Asymmetric strategies in A-3 coupling eactions

• Grant number: 11/03244-2
• Support Opportunities: Scholarships in Brazil - Master
• Start date: August 01, 2011
• End date: February 28, 2013
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Organic Chemistry
• Principal Investigator: Alcindo Aparecido dos Santos
• Grantee: Rafaela Costa Carmona
• Host Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil

Abstract

Desenvolvimento de métodos mais gerais de preparação de hidroxi-propargilaminas, incluindo as assimétricas opticamente ativas. Os produtos gerados dessas reações deverão ser empregados em resolução cinética enzimática para a obtenção dos produtos opticamente ativos, quando substratos racêmicos forem empregados. Também pretendemos preparar os correspondentes organocalcogenetos para empregá-los como substratos na preparação de materiais híbridos organo-inorgânicos nanoestruturados. (AU)

Scientific publications

(6)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

CARMONA, RAFAELA C.; SCHEVCIW, EVELYN P.; PETRARCA DE ALBUQUERQUE, JOAO L.; WENDLER, EDISON P.; DOS SANTOS, ALCINDO A.. Joint use of microwave and glycerol-zinc (II) acetate catalytic system in the synthesis of 2-pyridyl-2-oxazolines. GREEN PROCESSING AND SYNTHESIS, v. 2, n. 1, p. 8-pg., 2013-02-01. (08/55401-1, 11/11613-8, 11/03244-2, 12/17093-9)

CARMONA, RAFAELA C.; SCHEVCIW, EVELYN P.; PETRARCA DE ALBUQUERQUE, JOAO L.; WENDLER, EDISON P.; DOS SANTOS, ALCINDO A.. Joint use of microwave and glycerol-zinc (II) acetate catalytic system in the synthesis of 2-pyridyl-2-oxazolines. GREEN PROCESSING AND SYNTHESIS, v. 2, n. 1, SI, p. 35-42, FEB 2013. (08/55401-1, 12/17093-9, 11/11613-8, 11/03244-2)

RAFAELA C. CARMONA; EDISON P. WENDLER; GEORGE H. SAKAE; JOÃO V. COMASSETO; ALCINDO A. DOS SANTOS. A3-Coupling Reaction as a Strategy Towards the Synthesis of Alkaloids. Journal of the Brazilian Chemical Society, v. 26, n. 1, p. 117-123, 2015-01-00. (08/55401-1, 11/03244-2, 11/11613-8)

DONATONI, MARIA C.; JUNIOR, GILMAR A. B.; DE OLIVEIRA, KLEBER T.; ANDO, ROMULO A.; BROCKSOM, TIMOTHY J.; DOS SANTOS, ALCINDO A.. Solvent-free Diels-Alder reactions catalyzed by FeCl3 on Aerosil((R)) silica. Tetrahedron, v. 70, n. 20, p. 3231-3238, MAY 20 2014. (08/55401-1, 12/17093-9, 13/06532-4, 11/13993-2, 11/11613-8, 11/03244-2)

REIS DE SA, LEANDRO FIGUEIRA; TOLEDO, FABIANO TRAVANCA; DE SOUSA, BRUNO ARTUR; GONCALVES, AUGUSTO CESAR; TESSIS, ANA CLAUDIA; WENDLER, EDISON P.; COMASSETO, JOAO V.; DOS SANTOS, ALCINDO A.; FERREIRA-PEREIRA, ANTONIO. Synthetic organotelluride compounds induce the reversal of Pdr5p mediated fluconazole resistance in Saccharomyces cerevisiae. BMC Microbiology, v. 14, JUL 26 2014. (08/55401-1, 12/17093-9, 11/11613-8, 11/03244-2)

CARMONA, RAFAELA C.; WENDLER, EDISON P.; SAKAE, GEORGE H.; COMASSETO, JOAO V.; DOS SANTOS, ALCINDO A.. A(3)- Coupling Reaction as a Strategy Towards the Synthesis of Alkaloids. Journal of the Brazilian Chemical Society, v. 26, n. 1, p. 117-123, JAN 2015. (11/03244-2, 08/55401-1, 11/11613-8)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

CARMONA, Rafaela Costa. Asymmetric strategies in A3-coupling reactions. 2013. Master's Dissertation - Universidade de São Paulo (USP). Conjunto das Químicas (IQ e FCF) (CQ/DBDCQ) São Paulo.