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Fabrication and characterization of devices and systems based on hybrid nanomembranes

Abstract

Nanomembranes are freestanding nanostructures with mescopic thicknesses and with lateral dimensions in the macroscopic range. By strain and stress engineering inside the nanomembranes, self-assembled three-dimensional (3D) structures, such as microtubes and micro-ribbons, can be formed. Since the patterning methods used for manufacturing the nanomembranes are the same ones employed in standard microfabrication processes, the creation of 3D devices based on microtubes and micro-ribbons is a typical case where bottom-up and top-down methods are combined to give rise to novel technologies. In this proposal, we intend to implement and consolidate the processes of synthesis, patterning and characterization of hybrid organic/inorganic nanomembranes, as well as their application in electronic, electrochemical and microfluidic devices at LNNano/CNPEM. Three categories of demonstrators are proposed in order to solidify the fabrication processes: a) Ultra-compact elements, such as supercapacitors and organic transistors, which use the mechanical flexibility of the nanomembranes to reduce the devices footprint. b) Sensors that exploit the quasi-bidimensional nature of the nanomembranes to improve their performance and to incorporate different functionalities. c) Hybrid organic/inorganic heterojunctions, that uses the mechanical flexibility of the nanomembrane, associated with their patterning and integration capabilities, to generate robust devices on-a-chip exhibiting novel physical and chemical properties. (AU)

Articles published in Agência FAPESP Newsletter about the research grant:
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Scientific publications (42)
(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)
BARCELOS, INGRID D.; CADORE, ALISSON R.; ALENCAR, ANANIAS B.; MAIA, FRANCISCO C. B.; MANIA, EDRIAN; OLIVEIRA, RAFAEL F.; BUFON, CARLOS C. B.; MALACHIAS, ANGELO; FREITAS, RAUL O.; MOREIRA, ROBERTO L.; et al. Infrared Fingerprints of Natural 2D Talc and Plasmon-Phonon Coupling in Graphene-Talc Heterostructures. ACS PHOTONICS, v. 5, n. 5, SI, p. 1912-1918, . (14/25979-2)
FERRO, LETICIA M. M.; MERCES, LEANDRO; DE CAMARGO, DAVI H. S.; BUFON, CARLOS C. B.. Ultrahigh-Gain Organic Electrochemical Transistor Chemosensors Based on Self-Curled Nanomembranes. Advanced Materials, . (17/21117-4, 13/22127-2, 14/25979-2, 14/50906-9, 18/18136-0)
