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Vibrational spectroscopy with spatial resolution

Grant number: 16/21070-5
Support type:Research Projects - Thematic Grants
Duration: April 01, 2018 - March 31, 2023
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
Principal Investigator:Mauro Carlos Costa Ribeiro
Grantee:Mauro Carlos Costa Ribeiro
Home Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil
Co-Principal Investigators:Dalva Lucia Araujo de Faria ; Marcia Laudelina Arruda Temperini ; Paola Corio ; Paulo Sergio Santos ; Rômulo Augusto Ando
Assoc. researchers:Diego Pereira dos Santos ; Rômulo Augusto Ando
Associated grant(s):18/15987-9 - Frontiers and challenges of surface enhanced Raman spectroscopy (SERS), AV.EXT
18/08916-8 - Multi-user equipment approved in grant 16/21070-5: infrared spectrometer with microscope, model vertex, Bruker, AP.EMU
18/08917-4 - Multi-user equipment approved in grant 16/21070-5: Raman spectrometer, model MultiRam, Bruker, AP.EMU
18/08918-0 - Multi-user equipment approved in grant 16/21070-5: confocal Raman microscope, Witec, AP.EMU
Associated scholarship(s):20/06766-9 - Molecular dynamics of Deep Eutectic Solvents, BP.PD
19/21939-0 - Bimetallic anisotropic nanoparticles (Au/Pd) for the study of catalytic processes through surface enhanced Raman scattering, BP.PD
19/00207-0 - Density functional theory applyed to vibrational dynamics of crystals of ionic systems, BP.PD
+ associated scholarships 19/05989-7 - SERS performance of AuNP encapsulated in alginate and chitosan templates for drugs detection, BP.IC
18/25737-0 - Porous ionic liquids for the selective capture of gases, BP.DD
19/03371-6 - Investigation of the SERS and catalytic activity of plasmonic nanostructures in the degradation of organochlorine and organophosphorus pesticides, BP.DD
18/25422-9 - Biofilm synthesis based on lichen beta glucans: study of properties and identification of its vibrational signatures, BP.PD - associated scholarships

Abstract

Several research activities in the Laboratório de Espectroscopia Molecular, Instituto de Química, Universidade de São Paulo, LEM/IQ-USP, are related to infrared and Raman spectroscopy. Coupling of optical microscopes to infrared and Raman spectrometers provides to vibrational spectroscopy the spatial resolution of the order of micrometer or below micrometer, then combining molecular structure characterization and imaging. This work includes several research projects whose development need spectral and spatial resolutions. The work will be undertaken by a group of seven professors, and their undergraduate students, PhD students, and pos-docs, of Chemistry institutes at São Paulo and Campinas universities (USP and UNICAMP). In this work, the researches in vibrational microspectroscopy include studies on solid and fluid inclusions of the order of micrometers in natural crystals of geological interest, phase transitions and glass formation of ionic liquids under wide range of pressure and temperature, hybrid materials for absorption of gases, inorganic matrixes for modified releasing of drugs and their interface with live tissues, and degradation processes of cultural goods in the forensic area and identification of falsifications and frauds. Projects in surface enhanced Raman spectroscopy (SERS) will be undertaken aiming the understanding of fundamental issues related to the mechanism of signal intensification as well as several applications. The SERS effect relies on the morphology of colloidal nanoparticles or metallic surfaces, so that these will be studied aiming the best performance of such surfaces for new technologies. The high performance SERS systems to be studied in this project include anisotropic nanoparticles, polymers and metallic nanoparticles, and bimetallic nanoparticles. These systems will be applied for analysis of species of environmental and biological interests in the range of single molecule detection, catalytic processes, for instance, carbon dioxide hydrogenation to generate fuels, and in forensic applications. (AU)

