA, F. C.. Thermochemical stability of zirconia-titanium nitride as mixed ionic-electronic composites. CERAMICS INTERNATIONAL, v. 44, n. 7, p. 8440-8446, MAY 2018. (14/50279-4, 15/20434-0, 14/09087-4)

ANTONIASSI, R. M.; OTUBO, L.; VAZ, J. M.; OLIVEIRA NETO, A.; SPINACE, E. V.. Synthesis of Pt nanoparticles with preferential (100) orientation directly on the carbon support for Direct Ethanol Fuel Cell. JOURNAL OF CATALYSIS, v. 342, p. 67-74, OCT 2016. (14/09087-4)

DA SILVA, A. A. A.; BION, N.; EPRON, F.; BARAKA, S.; FONSECA, F. C.; RABELO-NETO, R. C.; MATTOS, L. V.; NORONHA, F. B.. Effect of the type of ceria dopant on the performance of Ni/CeO2 SOFC anode for ethanol internal reforming. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 206, p. 626-641, JUN 5 2017. (13/26961-7, 14/09087-4)

MATOS, BRUNO R.; DA SILVA, JAQUELINE S.; SANTIAGO, ELISABETE I.; PARRA, DUCLERC F.; CARASTAN, DANILO J.; DE FLORIO, DANIEL Z.; ANDRADA, HEBER E.; CARRERAS, ALEJO C.; FONSECA, FABIO C.. Proton and cesium conductivity in perfluorosulfonate ionomers at low and high relative humidity. Solid State Ionics, v. 301, p. 86-94, MAR 2017. (14/50279-4, 14/09087-4, 13/50151-5)

OTTONI, CRISTIANE ANGELICA; DE SOUZA, RODINEY RANDELLO; DA SILVA, SIRLANE GOMES; SPINACE, ESTEVAN VITORIO; BRAMBILLA DE SOUZA, RODRIGO FERNANDO; NETO, ALMIR OLIVEIRRA. Performance of Pd Electrocatalyst Supported on a Physical Mixture Indium Tin Oxide-carbon for Glycerol Electro-oxidation in Alkaline Media. Electroanalysis, v. 29, n. 4, p. 960-964, APR 2017. (14/50279-4, 14/09087-4)

MATOS, BRUNO R.; DRESCH, MAURO A.; SANTIAGO, ELISABETE I.; MORAES, LETICIA P. R.; CARASTAN, DANILO J.; SCHOENMAKER, JEROEN; VELASCO-DAVALOS, IVAN A.; RUEDIGER, ANDREAS; TAVARES, ANA C.; FONSECA, FABIO C.. Nafion membranes annealed at high temperature and controlled humidity: structure, conductivity, and fuel cell performance. Electrochimica Acta, v. 196, p. 110-117, APR 1 2016. (14/50279-4, 14/09087-4, 13/50151-5)

PINHEIRO, L. B.; TABUTI, F. N.; MARTINELLI, A. E.; FONSECA, F. C.. Influence of microwave-assisted hydrothermal treatment on the properties of nickel oxide-zirconia based composites. CERAMICS INTERNATIONAL, v. 42, n. 7, p. 9058-9064, MAY 15 2016. (13/26961-7, 14/50279-4, 14/09087-4)

FERREIRA, JOAO C.; CAVALLARI, V, ROGER; BERGAMASCHI, VANDERLEI S.; ANTONIASSI, RODOLFO M.; TEIXEIRA-NETO, ANGELA A.; LINARDI, MARCELO; SILVA, JULIO CESAR M.. Palladium nanoparticles supported on mesoporous biocarbon from coconut shell for ethanol electro-oxidation in alkaline media. MATERIALS FOR RENEWABLE AND SUSTAINABLE ENERGY, v. 7, n. 4, NOV 2018. (17/15469-5, 14/09087-4)

PANESI, A. R. Q.; SILVA, R. P.; CUNHA, E. F.; KORKISCHKO, I.; SANTIAGO, E. I.. Three-dimensional CFD modeling of H-2/O-2 HT-PEMFC based on H3PO4-doped PBI membranes. IONICS, JUN 2021. (14/09087-4, 17/11937-4, 14/50279-4, 16/12397-0)