SANTHIAGO, MURILO; CORREA, CATIA C.; BERNARDES, JULIANA S.; PEREIRA, MARIANE P.; OLIVEIRA, LETICIA J. M.; STRAUSS, MATHIAS; BUFON, CARLOS C. B.. Flexible and Foldable Fully-Printed Carbon Black Conductive Nanostructures on Paper for High-Performance Electronic, Electrochemical, and Wearable Devices. ACS APPLIED MATERIALS & INTERFACES, v. 9, n. 28, p. 24365-24372, . (14/25979-2, 09/54066-7, 13/22127-2)
MERCES, LEANDRO; DE OLIVEIRA, RAFAEL FURLAN; GOMES, HENRIQUE LEONEL; BOF BUFON, CARLOS CESAR. The role of the electrode configuration on the electrical properties of small-molecule semiconductor thin-films. ORGANIC ELECTRONICS, v. 49, p. 107-113, . (14/25979-2)
VELLO, TATIANA P.; DE OLIVEIRA, RAFAEL F.; SILVA, GUSTAVO O.; DE CAMARGO, DAVI H. S.; BUFON, CARLOS C. B.. A simple capacitive method to evaluate ethanol fuel samples. SCIENTIFIC REPORTS, v. 7, . (14/25979-2, 13/22127-2)
DE MORAIS, VITORIA BRITO; CORREA, CATIA CRISPILHO; LANZONI, EVANDRO MARTIN; RODRIGUES COSTA, CARLOS ALBERTO; BOF BUFON, CARLOS CESAR; SANTHIAGO, MURILO. Wearable binary cooperative polypyrrole nanofilms for chemical mapping on skin. JOURNAL OF MATERIALS CHEMISTRY A, v. 7, n. 10, p. 5227-5233, . (14/25979-2, 13/22127-2)
POZZOLI, GUILHERME L.; MERCES, LEANDRO; YASSITEPE, EMRE; DE MORAIS, VITORIA B.; DE CAMARGO, DAVI H. S.; BUFON, CARLOS C. BOF. Charge Transport and Gradient Doping in Nanostructured Polypyrrole Films for Applications in Photocurrent Generation. ACS APPLIED NANO MATERIALS, v. 3, n. 3, p. 3060-3070, . (18/18136-0, 14/25979-2, 14/50906-9)
JIMENEZ, MAWIN J. M.; DE OLIVEIRA, RAFAEL F.; SHIMIZU, FLAVIO M.; BUFON, CARLOS CESAR B.; RODRIGUES, VARLEI; GOBBI, ANGELO L.; PIAZZETTA, MARIA H. O.; RIUL JR, ANTONIO. Poole-Frenkel emission on functionalized, multilayered-packed reduced graphene oxide nanoplatelets. Nanotechnology, v. 29, n. 50, . (14/25979-2, 14/03691-7)
MERCES, LEANDRO; DE OLIVEIRA, RAFAEL FURLAN; BOF BUFON, CARLOS CESAR. Nanoscale Variable-Area Electronic Devices: Contact Mechanics and Hypersensitive Pressure Application. ACS APPLIED MATERIALS & INTERFACES, v. 10, n. 45, p. 39168-39176, . (14/25979-2, 13/22127-2)
ALBANO, LUIZ G. S.; VELLO, TATIANA P.; DE CAMARGO, DAVI H. S.; DA SILVA, RICARDO M. L.; PADILHA, ANTONIO C. M.; FAZZIO, ADALBERTO; BUFON, CARLOS C. B.. Ambipolar Resistive Switching in an Ultrathin Surface-Supported Metal-Organic Framework Vertical Heterojunction. Nano Letters, v. 20, n. 2, p. 1080-1088, . (17/25553-3, 14/50906-9, 17/02317-2, 16/25346-5, 14/25979-2, 18/05565-0)
BREGADIOLLI, BRUNA ANDRESSA; PAULIN, JOAO VITOR; ALBANO, LUIZ GUSTAVO SIMAO; MARTINS, LUCAS MICHELAO; DE CAMARGO, DAVI HENRIQUE STARNINI; DA SILVA-FILHO, LUIZ CARLOS; BUFON, CARLOS CESAR BOF; GRAEFF, CARLOS FREDERICO DE OLIVEIRA. A strategy towards melanin-based functional material: rGO and sulfonated melanin composites. JOURNAL OF MATERIALS CHEMISTRY C, v. 9, n. 47, . (17/07627-0, 18/09235-4, 13/07296-2, 14/25979-2, 17/25553-3, 15/23000-1)