Articles published in other media outlets (21 total):
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Portal Exame: Ciência e arte se aliam na restauração do quadro “Independência ou Morte” (17/Feb/2020)
Portal R7: Ciência e arte para restaurar o quadro Independência ou Morte (17/Feb/2020)
Folha.com: Pintura centenária do Museu Paulista passa por restauro; entenda o processo (17/Feb/2020)
Projeto Colabora: Ciência e arte na restauração de Independência ou Morte (28/Feb/2020)
Planeta online: Ciência e arte se aliam na restauração da tela “Independência ou Morte” (24/Feb/2020)
MSN: Ciência e arte se aliam na restauração da tela “Independência ou Morte” (24/Feb/2020)
Mix Vale: Restauração do quadro Independência ou Morte alia ciência e arte em SP (19/Feb/2020)
Nota Diária: Restauração do quadro Independência ou Morte alia ciência e arte em SP (19/Feb/2020)
Leia Já: Tela 'Independência ou Morte' passa por restauração em SP (19/Feb/2020)
Z1 Portal de Notícias: Restauração do quadro Independência ou Morte alia ciência e arte em SP (19/Feb/2020)
Primeira Edição: Restauração do quadro Independência ou Morte alia ciência e arte em SP (19/Feb/2020)
Central das Notícias: Tela 'Independência ou Morte' passa por restauração em SP (19/Feb/2020)
Portal do Governo do Estado de São Paulo: Restauração do quadro Independência ou Morte alia ciência e arte em SP (19/Feb/2020)
FM Metropolitana Online: Restauração do quadro Independência ou Morte alia ciência e arte em SP (19/Feb/2020)
Guajara Hoje: Ciência e arte para restaurar o quadro Independência ou Morte (18/Feb/2020)
LabNetwork: Ciência e arte se aliam na restauração do quadro Independência ou Morte (18/Feb/2020)
Interdependente: Arte e ciência aliadas na restauração do quadro "Independência ou morte" (17/Feb/2020)
MSN: Ciência e arte se aliam na restauração do quadro “Independência ou Morte” (17/Feb/2020)
JC Notícias (São Paulo, SP): Ciência e arte se aliam na restauração do quadro Independência ou Morte (17/Feb/2020)
Revista Museu: Ciência e arte se aliam na restauração do quadro 'Independência ou Morte' (17/Feb/2020)
TV Globo: Quadro centenário e emblemático da história brasileira é restaurado (16/Feb/2020)

Scientific publications (36)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
BERNARDINO, KALIL; ZHANG, YONG; RIBEIRO, MAURO C. C.; MAGINN, EDWARD J. Effect of alkyl-group flexibility on the melting point of imidazolium-based ionic liquids. Journal of Chemical Physics, v. 153, n. 4 JUL 28 2020. Web of Science Citations: 0.
RIBEIRO, MAURO C. C. Strong anion-anion hydrogen bond in the ionic liquid 1-ethyl-3-methylimidazolium hydrogen sulfate. JOURNAL OF MOLECULAR LIQUIDS, v. 310, JUL 15 2020. Web of Science Citations: 0.
RODRIGUES, BARBARA SCOLA; BRANCO, CAROLYNE MARTINS; CORIO, PAOLA; SOUZA, JULIANA S. Controlling Bismuth Vanadate Morphology and Crystalline Structure through Optimization of Microwave-Assisted Synthesis Conditions. Crystal Growth & Design, v. 20, n. 6, p. 3673-3685, JUN 3 2020. Web of Science Citations: 0.
LEPRE, LUIZ FERNANDO; COSTA GOMES, MARGARIDA; ANDO, ROMULO AUGUSTO. Probing the Reorganization of Ionic Liquids' Structure Induced by CO2 Sorption. ChemPhysChem, v. 21, n. 12 MAY 2020. Web of Science Citations: 0.
LIMA, THAMIRES A.; PASCHOAL, VITOR H.; FREITAS, RAFAEL S.; FARIA, LUIZ F. O.; LI, ZHIXIA; TYAGI, MADHUSUDAN; RIBEIRO, MAURO C. C. An inelastic neutron scattering, Raman, far-infrared, and molecular dynamics study of the intermolecular dynamics of two ionic liquids. Physical Chemistry Chemical Physics, v. 22, n. 16, p. 9074-9085, APR 28 2020. Web of Science Citations: 0.