JIMENEZ, MAWIN J. M.; OLIVEIRA, RAFAEL F.; ALMEIDA, TIAGO P.; HENSEL FERREIRA, RAFAEL C.; BUFON, CARLOS CESAR B.; RODRIGUES, VARLEI; PEREIRA-DA-SILVA, MARCELO A.; GOBBI, ANGELO L.; PIAZZETTA, MARIA H. O.; RIUL, JR., ANTONIO. Charge carrier transport in defective reduced graphene oxide as quantum dots and nanoplatelets in multilayer films. Nanotechnology, v. 28, n. 49, . (14/25979-2, 14/03691-7)
BAR, JACIARA; DE BARROS, ANERISE; DE CAMARGO, DAVI H. S.; PEREIRA, MARIANE P.; MERCES, LEANDRO; SHIMIZU, FLAVIO MAKOTO; SIGOLI, FERNANDO A.; BOF BUFON, CARLOS CESAR; MAZALI, ITALO ODONE. Silicon Microchannel-Driven Raman Scattering Enhancement to Improve Gold Nanorod Functions as a SERS Substrate toward Single-Molecule Detection. ACS APPLIED MATERIALS & INTERFACES, v. 13, n. 30, p. 36482-36491, . (14/25979-2, 14/50906-9, 18/18136-0, 13/22127-2)
PAULIN, JOAO V.; BUFON, CARLOS C. B.. Sustainable brain-inspired electronics: digging into natural biomaterials for healthcare applications. RSC SUSTAINABILITY, v. 2, n. 11, p. 29-pg., . (20/15869-6, 14/25979-2, 23/09820-2)
BARCELOS, INGRID D.; CADORE, ALISSON R.; ALENCAR, ANANIAS B.; MAIA, FRANCISCO C. B.; MANIA, EDRIAN; OLIVEIRA, RAFAEL F.; BUFON, CARLOS C. B.; MALACHIAS, ANGELO; FREITAS, RAUL O.; MOREIRA, ROBERTO L.; et al. Infrared Fingerprints of Natural 2D Talc and Plasmon-Phonon Coupling in Graphene-Talc Heterostructures. ACS PHOTONICS, v. 5, n. 5, p. 13-pg., . (14/25979-2)
DA SILVA, RICARDO M. L.; ALBANO, LUIZ G. S.; VELLO, TATIANA P.; DE ARAUJO, WAGNER W. R.; DE CAMARGO, DAVI H. S.; PALERMO, LEIRSON D.; CORREA, CATIA C.; WOELL, CHRISTOF; BUFON, CARLOS C. B.. Surface-Supported Metal-Organic Framework as Low-Dielectric-Constant Thin Films for Novel Hybrid Electronics. ADVANCED ELECTRONIC MATERIALS, v. N/A, p. 12-pg., . (16/25346-5, 14/25979-2, 17/02317-2, 17/25553-3, 14/50906-9)
PAULIN, JOAO V.; ALBANO, LUIZ G. S.; CAMARGO, DAVI H. S.; PEREIRA, MARIANE P.; BREGADIOLLI, BRUNA A.; GRAEFF, CARLOS F. O.; BUFON, CARLOS C. B.. Eumelanin-based multisensory platform: A case of study for photolithographic patterning. APPLIED MATERIALS TODAY, v. 28, p. 9-pg., . (20/15869-6, 17/07627-0, 14/25979-2, 17/02317-2, 17/25553-3)
FINGOLO, ANA C.; DE MORAIS, VITORIA B.; COSTA, V, SAIONARA; CORREA, CATIA C.; LODI, BEATRIZ; SANTHIAGO, MURILO; BERNARDES, JULIANA S.; BUFON, CARLOS C. B.. Enhanced Hydrophobicity in Nanocellulose-Based Materials: Toward Green Wearable Devices. ACS APPLIED BIO MATERIALS, v. 4, n. 9, p. 6682-6689, . (14/25979-2, 16/04514-7, 14/50906-9)
MERCES, LEANDRO; CANDIOTTO, GRAZIANI; MINATOGAU FERRO, LETICIA MARIE; DE BARROS, ANERISE; SANTOS BATISTA, CARLOS VINICIUS; NAWAZ, ALI; RIUL JR, ANTONIO; CAPAZ, RODRIGO B.; BOF BUFON, CARLOS CESAR. Reorganization Energy upon Controlled Intermolecular Charge-Transfer Reactions in Monolithically Integrated Nanodevices. SMALL, v. 17, n. 45, . (14/25979-2, 18/18136-0, 14/50906-9, 19/10188-3, 17/02317-2, 17/21117-4, 19/14949-9)
ALBANO, LUIZ G. S.; DE CAMARGO, DAVI H. S.; SCHLEDER, GABRIEL R.; DEEKE, SAMANTHA G.; VELLO, TATIANA P.; PALERMO, LEIRSON D.; CORREA, CATIA C.; FAZZIO, ADALBERTO; WOELL, CHRISTOF; BUFON, CARLOS C. B.. Room-Temperature Negative Differential Resistance in Surface-Supported Metal-Organic Framework Vertical Heterojunctions. SMALL, v. 17, n. 35, . (17/18139-6, 14/25979-2, 16/25346-5, 14/50906-9, 19/01561-2, 17/02317-2, 17/25553-3)
DAMASCENO, SERGIO; CORREA, CATIA CRISPILHO; GOUVEIA, RUBIA FIGUEREDO; STRAUSS, MATHIAS; BOF BUFON, CARLOS CESAR; SANTHIAGO, MURILO. Delayed Capillary Flow of Elastomers: An Efficient Method for Fabrication and Nanofunctionalization of Flexible, Foldable, Twistable, and Stretchable Electrodes from Pyrolyzed Paper. ADVANCED ELECTRONIC MATERIALS, v. 6, n. 1, . (14/25979-2, 13/22127-2)
NAWAZ, ALI; MERCES, LEANDRO; DE ANDRADE, DENISE M.; DE CAMARGO, DAVI H. S.; BOF BUFON, CARLOS C.. Edge-driven nanomembrane-based vertical organic transistors showing a multi-sensing capability. NATURE COMMUNICATIONS, v. 11, n. 1, . (14/25979-2, 16/25346-5, 14/50906-9, 18/18136-0)
VELLO, TATIANA PARRA; STRAUSS, MATHIAS; RODRIGUES COSTA, CARLOS ALBERTO; CORREA, CATIA CRISPILHO; BOF BUFON, CARLOS CESAR. Deterministic control of surface mounted metal-organic framework growth orientation on metallic and insulating surfaces. Physical Chemistry Chemical Physics, v. 22, n. 10, p. 5839-5846, . (14/25979-2, 16/25346-5, 14/50906-9)
TORIKAI, KLEYTON; DE OLIVEIRA, RAFAEL FURLAN; STARNINI DE CAMARGO, DAVI H.; BOF BUFON, CARLOS C.. Low-Voltage, Flexible, and Self-Encapsulated Ultracompact Organic Thin-Film Transistors Based on Nanomembranes. Nano Letters, v. 18, n. 9, p. 5552-5561, . (14/25979-2)
JIMENEZ, MAWIN J. M.; DE OLIVEIRA, RAFAEL F.; BUFON, CARLOS CESAR B.; PEREIRA-DA-SILVA, MARCELO A.; RODRIGUES, VARLEI; GOBBI, ANGELO L.; PIAZZETTA, MARIA H. O.; ALVAREZ, FERNANDO; CESAR, CARLOS LENZ; RIUL JR, ANTONIO. Enhanced mobility and controlled transparency in multilayered reduced graphene oxide quantum dots: a charge transport study. Nanotechnology, v. 30, n. 27, . (14/25979-2, 14/03691-7)
MERCES, LEANDRO; DE OLIVEIRA, RAFAEL FURLAN; STARNINI DE CAMARGO, DAVI HENRIQUE; BOF BUFON, CARLOS CESAR. Long-Range Coherent Tunneling in Physisorbed Molecular Ensembles. Journal of Physical Chemistry C, v. 121, n. 31, p. 16673-16681, . (14/25979-2)