PASTORELLO, MURILO; SIGOLI, FERNANDO A.; DOS SANTOS, DIEGO P.; MAZALI, ITALO O. On the use of Au@Ag core-shell nanorods for SERS detection of Thiram diluted solutions. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 231, APR 15 2020. Web of Science Citations: 0.
PASCHOAL, VITOR H.; RIBEIRO, MAURO C. C. Pseudo-Optical Modes in Room-Temperature Ionic Liquids. Journal of Physical Chemistry B, v. 124, n. 13, p. 2661-2667, APR 2 2020. Web of Science Citations: 0.
DOS SANTOS, DIEGO PEREIRA. Statistical Analysis of Surface-Enhanced Raman Scattering Enhancement Distributions. Journal of Physical Chemistry C, v. 124, n. 12, p. 6811-6821, MAR 26 2020. Web of Science Citations: 0.
BERNARDINO, KALIL; GOLOVIZNINA, KATERYNA; GOMES, MARGARIDA COSTA; PADUA, AGILIO A. H.; RIBEIRO, MAURO C. C. Ion pair free energy surface as a probe of ionic liquid structure. Journal of Chemical Physics, v. 152, n. 1 JAN 7 2020. Web of Science Citations: 0.
DOS SANTOS, ISABELA F. S.; TEMPERINI, MARCIA L. A. Investigation of the correlation between chemical structure and morphology in oligoaniline microspheres produced in buffered conditions. EUROPEAN POLYMER JOURNAL, v. 122, JAN 5 2020. Web of Science Citations: 0.
VILLA, JAVIER E. L.; AFONSO, MARCO A. S.; DOS SANTOS, DIEGO P.; MERCADAL, PABLO A.; CORONADO, EDUARDO A.; POPPI, RONEI J. Colloidal gold clusters formation and chemometrics for direct SERS determination of bioanalytes in complex media. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 224, JAN 5 2020. Web of Science Citations: 0.
SOUZA, KLESTER S.; TEIXEIRA-NETO, ERICO; TEMPERINI, MARCIA L. A.; DOS SANTOS, DIEGO P. Interplay between Near-Field Properties and Au Nanorod Cluster Structure: Extending Hot Spots for Surface-Enhanced Raman Scattering. Journal of the Brazilian Chemical Society, v. 30, n. 12, SI, p. 2624-2633, DEC 2019. Web of Science Citations: 0.
BERNARDINO, KALIL; LIMA, THAMIRES A.; RIBEIRO, MAURO C. C. Low-Temperature Phase Transitions of the Ionic Liquid 1-Ethyl-3-methylimidazolium Dicyanamide. Journal of Physical Chemistry B, v. 123, n. 44, p. 9418-9427, NOV 7 2019. Web of Science Citations: 0.
AMEKU, WILSON A.; DE ARAUJO, WILLIAM R.; RANGEL, CLARA J.; ANDO, ROMULO A.; PAIXAO, THIAGO R. L. C. Gold Nanoparticle Paper-Based Dual-Detection Device for Forensics Applications. ACS APPLIED NANO MATERIALS, v. 2, n. 9, p. 5460-5468, SEP 2019. Web of Science Citations: 0.
SANTOS, JONNATAN J.; TOMA, SERGIO H.; MONEZI, NATALIA M.; ANDO, ROMULO A.; CORIO, PAOLA; ARAKI, KOITI. Selecting the Mechanism of Surface-Enhanced Raman Scattering Effect using Shell Isolated Nanoparticles and an Oxo-Triruthenium Acetate Cluster Complex. Inorganic Chemistry, v. 58, n. 15, p. 10399-10407, AUG 5 2019. Web of Science Citations: 0.
LEPRE, LUIZ F.; GOMES, MARGARIDA COSTA; PADUA, AGILIO A. H.; ANDO, ROMULO A.; RIBEIRO, MAURO C. C. On the Regular Behavior of a Binary Mixture of Ionic Liquids. Journal of Physical Chemistry B, v. 123, n. 30, p. 6579-6587, AUG 1 2019. Web of Science Citations: 1.