LOPES, CAROLINA SERGI; MERCES, LEANDRO; DE OLIVEIRA, RAFAEL FURLAN; STARNINI DE CAMARGO, DAVI HENRIQUE; BOF BUFON, CARLOS CESAR. Rectification ratio and direction controlled by temperature in copper phthalocyanine ensemble molecular diodes. NANOSCALE, v. 12, n. 18, p. 10001-10009, . (16/25346-5, 14/25979-2, 14/50906-9, 18/18136-0)
SANTHIAGO, MURILO; DA COSTA, PRISCILA G.; PEREIRA, MARIANE P.; CORREA, CATIA C.; DE MORAIS, VITCORIA B.; BUFON, CARLOS C. B.. Versatile and Robust Integrated Sensors To Locally Assess Humidity Changes in Fully Enclosed Paper-Based Devices. ACS APPLIED MATERIALS & INTERFACES, v. 10, n. 41, p. 35631-35638, . (14/25979-2, 13/22127-2)
SILVA, RICARDO M. L.; MERCES, LEANDRO; BOF BUFON, CARLOS C.. Temperature-Independent Polarization of Ultrathin Phthalocyanine-Based Hybrid Organic/Inorganic Heterojunctions. ACS APPLIED MATERIALS & INTERFACES, v. 12, n. 26, p. 29556-29565, . (18/18136-0, 14/25979-2, 14/50906-9)
PETRINI, PAULA A.; SILVA, RICARDO M. L.; DE OLIVEIRA, RAFAEL F.; MERCES, LEANDRO; BOF BUFON, CARLOS C.. Hybrid nanomembrane-based capacitors for the determination of the dielectric constant of semiconducting molecular ensembles. Nanotechnology, v. 29, n. 26, . (14/25979-2)
SANTHIAGO, MURILO; STRAUSS, MATHIAS; PEREIRA, MARIANE P.; CHAGAS, ANDREIA S.; BUFON, CARLOS C. B.. Direct Drawing Method of Graphite onto Paper for High-Performance Flexible Electrochemical Sensors. ACS APPLIED MATERIALS & INTERFACES, v. 9, n. 13, p. 11959-11966, . (14/25979-2, 09/54066-7, 13/22127-2)
VELLO, TATIANA P.; DA SILVA, LARISSA M. B.; SILVA, GUSTAVO O.; DE CAMARGO, DAVI H. S.; CORREA, CATIA C.; BOF BUFON, CARLOS C.. Hybrid organic/inorganic interfaces as reversible label-free platform for direct monitoring of biochemical interactions. BIOSENSORS & BIOELECTRONICS, v. 87, p. 209-215, . (14/25979-2, 13/22127-2)
DE OLIVEIRA, RAFAEL FURLAN; MERCES, LEANDRO; MARQUES, FELIPE; TEIXEIRA-NETO, ERICO; STARNINI DE CAMARGO, DAVI HENRIQUE; BOF BUFON, CARLOS CESAR. Single-Electron Charging Effects in Hybrid Organic/Inorganic Nanomembrane-Based Junctions. Journal of Physical Chemistry C, v. 122, n. 23, p. 12131-12139, . (14/25979-2)
DE ANDRADE, DENISE MARIA; MERCES, LEANDRO; NAWAZ, ALI; BUFON, CARLOS CESAR BOF. Pushing On-Chip Photosensitivity Forward Using Edge-Driven Vertical Organic Phototransistors. ACS APPLIED ELECTRONIC MATERIALS, v. 5, n. 6, p. 10-pg., . (19/14949-9, 17/02317-2, 14/50906-9, 18/18136-0, 14/25979-2)
SANTOS BATISTA, CARLOS VINICIUS; MERCES, LEANDRO; RODRIGUES COSTA, CARLOS ALBERTO; STARNINI DE CAMARGO, DAVI HENRIQUE; BOF BUFON, CARLOS CESAR. High-Performance Ultrathin Molecular Rectifying Diodes Based on Organic/Inorganic Interface Engineering. ADVANCED FUNCTIONAL MATERIALS, v. 32, n. 6, . (14/50906-9, 14/25979-2, 19/10188-3, 18/18136-0)
MINATOGAU FERRO, LETICIA MARIE; DE BARROS, ANERISE; ZAPAROLI FALSETTI, LUIS OTAVIO; CORREA, CATIA CRISPILHO; MERCES, LEANDRO; BOF BUFON, CARLOS CESAR. Highly efficient electrochemical energy conversion in a 3D hollow microenvironment: towards on-a-chip sensor applications. JOURNAL OF MATERIALS CHEMISTRY A, v. 8, n. 38, p. 11-pg., . (18/18136-0, 14/50906-9, 17/21117-4, 14/25979-2)
GUERRA, NAYRIM BRIZUELA; LIMA, JOAO VICTOR MORAIS; PAULIN, JOAO VITOR; NOZELLA, NATAN LUIZ; BORATTO, MIGUEL HENRIQUE; NOGUEIRA, GABRIEL LEONARDO; BUFON, CARLOS CESAR BOF; GRAEFF, CARLOS FREDERICO DE OLIVEIRA. Electrochemical behavior of non-functionalized and sulfonated melanins at different pH values. Polymer International, v. 73, n. 11, p. 9-pg., . (20/15869-6, 17/20809-0, 22/00410-3, 21/09207-3, 20/04721-8, 21/03379-7, 14/25979-2)
FERRO, LETICIA M. M.; MERCES, LEANDRO; DE CAMARGO, DAVI H. S.; BUFON, CARLOS C. B.. Ultrahigh-Gain Organic Electrochemical Transistor Chemosensors Based on Self-Curled Nanomembranes. Advanced Materials, v. 33, n. 29, . (14/25979-2, 13/22127-2, 14/50906-9, 18/18136-0, 17/21117-4)
VELLO, TATIANA PARRA; ALBANO, LUIZ GUSTAVO SIMAO; DOS SANTOS, THAMIRIS CESCON; COLLETTI, JULIA CANTOVITZ; SANTOS BATISTA, CARLOS VINICIUS; LEME, VITORIA FERNANDES CINTRA; DOS SANTOS, THAMIRIS COSTA; MIGUEL, MARIA PAULA DIAS CARNEIRO; DE CAMARGO, DAVI HENRIQUE STARNINI; BOF BUFON, CARLOS CESAR. Electrical Conductivity Boost: In Situ Polypyrrole Polymerization in Monolithically Integrated Surface-Supported Metal-Organic Framework Templates. SMALL, v. N/A, p. 14-pg., . (17/02317-2, 14/50906-9, 16/25346-5, 19/01561-2, 14/25979-2, 17/25553-3)
PAULIN, JOAO V.; BAYRAM, SINAN; GRAEFF, CARLOS F. O.; BUFON, CARLOS C. B.. Exploring the Charge Transport of a Natural Eumelanin for Sustainable Technologies. ACS APPLIED BIO MATERIALS, v. 6, n. 9, p. 5-pg., . (17/02317-2, 20/15869-6, 14/50906-9, 14/25979-2)
PAULIN, JOAO V.; PEREIRA, MARIANE P.; BREGADIOLLI, BRUNA A.; CACHANESKI-LOPES, JOAO P.; GRAEFF, CARLOS F. O.; BATAGIN-NETO, AUGUSTO; BUFON, CARLOS C. B.. Controlling ions and electrons in aqueous solution: an alternative point of view of the charge-transport behavior of eumelanin-inspired material. JOURNAL OF MATERIALS CHEMISTRY C, v. 11, n. 18, p. 12-pg., . (17/02317-2, 17/07627-0, 14/50906-9, 20/15869-6, 14/25979-2)
PAULIN, JOAO V.; GRAEFF, CARLOS F. O.; MOSTERT, A. BERNARDUS. Decoding eumelanin's spin label signature: a comprehensive EPR analysis. MATERIALS ADVANCES, v. 5, n. 4, p. 25-pg., . (20/15869-6, 14/25979-2, 13/07296-2)