DE MATOS, CAROLINE S.; NOBREGA, MARCELO M.; TEMPERINI, MARCIA L. A.; CONSTANTINO, VERA R. L. Hybrid Ni-Al layered double hydroxide: Characterization and in situ synchrotron XRD and vibrational spectroscopic studies under high-pressure. APPLIED CLAY SCIENCE, v. 174, p. 152-158, JUN 15 2019. Web of Science Citations: 0.
LIMA, THAMIRES A.; FARIA, LUIZ F. O.; PASCHOAL, VITOR H.; RIBEIRO, MAURO C. C. Exploring the phase diagram of the ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesufonyl)imide. Journal of Molecular Structure, v. 1183, p. 149-156, MAY 5 2019. Web of Science Citations: 1.
LIMA, THAMIRES A.; RIBEIRO, MAURO C. C. Low-frequency Raman spectra of a glass-forming ionic liquid at low temperature and high pressure. Journal of Chemical Physics, v. 150, n. 16 APR 28 2019. Web of Science Citations: 0.
PENNA, TATIANA C.; RIBEIRO, MAURO C. C. Vibrational frequency shift of 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids under high pressure. JOURNAL OF MOLECULAR LIQUIDS, v. 278, p. 213-218, MAR 15 2019. Web of Science Citations: 1.
FARIA, LUIZ F. O.; NOBREGA, MARCELO M.; FALSINI, NAOMI; FANETTI, SAMUELE; TEMPERINI, MARCIA L. A.; BINI, ROBERTO; RIBEIRO, MAURO C. C. Structure and Reactivity of the Ionic Liquid 1-Allyl-3-methylimidazolium Iodide under High Pressure. Journal of Physical Chemistry B, v. 123, n. 8, p. 1822-1830, FEB 28 2019. Web of Science Citations: 0.
DOS SANTOS, PAMYLA L.; KATIC, VERA; LOUREIRO, HUGO C.; DOS SANTOS, MATHEUS F.; DOS SANTOS, DIEGO P.; FORMIGA, ANDRE L. B.; BONACIN, JULIANO A. Enhanced performance of 3D printed graphene electrodes after electrochemical pre-treatment: Role of exposed graphene sheets. SENSORS AND ACTUATORS B-CHEMICAL, v. 281, p. 837-848, FEB 15 2019. Web of Science Citations: 9.
SOUZA, JULIANA S.; HIRATA, FERNANDO T. H.; CORIO, PAOLA. Microwave-assisted synthesis of bismuth vanadate nanoflowers decorated with gold nanoparticles with enhanced photocatalytic activity. JOURNAL OF NANOPARTICLE RESEARCH, v. 21, n. 2 FEB 10 2019. Web of Science Citations: 1.
DOS SANTOS, DIEGO P.; TEMPERINI, MARCIA L. A.; BROLO, ALEXANDRE G. Intensity Fluctuations in Single-Molecule Surface-Enhanced Raman Scattering. ACCOUNTS OF CHEMICAL RESEARCH, v. 52, n. 2, p. 456-464, FEB 2019. Web of Science Citations: 6.
VIEIRA, EDUARDO GUIMARAES; MIGUEL, RODRIGO BERNARDI; DA SILVA, DANIEL RODRIGUES; FAZZI, RODRIGO BONI; ALVES DE COUTO, RICARDO ALEXANDRE; MARIN, JAYR HENRIQUE; ARRUDA TEMPERINI, MARCIA LAUDELINA; SHINOHARA, JORGE DA SILVA; TOMA, HENRIQUE EISI; RUSSO, LILIAN CRISTINA; MAGALHAES, YULI THAMIRES; DIAS FILHO, NEWTON LUIZ; FORTI, FABIO LUIZ; DA COSTA FERREIRA, ANA MARIA. Functionalized nanoparticles as adjuvant to increase the cytotoxicity of metallodrugs toward tumor cells. NEW JOURNAL OF CHEMISTRY, v. 43, n. 1, p. 386-398, JAN 7 2019. Web of Science Citations: 2.
MICHELE LEMOS DE SOUZA; PAOLA CORIO. INVESTIGAÇÃO DO SOLVATOCROMISMO E IONOCROMISMO DO CORANTE AZUL DO NILO ATRAVÉS DAS ESPECTROSCOPIAS RAMAN, INFRAVERMELHO E UV-VIS. Química Nova, v. 42, n. 9, p. 1091-1097, Set. 2019.
THIAGO S. PUGLIERI; RAUL DE O. FREITAS; FRANCISCO C. B. MAIA; DALVA L. A. DE FARIA. NANOESPECTROSCOPIA DE ABSORÇÃO DE RADIAÇÃO SÍNCROTRON NO INFRAVERMELHO PARA NANOESPECIAÇÃO DE PRODUTOS DE CORROSÃO METÁLICA. Química Nova, v. 42, n. 9, p. 1050-1055, Set. 2019.
DALVA L. A. DE FARIA; MARCIA L. A. TEMPERINI. HANS STAMMREICH: UM DOS PRESENTES DE HITLER. Química Nova, v. 42, n. 9, p. 991-992, Set. 2019.
DALVA L. A. DE FARIA. HANS STAMMREICH: UMA PERSPECTIVA HISTÓRICA. Química Nova, v. 42, n. 9, p. 993-1002, Set. 2019.
MARIA T. C. SANSIVIERO; CARLOS E. SAMPIETRI; MARCOS V. DA COSTA; NORMA C. CASSARES; DALVA L. A. FARIA. INVENTÁRIO DO SAPATEIRO DAMIÃO SIMÕES: UM ESTUDO FÍSICO-QUÍMICO DO DOCUMENTO MAIS ANTIGO DO ESTADO DE SÃO PAULO. Química Nova, v. 42, n. 9, p. 1104-1111, Set. 2019.
DAYANE V. N. DOS SANTOS; DIEGO P. DOS SANTOS. CORRELATING SINGLE-MOLECULE SERS STATISTICS TO PLASMONIC NANOCLUSTER STRUCTURE AND NEAR-FIELD PROPERTIES. Química Nova, v. 42, n. 9, p. 1029-1037, Set. 2019. Web of Science Citations: 0.
KLESTER S. SOUZA; ERICO TEIXEIRA-NETO; MARCIA L. A. TEMPERINI; DIEGO P. DOS SANTOS. Interplay between Near-Field Properties and Au Nanorod Cluster Structure: Extending Hot Spots for Surface-Enhanced Raman Scattering. Journal of the Brazilian Chemical Society, v. 30, n. 12, p. 2624-2633, Dez. 2019.
MÓNICA B. MAMIÁN-LÓPEZ; MARCIA L. A. TEMPERINI. HOTSPOT STABILIZATION OF GOLD NANOPARTICLES FOR APPLICATION OF QUANTITATIVE SERS IN BIOANALYTICAL SYSTEMS. Química Nova, v. 42, n. 9, p. 1084-1090, Set. 2019. Web of Science Citations: 0.
NATÁLIA M. MONEZI; LUIZ F. LEPRE; RÔMULO A. ANDO. UNRAVELING THE SOLVATOCHROMISM OF A TRIARYLMETHANE DYE BY RESONANCE RAMAN SPECTROSCOPY. Química Nova, v. 42, n. 9, p. 1116-1121, Set. 2019. Web of Science Citations: 0.
MAMIAN-LOPEZ, MONICA B.; TEMPERINI, MARCIA L. A. On the Cooperativity Effect in Watson and Crick and Wobble Pairs for a Halouracil Series and Its Potential Quantitative Application Studied through Surface-Enhanced Raman Spectroscopy. Analytical Chemistry, v. 90, n. 24, p. 14165-14172, DEC 18 2018. Web of Science Citations: 1.
DE SOUZA, MICHELE LEMOS; DOS SANTOS, DIEGO PEREIRA; CORIO, PAOLA. Localized surface plasmon resonance enhanced photocatalysis: an experimental and theoretical mechanistic investigation. RSC ADVANCES, v. 8, n. 50, p. 28753-28762, 2018. Web of Science Citations: 5.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.